Organic Chemistry: Reaction Types

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Catalytic Hydrogenation

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Catalytic Hydrogenation

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Acid

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Acid

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Addition of HX to Double Bond

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Addition of HX to double bond

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Addition of HX to double bond

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Reaction of Alkene with HX in the presence of peroxide and heat

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Reaction of Alkene with HX in the presence of peroxide and heat

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Hydration of alkenes to form alcohols

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Hydration of alkenes to form alcohols

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Hydration of alkenes to form alcohols

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Dehydrohalogenation

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Oxymercuration, demercuration

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Oxymercuration, demercuration

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Hydroboration Oxidation of Alkenes

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Hydroboration Oxidation of Alkenes

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Addition of X2 to double bonds

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Addition of X2 to double bonds

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Halogenation

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Halogenation

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Epoxidation

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Epoxidation

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Reaction with HX

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Cyclopropanation

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Cyclopropanation

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Ozonalysis

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Ozonalysis in the presence of a reductive agent

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Oxidation of KMNO4

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Oxidation of KMNO4

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A diene that has two or more single bonds separating the double bonds.

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Isolated

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A diene with no single bonds between the two double bonds.

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Cumulated

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A diene with one single bond between two double bonds.

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Conjugated

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What is the most stable diene?

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Conjugated

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What is the least stable diene?

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Cumulated

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1, 2 addition of HX

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1, 4 addition of HX

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1, 2 addition of HX

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1, 4 addition of HX

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What will make a dienophile more reactive?

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Electron Withdrawing Group

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What will make a diene more reactive?

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Electron Donating Group

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What are some examples of Electron Donating Groups?

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CH3, CH2CH3, OCH3, OH, NH2

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What are some examples of Electron Withdrawing Groups?

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Cl, Br, I, F, NO2, CF3

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Dienes must be _______ for Diels Alder reaction to take place.

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Cis

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Diels Alder

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Diels Alder

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Diels Alder

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Allylic Bromination

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Allylic Bromination

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Halohydrine

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Why do the E1 reactions require a polar, protic solvent?

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Polar protic solvents have acidic hydrogens which help the leaving group to dissociate into solution.

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Syn Addition

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The addition of two substituents to the same side of a double bond or triple bond.

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Which one is the most stable?

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B

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Which one is the least stable?

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D