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26 Cards in this Set

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Polar covalent bonds

Chemical bond where pair of electrons unequally shared between two atoms

Nonpolar covalent bonds

Both atoms pull equally of pair of electrons so no net charge,no poles, pure covalent bond

Diatomic molecules

Molecular polarity depends on what

Depends on bond polarity and molecular structure

Nonpolar molecule

Hydrophobic (do not dissolve in watery but dissolve in other non polar molecule)


Symmetrical molecular structure

CCL4

Polar molecules

Asymmetrical


Hydrophilic(since water is polar molecule)

Intermolecular forces

Weaker than intramolecular forces(covalent and ionic bond)


Determine physical properties(solubility, BP,MP)


Strength depends on polarity ,size, shape

London dispersion forces

Weakest bond


Between noble gas and nonpolar molecules


Temporary unequal distribution of electrons

Dipole dipole force

Stronger than LDF


Between 2 polar molecules


Partially positive side attract partially negative side

Hydrogen bond

Strongest force


Partially positive H attract partially negative N,O,F


Most significant for function of cell

Organic compound vs inorganic compound

Organic contains combo of C and H atoms


Inorganic does not

Hydrocarbon

Contain only C,H


Hydrophobic side CC and CH bonds are nonpolar

Chemical formulas

Molecular formula gives #of atoms of each element in compound



Empirical same as molecular but at smallest possible ratio



Structural like a diagram and shows how various atoms are bonded



Simplified does not showC, H, Hbonds

Polymer vs monomer

Polymer/ macromolecules is large chemical compound composed of repetitive monomers



Monomers subunit of polymers

Condensation reaction

Take out water


Connect micromolecules to form macromolecules


Eg.

Hydrolysis reaction

Add in water


Macromolecules break down into micromolecules


E.g. digestion

Neutralization reaction

Acid+base= water + salt

Redox reaction

Chemical reaction where electrons are transferred between atoms


Oxidation is loss


Reduction is gain

OIL


RIG

Important elements

Nitrogen part of amino group of amino acids that makes up proteins and nitrogenous base of nucleic acids



Calcium needed to make mineral CA3(PO4)2 which strengthens bones and teeth



Iron NEEDED to make hemoglobin(carriers of O and CO2) and part of proteins that involve electron transport in plants, animals, prokaryotes



Phosphate are in phosphate groups and nucleotides (DNA, RNA)



Sodium used in neurons for transmission of nerve impulses

N,Ca,Na,Pb,P

Falsification of theory

Vitalism is philosophy that life not subject to laws of physics and chemistry



Urea is nitrogen containing compound produced in liver when there is excess amino acids


Transported by blood to kidney then filtered through urine



1828 Friedrich wohler artificially created urea with silver izocyanate and ammonium chloride



Ammonium cyanate is unstable but particles rearrange to form urea



Inorganic become organic



Urea

Macromolecules major 4

Carbohydrates if CHO ratio 1:2:1


Micromolecule is monosaccharidses



Lipids if less oxygen and many hydrocarbon


Micromolecule is glycerol and fat acids



Nucleic acid if repeating sugar and phosphate group


Micromolecule is nucleotide



Protein if contain N and repeating peptide link


Micromolecule is amino acids

Isomers

Same molecular formula but different structure so different properties



Structural had different covalent arrangement



Geometric has different spatial arrangement and at least one double bond


Cis is natural and 2 groups on same side of double bond


Trans is unnatural and 2 groups on different sides of double bond



Enantiomers is mirror images, usually one form is biologically active and other is not


Functional group



Functional group define characteristic group of compound and determine properties


Carbohydrate

CHO ratio 121


Made of sugar and their polymers formed by condensation reaction


Easily digested so energy released faster than lipids


Soluble so easily transported



Important for cell to cell communication and cell support


Used as raw material to build amino acids, lipids and nucleic acids


6 points

Monosaccaharidses

Simple sugar 3 to 7 carbon


Composed of hydroxyl and aldose or ketone group


Major nutrient for cell



Aldose


Triose glyceraldehyde


Pentose ribose


Hexose glucose, galactose



Ketose


Triose dihydroxiacetone


Pentose ribulose


Hexose fructose



Usually form rings on aqueous solution

Dissacharide

Made of 2 monosaccharides



Gylcosidic linkage is covalent bond formers by condensation reaction between 2 sugar



Ether linkage is formed between 2 alcohols



Maltose is 2 glucose


Sucrose is glucose and fructose


Lactose is glucose and galactose

3 points

Starch vs celulose polysaccharide