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42 Cards in this Set

  • Front
  • Back
What is a Hydrocarbon?
A compound composed only of carbon and hydrogen
What is a saturated hydrocarbon?
A hydrocarbon containing only single bonds.
What is an unsaturated hydrocarbon?
A hydrocarbon that contains one or more carbon-carbon double or triple bonds.
What is an alkane?
A saturated hydrocarbon whose carbons are arranged in an open chain.
What is an aliphatic hydrocarbon?
Another name for an alkane
Give an example of an aromatic hydrocarbon.
Benzene (C6H6)
What is the shape of an Alkane?
tetrahedral
What are the measurements of the bond angles for Alkanes?
109.5 degrees
What is a line angle formula?
An abbreviated way to draw a structural formula
Each vertex and line ending represents a _______ in a line angle formula.
carbon
What are constitutional isomers?
Compounds with the same molecular formula but a different connectivity of their atoms
Name the four steps in telling whether two formulas are constitutional isomers.
1.Write the molecular formula for each
2.Find the largest carbon chain
3.Number the chain from the end nearest the first branch
4.Compare the chain lengths as well s the identity and location of the branches
Meth-
one carbon
eth-
2 carbons
prop-
3 carbons
but-
4 carbons
pent-
5 carbons
hex-
6 carbons
hept-
7 carbons
oct-
8 carbons
non-
9 carbons
dec-
10 carbons
undec-
11 carbons
dodec-
12 carbons
tridec-
13 carbons
tetradec-
14 carbons
pentadec-
15 carbons
hexadec-
16 carbons
heptadec-
17 carbons
octadec-
18 carbons
nonadec-
19 carbons
elcos -
20 carbons
What is the suffix used in nomenclature for Alkanes?
-ane
How do you find the Parent (root) name in nomenclature?
the longest carbon chain
What is a substituent?
A group bonded to the parent chain.
What is an Alkyl group?
a substituent derived by removal of a hydrogen from an alkane.
If you take the Methane (CH4) structure how would you make it an Alkyl group?
Remove a hydrogen (CH3-) to create the Methyl Group.
How do you name a structure according to IUPAC?
1.) Find the parent chain
2.)Number the chain by giving the substituent the lowest number possible.
3.) give the substituent a name and number.
When naming according to IUPAC, what happens if there are two or more identical substituents?
1.)Number the chain from the end that gives the lower number to the substituent encountered first.
2.) Indicate the number of times the substituent appears by a prefix like di, tri, tetra, etc.
3.) Use a comma to separate position numbers.
When naming according to IUPAC, what do you do when there are two or more different substituents?
1.) list them in alphabetical order
2.) number from the end of the chain that gives the substituent encountered first the lower number.
True or false:
According to IUPAC, the prefixes di, tri, tetra, etc. are NOT included in alphabetization.
True
According to IUPAC nomenclature, what happens when there are two or more parent chains of identical length?
Choose the parent chain with the greater number of substituents and continue nomenclature from there.