Orgo Chem Rxns 3

Front 1

Alkane to alkyne

Back 1

2NaNH2

Heat

Front 2

Dissolving metal of an alkyne yields

Back 2

trans alkene (E)

Front 3

Alkyne to cis (Z) alkene

Back 3

H2

(Lindlers catalyst) Pd, CaCO3, Quinoline

Or

Ni2B(P-2)

Front 4

Pg 13 test

Back 4

C2H5OH delta

Front 5

Alkyne to trans (E) alkene

Anti addition

Back 5

(Li) + Base

(Na)

Disolving metal reduction

Front 6

Alkene forms cyclopropane

Back 6

CH2I2 , Zn(Cu)

Retains stereo chem

Front 7

Alkene Br added to less substituted carbon

Back 7

HBr , ROOR

Antimarkovnikov

Front 8

Alkane with X (Br) elimination at less substituted C

Back 8

t-BuOK , t-BuOH

Bulky base and Neutriphile

Hoffman product

Front 9

Alkene I added to less sub and Cl added most subbed Carbon

Back 9

ICl

Front 10

Alkane Br sub for H (tert)

Back 10

Br2 hv

Radical rxn

Front 11

(CH3)2C=CH2 into cyclopropane (dichloro)

Back 11

HCCl3 + (CH3)3COK

Front 12

Radical

Back 12

Intermediate with an unpaired electron

Front 13

Syn addition

Back 13

Pg9

Front 14

Dehydration leaving group

Back 14

H2O

Front 15

Geometry of methyl radical

Back 15

Trigonal planar

Front 16

Stability of radiacal

Back 16

3°>2°>1°>ch3

Front 17

Electrophilic addition of hydrogen halides yields in RDS

Back 17

Carbocation

Front 18

Decomposition of diazomethane in heat or light yields

Back 18

Methelene :CH2

simplest carbene

Front 19

Rxn only bonds breaking

Only forming

Back 19

Endothermic

Exothermic

Front 20

Haloalcohol

Back 20

Halohydride

Ffhjne

Front 21

Show synthesis of product given reactant

Back 21

Start with final product go backwards using to determine reagents used

Front 22

Chain terminating step

Back 22

1)No free radical formed

2)process is exothermic

3) energy of activation is 0

4) delta H is negative

Front 23

Addition of hydrogen chloride to alkene stereo chem

Back 23

Fill either P orbital

Both enantiomers

Front 24

ICl type of addition

Back 24

Markovnikov product

Regioselective

Front 25

Br2 to alkene selectivity

Back 25

Stereo slective

Front 26

Alkene markovnikov addition of h2o without rearrangement

Back 26

1)Hg(OAc)2 , THF-H2O

2) NaBH4, HO-

Front 27

Q10 pg5

Back 27

A

Front 28

Alcohol that most rapidly dehydrates with H2SO4

Back 28

Tert, alcohol

Front 29

Carbocations

Back 29

1) rearrange to be more stable

2) lose a proton to form an alkene

3) combine with a nucleophile

4) react with an alkene to form larger...

Front 30

Heat (reflux) favors

Back 30

E2

Zaytsev product

Front 31

Elimination favors

Back 31

1) high temp

2) tert-butoxide ion used

3) 3°(2°) alkyl halides with strong base

Front 32

Sn1 rxn will be fallowed by

Back 32

E1 Rxn

pg2

Front 33

Ir bands 3300cm

Back 33

Pg14

Front 34

Elimination of R-X (Br)

Less substituted

Back 34

NaOEt heat(^)

Front 35

Cyclohexane to cyclohexene

Back 35

Br2 hv (adds br)

RO- Heat(^) removes Br forms double bond

Front 36

Add OH to terminal double bond

Antimarkovnikov

Back 36

1) BH3/THF

2) H2O2 , -OH