Carbon-13

Diels-Alder Reaction Objective: The objective of this lab was to do a diels-alder reaction using anthracene, maleic anhydride, and xylene to create 9,10-dihydroanthracene, 10-, -succinic acid anhydride. Experimental: Anthracene (1.00g, 5.61x 10-3 mol), maleic anhydride (0.75g, 7.61x 10-3 mol), xylene (5mL, 4.71x 10-2 mol), and a stir rod were added into a round-bottomed flask. The round-bottom flask was then moved to the hood where the it was attached to a distillation column, placed on…

staggered conformation,dihedral angle and a few more. Eclipsed conformation is the conformation whereby the C-H bonds on one carbon is directly aligned with the C-H bonds of the adjacent carbon. When the C-H bond of one carbon bisects the H-C-H bond on the adjacent carbon, it is known as staggered conformation. Dihedral angle is the angle which separates the the bond on carbon atom from another bond of the adjacent atom. The conformer is each possible structure of the isomerism. Conformational…

6.3. A. Microemulsions (135-143) Microemulsions are clear, stable, isotropic mixtures of oil, water, and surfactant, frequently in combination with a cosurfactant 135-137. Microemulsions have several advantages such as enhanced drug solubility, good thermodynamic stability, and higher transdermal permeability over conventional formulations 138,139. Many studies reported the use of microemulsions as topical drug delivery vehicles showed their ability to improve transdermal and dermal delivery…

Lubczak R (2013) Polyester resins with carbazole ring. Polymer Intern 62; 1243-1249. Doi: http://dx.doi.org/10.1002/pi.4415 18. “Epoxide resins. Method of testing. Determination of the epoxide number and epoxide equivalent”, Polish Standards PN-C-89085-13:1987, Ed. Polish Committee for Standardization, 1987. 19. Kijowska D (2005) Alkylene carbonates with the five-membered ring. Preparation, properties and applications “ Przemysł Chemiczny, 84;…

In pursuit of our continued interest in the development of solvent-free and green synthetic procedures, we decided to explore the use of tartaric acid catalyst for synthesis of polysubstituted quinolines via Friedlander condensation in high to excellent yields at 70 °C under solvent-free conditions. Initially the reaction between 2-aminobenzophenone (1.0 mmol) and dimedone (1.0 mmol), as the model reaction was examined in the presence varying amount of tartaric acid as catalyst and the results…

2. Materials and methods 2.1. Chemicals Zingerone was obtained from Alfa Aesar, Heysham, UK. Cisplatin, Bradford reagent, trichloroacetic acid (TCA), thiobarbituric acid (TBA), reduced glutathione (GSH), glacial metaphosphoric acid (Gmpa), 5,5ˊ-dithiobis-(2-nitrobenzoic acid) (DTNB), proteinase K and agarose were purchased from Sigma-Aldrich Co, MO, USA. All other chemicals and solvents used were of the highest purity grade available. 2.2. Animals Sixty Adult male albino rats (180-200g) were…

In gloves industry, and for the maximum care of hands, Polyurethane-made gloves has shown the most remarkable effect than any other material. Known as one of the most versatile quality polymers, Polyurethane gloves are in huge demands at the consumer end. Well, what are the qualities that make a Polyurethane glove the best? To be honest, you can't find much stronger grip (and no sticky sensation) in a glove made by Polyurethane than any other material. The other qualities of this material are…

The role of oxysterols in human body and disease 1. Introduction Oxysterols are 27-carbon derivatives of cholesterol created by spontaneous or enzymatic oxidation (Figure 1, (Brown and Jessup, 2009)). The oxidation of cholesterol occurs either on the side chain or on the sterol core. Side chain oxidation generates, e.g., 24-hydroxycholesterol (24-HC), 25-hydroxycholesterol (25-HC) or 27-hydroxycholesterol (27-HC) while the core oxidation gives rise to ring oxysterols, mostly ring-B oxysterols,…

The zeolite XRD analysis result showed that it is 100% Clinoptilolite ─ Ca with the chemical formula Si29.04Al6.96O96.40Na1.92Ca1.57Ba0.32K0.56Mg0.72. Particle size distribution and Zeta potential for minerals have been carried out using Zeta sizer nano series (Nano ZS), Malvern, UK - Size range (nm):0.6:6000 nm and Zeta potential range (mV): (-200:200 mV) and analysis results are presented in Table 3. They The minerals were applied before planting in two separate rates ≈ 595.24 and 1190.48 5…

The polyurethane segments show high intersegment attraction such as hydrogen bonding and may be able to crystallize and form hard segments. In such polymers hard segments with Tg well above normal ambient temperature are separated by polyol soft segments, which in the mass are rubbery in nature. Hard and soft segments are arranged alternate along the polymer chain. Fig.7. Polyurethane chain configuration [32] 4.2.2. Polyurethane properties and advantages for product development…