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21 Cards in this Set

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Explain radical polymerisation with dibenzoyl peroxide.

Initiation: the dibenzoyl peroxide splits up by UV light into two reactive radicals. Propagation: the radicals attack the monomer. The product is a new radical. This attacks another monomer. Longer chain.

What is required for a monomer?

Multiple bonds or at least two functional groups.

What types of reactions ocurr to link different monomers?

Polymerisation,polycondensation and polyaddition.

What is a Polymer?

Huge chains of organic repeating units called monomers.

What is a monomer?

They can bond to each other on each side.

Name the steps of esterification.

Activation, addition, elimination, stabilisation

Explain esterification.

It needs a catalyst. Then the alcohol comes to play. Remember that you need carboxylic acid.

Saponification is the reaction of an.... To an....

Ester...alcohol and incomplete acid.

What is a thermoset,Thermoplast and elastomer?

What is the functional group in Polymerisation?

The double bond.

What is polycondensation?

Depending on the functional group the monomer becomes a different plastic. A small molecule is given off at the end.

We have a bifunctional and trifunctional monomer reacting through polycondensation. What properties do the plastics have?

A bifunctional monomer results in a thermoplast. A trifunctional monomer results in a thermoset.

Which functional group is necessary to result in a polyester through polycondensation?

Hydroxy group. OH

Which functional group do we need for a Polyamide (polycondensation)

Amide group. NH2

Which functional group do we need to result in polycarbonate?( Polycondensation)

Phosgene

In conclusion. What can result through polycondensation?

Polyester. Polyamide. Polycarbonate

The functional group of a polyester is?

Ester group.

The functional group of a Polyamide ist?

A peptide group.

Polyaddition requires what stupid?

Monomer with functional groups added to the double bonds.

What is the product of a polyaddition?

Polyurethane

What happens in polyaddition. Ya dumb