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45 Cards in this Set

  • Front
  • Back

Rayon




Cross-section...


Material...


Production method...

Cross-section: crenulated (star)


Material: regenerated cellulose


Wet spun

Lyocell




Cross-section...


Material...


Production method...

Cross-section: round


Material: regenerated cellulose


Wet spun

Acetate




Cross-section...


Material...


Production method...


Chemical component...

Cross-section: irregular


Material: regenerated cellulose


Dry spun


Notable chemical component: acetyl groups

Triacetate




Cross-section...


Material...


Production method...


Chemical component...

Cross-section: irregular


Material: regenerated cellulose


Dry spun


Notable chemical component: acetyl groups

Wet Spinning

Raw material dissolved by chemicals


Fiber is spun in a chemical bath


Fiber solidified when coagulated by bath

Dry Spinning

Resin solids are dissolved by solvent


Fiber is spun in warm air


Fiber solidifies by evaporation of the solvent

Melt Spinning

Resin solids are melted in autoclave


Fiber is spun into the air


Fiber solidifies on cooling


The preferred process: cleaner

Dope

thick solutions of raw material, also called spinning solution

Microfiber

Fibers with deniers of less than 1.0

Mixed-denier filament bundling

Combines fibers of several denier sizes in one yarn


Microfibers add softness while macrofibers add drape, durability

Trilobal Shape

Three-sided fiber cross-section designed to imitate silk

Thick-thin fibers

Have uneven diameter

How to modify for higher tenacity

Draw or stretch (increase crystallinity)


Chemical modification (increase DoP)

How to modify for low-pilling

Decrease molecular weight

Biconstituent/Bicomponent Fibers

Two different generic types contained in one fiber (e.g. nylon polyester)

Side-by-side Bicomponent fiber

Each type takes up half of the cross-section


Will create a spiral crimp when exposed to heat or moisture

Cover/core Bicomponent fiber

One polymer forms the core, the other wraps around the outside


Used for dye effects and to modify hand

Matrix-Fibril Bicomponent Fiber

One polymer forms a continuous phase with the other within it in theform of very small fibers called fibrils. Used for specialty fabricproduction. A way to produce microfibers.

How to de-luster a fiber

Add titanium dioxide to the spinning solution

How to make a fiber anti-static

Add a chemical conductor into the fiber to increase regain

How are manufactured cross-section controlled? What does the cross-section shape contribute?

Shape of spinneret hole


Wickability, luster, hiding soil

How to distinguish one man made fiber from another?

Solubility/chemical tests

Rayon Properties




Physical


Mechanical


Chemical



PHYSICAL


White, striations along surface


MECHANICAL


Weak when wet, poor resistance to abrasion, poor elongation, wrinkles


CHEMICAL


Amorphous


High regain


Damaged by acids and bases


Not more than 15% of hydroxyl groups are replaced by substitutes


Summary: It wrinkles easily and it's not strong but it's absorbent and dyes very well

Lyocell Properties




Physical


Mechanical


Chemical

PHYSICAL


smooth longitudinal structure


MECHANICAL


Strong, Weaker when wet, poor resistance to abrasion, adequate elongation


CHEMICAL


High regain


Summary: A lot like rayon but with better strength

HWM Rayon

High-Wet-Modulus Rayon


Less wrinkling, better in the washing machine

Acetate Properties




Physical


Mechanical


Chemical


Care

PHYSICAL


longitudinal striations


MECHANICAL


very weak, highly amorphous, poor elastic recovery, heat resistant


CHEMICAL


92% of hydroxyl groups replaced with acetic acid, moderate regain


Damaged by sunlight


CARE


dry clean


Summary: Very weak and damaged by sunlight, but easy to take care of and somewhat heat resistant

Triacetate

Acetate that is heat-set for higher crystallinity (65%)


Better resilience, lower regain

Condensation

as large molecules are made, small molecules are removed by chemical reactions

Addition

Double bonds between 2 Carbon atoms are broken, reforms a single bond connecting two monomers

Nylon Properties

PHYSICAL


lustrous, lightweight, customizable


MECHANICAL


High elongation, excellent elastic recovery/resilience, high abrasion resistance, oleophilic


CHEMICAL


Low regain, builds up static charge, difficult to dye, damaged by sunlight


Summary: Lightweight and has good strength and resilience, but hard to dye and damaged by sunlight

Nylon Uses

Apparel, carpet, industrial, tire cord


Dominates the hosiery/lingerie and carpet markets

Aramids Properties/Uses

High strength, high thermal stability, high modulus, lightweight


Used in bulletproof vests, boat hulls

Polyester Properties



Physical


Mechanical


Chemical

PHYSICAL


customizable, medium weight


MECHANICAL


high modulus, high elastic recovery/resilience, wrinkle resistant


CHEMICAL


Low regain, hard to dye, oleophilic, not damaged by sunlight/weathering


Summary: Good strength and wrinkle-resistant, but hard to dye and damaged by sunlight

Polyester uses

Apparel, industrial, tire cord, carpet

Olefin Properties




Physical


Mechanical


Chemical

PHYSICAL


floats in water


MECHANICAL


high tenacity, high abrasion resistance, high elastic recover, good modulus


CHEMICAL


highly crystalline, ZERO regain, damaged by sunlight, NO dry clean, oleophilic


Summary: durable and lightweight, but watch out for oil and sunlight

Olefin uses

Activewear, carpet, marine tow ropes, roadbed stabilizing

Acrylic Properties




Physical


Mechanical
Chemical

PHYSICAL

customizable, lightweight


MECHANICAL


weak-medium tenacity, weak-medium modulus, high elastic recovery, great resilience


CHEMICAL


Low regain but irregular surface wicks moisture away, builds up static charge


Summary: Weak with low regain but good substitute for wool and has good elastic recovery

Acrylic Uses

Apparel, typically sweaters and socks, good wool substitute

Modacrylic

Contains less acrylonitrile (AN) than acrylic


Flame resistant


Used for wigs so they can be curled with a curling iron

Modulus

Resistance to extension

Nylon




Cross-section...


Material...


Production method...


Chemical component...

Various


Petroleum


Melt spun


Amide groups

Polyester




Cross-section...


Material...


Production method...


Chemical component...

Various


Petroleum


Melt spun


Ethylene groups

Acrylic




Cross-section...


Material...


Production method...


Chemical component...

Various


Petroleum


Wet or Dry spun


Acrylonitrile (AN)

Modacrylic




Cross-section...


Material...


Production method...


Chemical component...

Various


Petroleum


Wet or Dry spun


Acrylonitrile (AN)

Olefin




Cross-section...


Material...


Production method...

Various


Petroleum


Melt spun