Chemical bonding

Diels-Alder Reaction Objective: The objective of this lab was to do a diels-alder reaction using anthracene, maleic anhydride, and xylene to create 9,10-dihydroanthracene, 10-, -succinic acid anhydride. Experimental: Anthracene (1.00g, 5.61x 10-3 mol), maleic anhydride (0.75g, 7.61x 10-3 mol), xylene (5mL, 4.71x 10-2 mol), and a stir rod were added into a round-bottomed flask. The round-bottom flask was then moved to the hood where the it was attached to a distillation column, placed on…

INTRODUCTION Conformational isomerism is a type of stereoisomerism whereby the isomers are interconverted by rotations about the single bonds. There be terms used below such as eclipsed conformation, staggered conformation,dihedral angle and a few more. Eclipsed conformation is the conformation whereby the C-H bonds on one carbon is directly aligned with the C-H bonds of the adjacent carbon. When the C-H bond of one carbon bisects the H-C-H bond on the adjacent carbon, it is known as staggered…

Since suitable crystals for X-ray single crystal analysis was not obtained, to have reliable structural information, HR-TEM analysis of the product was carried out. The average size of the assembly calculated from HR-TEM measurement is found to be 2.8 nm which is in good agreement with the size of the previously reported Pd6L8 assembly where L is the non N-methylated (2.5nm, Fig. 2).9 As first step, to explore the catalytic activity of 1 in copper and phosphine free Sonogashira coupling reaction…

New method of synthesis of oligoetherols with carbazole ring Renata Lubczak Abstract: The new method of synthesis of multifuntional oligoetherols with carbazole ring suitable for obtaining the polyurethane foams of enhanced thermal resistance was presented. At the first step of the synthesis the carbazole was reacted with excess glycidol to obtain the product of (n +1) functionality, where n is number of equivalents of glycidol reacted with carbazole. Carbazole reacts with glycidol without…

Carbonyl compounds are the compounds the contain C=O group which is called carbonyl group (double bond oxygen to a carbon). There are many types of carbonyl compounds such as aldehydes, ketones, carboxylic acids, esters, amides etc. Aldehydes and ketones are the oxidation products of alcohols. Depending on the alcohol’s structure, the product obtained will be different. Primary alcohols have one carbon and two hydrogen atoms attached will produce aldehyde and then to carboxylic acid in two…

Water is a transparent, odourless, tasteless liquid, a compound of hydrogen and oxygen freezing at 30°F or 0°C and boiling at 212°F or 100°C, that in a more or less impure state constitutes rain, oceans, lakes, rivers etc; it contain 11188% of hydrogen and 88.812% of oxygen by weight. (Dictionary.com) The Earth is surrounded by 70% of water, however, that 70% is composed of salt water and fresh water. The salt water is made up of 97% and fresh water is 3%. 2% of the fresh water is frozen up in…

Phase Solubility results The phase-solubility diagram (figure 1) obtained was classified as AL type(20) because the apparent solubility of ISH increased linearly with β-CD concentration over the entire concentration range studies, thereby suggesting the formation of a water soluble complex. A slope value of less than one indicated that an inclusion complex in a molar stoichiometric ratio of 1:1 was formed between the drug and β-CD in solution. The stability constant (718.58 M–1), computed from…

NiCd is the chemical abbreviation for the composition of Nickel-Cadmium batteries, which are a type of secondary (rechargeable) batteries. Nickel-Cadmium batteries contain the chemicals Nickel (Ni) and Cadmium (Cd), in various forms and compositions. The nickel-cadmium battery, invented by Waldmar Jungner in 1899, offered several advantages over the then only rechargeable battery, lead acid, but the materials were expensive and the early use was restricted. Developments lagged until 1932 when…

Most corrosion is an electrochemical reaction. Anything that affects the speed of the chemical reaction will in turn affect the amount of current flow, which will affect the rate of corrosion. The rate of corrosion is directly proportional to the amount of current in the electrochemical corrosion cell. If the current can be measured accurately, then an exact calculation of the metal loss can be made. 2.2.1 ELECTRICAL EFFECTS ON THE RATE OF CORROSION Any issue that have an effect on the…

5. Proposed Research Questions and Tasks Four proposed research tasks will direct to fabrication conditions (Task 1), fabrication thermal analysis (Task 2), fabricated parts performance (Task 3), microstructure control methodology (Task 4), respectively. These tasks are designed to answer the questions and solve the problems in the results of preliminary experiments and observations from reported investigations. 5.1. Task 1. Investigating feasible formation conditions and effects of laser power…