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Group 15

Metals non metals metalloids


NP


ArAn.


Bi


Nmetals


Metalloids


Metal

Nitrogen(1 2 4 OS)


Chile saltpetre


Indian saltpetre


OS- -3 +3 +5 BiF5 -5



Anomalous prty-


Small size high electro-vity


High ionisation enthalpy


Absence of d orbital


Pπ pπ bond


N-N bond weak dan P-P {high interelectronic repulsion of non bonding e-}



Max covalency 4

With H O X metals

Hydrides(EH3)


Stability decreases dwn d GRP


Reducing character??


Basicity??




Oxides(E2O3, E2O5)


Higher oxidatn state oxide acidity???


Dwn d GRP??


Acidic basic amphoteric oxide



X( EX3, EX5)


Nitrogen no pentaX due to???


More covalent?? ( penta or tri?)


Nly NF3 stable in case of nitrogen


Tri covalent except??



Metals


Binary compound -3 os


Ex- Ca3N2, Ca3P2, Na3As2, Zn3Sb2 Mg3Bi2