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10 Cards in this Set

  • Front
  • Back
What does this do to an alcohol?

Na
---------->
Peroxides
No Conversion of bonds.

Displaces H, leaving O⁻Na⁺
What does this do to an alcohol?

H₃PO₄
--------->
heat
No Conversion of bonds.

Removes OH

Converts single bond on α-β Carbon to double
What does this do to a di-alcohol across a single bond?

H₂SO₄
No Conversion of bonds.

Loss of one OH

Conversion of other OH to double-bond O

Pinacol Rearrangement
What does this do to a primary alcohol?

H₂CrO₄/H₂O
----------------->
acetone
No Conversion of bonds.

Converts COH to COOH (alcohol to acid)
What does this do to a secondary alcohol?

H₂CrO₄/H₂O
----------------->
acetone
No Conversion of bonds.

Converts OH to double-bonded O (alcohol to ketone)
What does this do to a primary alcohol?

PCC
No Conversion of bonds.

Converts alcohol to aldehyde
What does this do to a ringed vicinal-diol?

HIO₄
Cleaves bond between diols.

OH groups become Carbonyls and H (CHO)
What does this do to a Thiol?

O₂
No Conversion of bonds.

Converts Thiol to disulfide

2 RSH become RSSR
Function on an alcohol

TsCl
Reverses position of OH (Trans <-> Cis)

ROH + Tscl → ROTs + Nu: → RNu
Function for tBuO-
Converts alkane to alkene

Removes Br via E2