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31 Cards in this Set

  • Front
  • Back

Temporary hardness

- Bicarbonate


-easily removed by heating water to- 100^c


-calcium bicarbonate


-magnesium bicarbonate

Permanent Hardness

-not easily removed


-hard scale directly on heating surface


-calcium and magnesium sulfate


-calcium and magnesium chloride

Scale

-caused by dissolved solids


-settled on the heating surfaces


-prevent water to absorb heat.

1 gallon of water turns into how many gallons of steam

1600 gallons of steam

PH of acids

0-7

PH from 7-14

basic

what is neutral PH

7.0

ideal PH value for the boiler

10.5

treatment required for boiler water depends on



-water source


-boiler operating pressure


(higher boiling pressuer- more pure water must be)



surface water

-high in suspended solids and dissolved gasses


-low in dissolved solids (exception of sea water)



ground water

-low in suspended solids and dissolved gasses


-high in dissolved solids (high hardness)

treating surface water

-high suspended solids- settling and filtration


-high dissolved gasses- additional deaeration


-low dissolved solids- less chemical type treatments







treating ground water

-high in dissolved solids- extensive thermal and chemical treatments


-less deaeration necessary


-little filtration


-carbon filter used for high pressure plants.



external water treatment

-before water enters boiler


-upto and including deaerator



internal water treatment

-additions of chemicals



types of external water treatment

-evaporating: using heat to evaporate and remove all dissolved solids


-reverse osmosis: using high pressure to force water through a membrane that removes all dissolved solids


-Deaerating: using heat to drive off gasses like o2 or co2

types of internal water treatment

- adding chemicals to treat water


-chemicals can be used to :


-remove residual oxygen


- remove hardness


- adjust PH


- adjust tds (total dissolved solids)


- Disperse sludge


- reduce foam


- remove scale (extreme treatment)


- protect condensate from corrosion

clarifiers

-used to remove suspended solids


-by allowing them to settle (by gravity)


-commonly used for river water treatment

coagulation

-used in conjunction with settling tanks


-remove very fine particles by causing them to come together and make a larger particle (to settle better)


-neutralizes the negative charge



common coagulants

aluminium sulfate - AL2 ( SO4) 3


aluminum hydroxide


sodium aluminate

cartridge filter

-settling tanks to remove fine particles


-use until pressure drop across unit reaches set point.


-cartridges are replaced then



Cold Lime Soda Softening

- remove calcium & magnesium minerals


-Lime (calcium hydroxide ca(oh)2) & soda (sodium carbonate Na2Co3) are added to the water


-chemicals reacted with hardness in the water



Hot Lime Soda Softening

-heating decreases the reaction time & reduce the size of the vessel required


- used for boiler feed water treatment


- sludge is formed at the bottom


-

ion exchange water softening

process to remove hardness forming ions and replace them with sodium or Hydrogen



cation exchange

- calcium and magnesium cations removed


- replaced with sodium


- calcium carbonate to sodium carbonate


-magnesium chloride to sodium chloride

Hydrogen Zeolite softners

-replace all cations with hydrogen


-regenerated using acid (sulfuric acid)


ex- NaCl + H2Z = Na2Z + HCl

*demineralizers

*2 diff resins :


- 1 resin replaces cations with h2- Cation resin


- 1 resin replaces anions with h2- anion resin


-hydrogen and hydroxide radicals combine to form water


*-cation resin is regenerated with - sulfuric acid


*-anion resin regenerated with caustic soda

mechanical dearation

-removal of dissolved gasses from water


steps:- divide water into small particles (heat faster)


- heat water droplets to drive off dissolved gasses


- scrub gases away from water (prevent re dissolving)

grooving

-CO2attack

*deaerator controls

- pressure: -controlled by regulating steam flow


- Level : - controlled by regulating water flow


- overflow valve for when level too high


- high and low level alarm


-temp control: -controlled by Steam pressure


- Deaeration: - controlled by manual vent on top