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16 Cards in this Set

  • Front
  • Back

A species with a divalent carbon atom

Carbene

Reaction of an alkyl halide with a solvent

Solvolysis

The final step in a multi step mechanism

Product determining step

The group displaced in a nucleophilic substitution

Leaving group

The mathematical statement of how a reaction rate depends on concentration

Rate law

The regioselectivity to produce the most highly branched alkene isomers in an elimination reaction

Saytzeff's Rule

Generically an ROH compound

Alcohol

Slowest step in a multi step reaction

Rate Limiting step

Unstable state of maximum free energy

Transition state

When a group from the starting material has moved to a different position in the product

Rearrangement

Hydroboration

"Syn" addition, anti-markovnikof, products are H and OH

Oxymercuration-reduction (Hg-O-Ac)

"Anti" addition, markovnikof, products are H and OH

Halohydrin (Br&Br, Cl&Cl over OH)

"Anti" addition, markovnikof, products are Br/Cl and OH

Hydrogenation (H2 over Pt/Pd)

"Syn" addition, products are H and H

Halogenation (Br&Br, Cl&Cl over CCl4)

"Anti" addition, products are Br&Br, Cl&Cl

Tetrohydrofuran is an important solvent because it dissolves both organic compounds and water

True