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37 Cards in this Set

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Water is a polar molecule. This means that _____.
the opposite ends of the molecule have opposite electrical charges
In the case of water, the oxygen is slightly negative and the hydrogen atoms are slightly positive.
In a group of water molecules, hydrogen bonds form between _____.
the oxygen atom in one water molecule and a hydrogen atom in another water molecule
The slightly negatively charged region of an oxygen atom of one water molecule is attracted to the slightly positively charged region of a hydrogen atom of another water molecule.
What do cohesion, surface tension, and adhesion have in common with reference to water?
All are properties related to hydrogen bonding.
The extraordinary qualities of water are emergent properties resulting from hydrogen bonding.
Most of water's unique features (for example, its versatility as a solvent, ability to moderate temperature, and cohesive behavior) result from the fact that _____.
oxygen attracts electrons more than hydrogen does
Because oxygen is more electronegative than hydrogen, water molecules are polar and form hydrogen bonds that give water its extraordinary properties.
The partial charges on a water molecule occur because of _____.
the unequal sharing of electrons between the hydrogen and the oxygen atoms of a water molecule
Because oxygen is more electronegative than hydrogen, electrons of the polar bond spend more time closer to the oxygen atom, resulting in a slight negative charge on the oxygen atom and slight positive charges on the hydrogen atoms.
The ability of water molecules to form hydrogen bonds with other water molecules and water's ability to dissolve substances that have charges or partial charges are _____.
both caused by water's partial charges
Two molecules of water are held together by a hydrogen bond formed between the slight positive charge of the hydrogen and the slight negative charge of the oxygen. Water is a very versatile solvent, a quality traced to the polarity of the water molecule.
The phenomenon responsible for the maintenance of a column of water as it moves upward through a vessel is _____.
cohesion
Cohesion is a consequence of hydrogen bonding between water molecules.
Adhesion is best described as _____.
the clinging of one substance to another substance
Adhesion is the attraction of one substance to another.
You can fill a glass of water to just slightly above the rim without it spilling over the glass. What property of water best explains this phenomenon?
surface tension
Water has a greater surface tension, a measure of how difficult it is to break the surface of a liquid, than most other liquids.
Which action would involve the greatest transfer of heat?

..changing the temperature of 1 g of water from 10°C to 90°C
...cooling 10 g of water from 80°C to 40°C
...evaporating 1 g of water at 25°C
...condensing 5 g of steam to liquid water
...raising the temperature of 10 g of ethyl alcohol by 25°C
condensing 5 g of steam to liquid water
This would release about 2,900 calories (580 calories/gram x 5 grams).
Which example is not an effect of water's high specific heat?
Inland regions generally have milder climates than coastal regions.
Coastal regions generally have milder climates than inland regions because large bodies of water release stored heat as the water cools at night.
The amount of heat required to change the temperature of 1 g of any substance by 1°C is defined as _____.
the specific heat of that substance
The specific heat of a substance is defined as the amount of heat that must be absorbed or lost to change the temperature of 1 g of that substance by 1°C
The reason that coastal climates are more moderate than inland climates is due primarily to water's high _____.
specific heat
Because of its high specific heat, water's temperature will change less when it absorbs or loses a given amount of heat. Thus, the oceans can absorb and store a huge amount of heat and release it later when the temperature of the air has dropped.
Sweating has a cooling effect because of water's high _____.
heat of vaporization
Water's high heat of vaporization results in evaporative cooling because when water evaporates, the surface of the water cools down.
Water molecules have _____ than molecules of similar size, such as ammonia and methane.
a higher boiling point
More heat is needed to vaporize 1 g of water than most other liquids.
Because molecules of water are farther apart in ice than in liquid water, _____.
ice floats
Because water molecules in ice are farther apart than in liquid water, ice is less dense, and therefore, it floats.
Water is a very versatile solvent because water molecules are_____.
polar
Because molecules of polar solvents have a positive and a negative pole, polar solvents are excellent solvents for ions and for other polar materials.
Sodium chloride (NaCl) dissolves in water because water molecules _____.
are polar
Polar water molecules surround the individual ions, separating the sodium from the chloride and shielding the ions from one another.
Nonpolar molecules that cluster away from water molecules are called _____ molecules.
hydrophobic
Substances that are non-ionic and nonpolar repel water.
Hydrophilic substances, but not hydrophobic substances, _____.
have charges and partial charges to which water molecules can adhere
Hydrophilic substances are water loving and have an affinity for water. There is an unequal sharing of electrons resulting in a polar molecule, or there is the gain or loss of an electron(s) resulting in the formation of negatively and positively charged ions.
Hydrophobic molecules are _____ water.
repelled by
A molecule with all nonpolar bonds would not have an affinity for water and therefore would be hydrophobic.
Some substances, such as oil and gasoline, will not dissolve in water because _____.
their molecules have no charges or partial charges to which water molecules can adhere
The hydrophobic behavior of oil and gasoline molecules results from a prevalence of nonpolar covalent bonds between carbon and hydrogen.
An acid is _____.
a compound that donates hydrogen ions to a solution
An acid donates hydrogen ions to a solution.
Sucrose has a molecular mass of 342 daltons. To make a 2-molar (2 M) solution of sucrose, _____.
stir 342 g of sucrose in water to dissolve the sugar, and then add enough water to bring the total volume of the solution up to 0.5 L
Or you could stir 684 g of sucrose in water to dissolve the sugar, and then add enough water to bring the total volume of the solution up to 1 L.
A mole of ethyl alcohol weighs 46 g. How many grams of ethyl alcohol are needed to produce 1 L of a 2-millimolar (2 mM) solution?
0.092 g
This would produce a 0.002 M or a 2 mM solution.
Adding acid tends to ____ of a solution.
increase the hydrogen ion concentration and lower the pH
Because pH is a negative log, its value is inversely proportional to the hydrogen ion concentration.
Which of the following dissociations is that of an acid?
HF → H+ + F-
Hydrofluoric acid (HF) dissociates into a hydrogen ion and a fluoride ion.
A glass of grapefruit juice, at pH 3, contains _____ H+ as a glass of tomato juice, at pH 4.
ten times as much
The pH scale is a base-10 logarithmic scale. Each unit represents a tenfold increase or decrease in the hydrogen ion concentration.
A solution at pH 6 contains ____ than the same amount of solution at pH 8.
100 times more H+
Each pH unit change represents a tenfold difference in the hydrogen ion concentration; thus 10 x 10 = 100
Adding a base tends to _____ of a solution
lower the hydrogen ion concentration and increase the pH
A substance that reduces the hydrogen ion concentration is a base. Reducing the hydrogen ion concentration increases the pH.
When the pH of a solution shifts from 7 to 3, how has the hydrogen ion concentration changed?
It has increased by 10,000 times.
Because the pH number is the negative log of the hydrogen ion concentration, a change from a pH of 7 to a pH of 3 increases the hydrogen ion concentration by 10,000 times. (7 - 3 = 4; 104 = 10,000.)
Pure water has a pH of 7. Why does uncontaminated rainwater have a pH of 5.6?
formation of carbonic acid from carbon dioxide and water
The presence of carbonic acid in rain water causes it to have a lower pH than pure water.
A substance that minimizes changes in the concentration of H+ and OH- in a solution is a(n) ______.
buffer
Buffers are substances that minimize changes in the concentration of hydrogen ions and hydroxide ions in a solution; therefore, buffers maintain a relatively constant pH.
Which of the following statements does not correctly describe a buffer?

A buffer can accept H+ ions when needed.
A buffer can donate H+ ions when needed.
A buffer resists changes in the pH of a solution.
A buffer is only partly dissociated.
None of the above (all the above statements correctly describe a buffer).
None of the above (all the above statements correctly describe a buffer).
A buffer works by accepting hydrogen ions from the solution when they are in excess and donating hydrogen ions to the solution when they have been depleted, thereby minimizing changes in the concentration of hydrogen ions and hydroxide ions in a solution. This prevents changes in pH.
Which of the following statements is true about acid precipitation?
It harms aquatic life, but has little effect on terrestrial life.
It washes away some minerals that are plant nutrients, while causing some toxic minerals to accumulate.
Automobile use is the leading contributor to acid rain.
Industrial areas are hit hardest by acid rain.
None of the above.
It washes away some minerals that are plant nutrients, while causing some toxic minerals to accumulate.
Cells are surrounded by water, and cells themselves consist of about 70% to 95% water. As a result _____.
(1) the temperature of living things tends to change relatively slowly
(2) a variety of nutrient molecules are readily available as dissolved solutes
(3)waste products produced by cell metabolism can be easily removed
(4)dissolved substances can be easily transported within a cell or between cells in multicellular organisms
(5) all of the above
all of the above
The tendency of water molecules to stay close to each other as a result of hydrogen bonding _____.

(1)provides the surface tension that allows leaves to float on water
(2)is called cohesion
(3)keeps water moving through the vessels in a tree trunk
(4)acts to moderate temperature
(5)all of the above
all of the above