Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
199 Cards in this Set
- Front
- Back
What is the dominant type of binding for Titanium?
ionic hydrogen covalent van der waals metallic |
Metallic
|
|
Which of the following materials may form crystalline solids?
A. Polymers B. Metals and Ceramics C. All of the above D. None of the above |
C. All of the above
|
|
For the face-centered cubic crystal structure: How many atoms are associated with each unit cell?
A. 1 B. 2 C. 4 D. 14 |
C. 4
|
|
6. For the face-centered cubic crystal structure, what is the coordination number?
A. 4 B. 6 C. 8 D. 12 |
D. 12
|
|
7. For the face-centered cubic crystal structure what is the atomic packing factor?
A. 0.50 B. 0.68 C. 0.74 D. 0.80 |
C. 0.74
|
|
13. The atomic diameter radius of a BCC crystal (if a is lattice parameter) is (a) a/(√3/4)
(b) a/2 (c) a/(4/√3) (d) a/(4/√2) |
(c) a/(4/√3)
|
|
14. Miller indices of close packed planes in a bcc crystal (a) (100)
(b) (110) (c) (111) (d) depends on the atom type (e.g. Fe or Al) |
(b) (110)
|
|
15. The plane (1͞11) is parallel to
(a) ( ͞11͞1) (b) ( ͞1͞11) (c) (111) (d) (1͞11) |
(a) ( ͞11͞1)
|
|
16. If I quench a solid metal from high temperature (e.g. 0.8 Tmp) the number of vacancies will be ___________ if I cool slowly.
A. less than B. greater than C. the same as |
B. greater then
|
|
7. Calculate the fraction of atom sites that are vacant for silver at 661°C. (Silver has an fcc crystal structure) Assume an energy for vacancy formation of 0.63 eV/atom.
 a) 4.0 x 10-4 b) 1.58 x 10-5 c) 1.6 x 10-3 d)6.664 x 10-28 |
a) 4.0 x 10-4
|
|
18. The surface energy of a single crystal depends on the crystallographic orientation with respect to the
surface. a) always true b) always false c) it depends on the materials |
a) always true
|
|
Which is not a 2-dimensional imperfection?
(a) Twin boundary (b) Dislocation (c) Surface (d) Grain boundary |
(b) Dislocation
|
|
Which are thermodynamically stable defects?
(a) Point defects (b) Line defects (c) Surface defects (d) Volume defects |
(a) Point defects
|
|
Which of the following is false?
(a) Line defects are thermodynamically stable (b) Dislocation can end inside a crystal without forming loop (c) ABC ABC ABC...is stacking sequence for HCP crystal (d) All (e) None |
all
|
|
Modulus of elasticity ________________ as the bond energy increases
(a) increases (b) decreases (c) does not change |
increases
|
|
The diffusion rate for an interstitial atom is ________________ that of a substitutional atom.
(a) greater than (b) less than (c) the same as |
greater than
|
|
Solid solubility of element A in element B __________________ as the difference in their atomic radii decreases.
(a) increases (b) decreases (c) does not change |
increases
|
|
The stress required for slip in the (100) is ________________ what is required in the (110) in bcc metals.
(a) greater than (b) less than (c) same as |
greater than
|
|
With increasing bond strength the melting temperature will ___________________.
(a) increase (b) decrease (c) not change |
increase
|
|
Atoms in the slip plane are _________________ distance apart as atoms in other planes.
(a) closer (b) further (c) the same |
closer
|
|
In general hcp metals will exhibit ____________ ductility than fcc metals
(a) more (b) less (c) roughly the same |
less
|
|
After an edge dislocation has passed through some region of a crystal, the atomic arrangement of that
region is _______________ a) disordered b) the same as before (ordered) c) amorphous |
same as before
|
|
For a particular crystal structure, the slip direction is that direction in the slip plane having the: a) highest linear density b) lowest linear density c) it is unrelated to linear density
|
highest linear density
|
|
For a particular crystal structure, the slip plane is that plane having the:
a) least dense atomic packing b) densest atomic packing c) it is unrelated to packing density |
densest atomic packing
|
|
Niobium has an atomic radius of 0.143 nm and is bcc. Its atomic weight is 92.91 Calculate its density
a. 4.29 g/cm3 b. 8.57 g/cm3 c. 543.7 g/cm3 d. 105.56 g/cm3 |
b. 8.57 g/cm3
|
|
If the lattice of a material expands (e.g. due to substitution of larger atoms of a different type) the peaks on the diffraction pattern will
a) move to the left (smaller 2θ) b) move to the right (larger 2θ) c) remain unchanged (no shift) |
a) move to the left (smaller 2θ)
|
|
A hypoeutectoid composition steel will have an amount of ferrite in its microstructure that is
_______________ that found in a eutectoid steel. (a) greater than (b) less than (c) the same as |
greater than
|
|
The hardness of tempered martensite is _____________ that of untempered martensite. (a) greater than (b) less than (c) the same as
|
less than
|
|
The sintering rate of a ceramic material will ____________________ as the particle size is reduced. (a) increase (b) decrease (c) not change
|
increase
|
|
The melting point of a polymer will ______________ as the degree of polymerization decreases. (a) increase (b) decrease (c) not change
|
decrease
|
|
The eutectoid composition of steel _______________________ as more carbon is added to the system. (a) increase (b) decrease (c) not change
|
not change
|
|
The modulus of elasticity of polyethylene will ____________________ as the strain rate is increased. (a) increase (b) decrease (c) not change
|
increase
|
|
The degree of crystallization of polyethylene will ____________________ as the cooling rate from high temperature is decreased.
(a) increase (b) decrease (c) not change |
increase
|
|
The eutectoid composition of an alloy will ____________________ with cold working.
(a) increase (b) decrease (c) not change |
not change
|
|
Adding sulfur to polyisoprene (rubber) causes its modulus of elasticity to _____________.
(a) increase (b) decrease (c) not change |
increase
|
|
If the austenite grain size increases, the hardenability of a steel alloy will _________________? (a) increase (b) decrease (c) not change
|
increase
|
|
For each of the following pairs of polymers decide which is more likely to crystallize?
a) linear and syndiotactic polyvinyl chloride; b) linear and isotactic polystyrene |
a) linear and syndiotactic polyvinyl chloride
|
|
For each of the following pairs of polymers decide which is more likely to crystallize?
a) linear and syndiotactic polypropylene; b) crosslinked cis-isoprene |
a) linear and syndiotactic polypropylene
|
|
For each of the following pairs of polymers decide which is more likely to crystallize?
a) network phenol-formaldehyde; b) linear and isotactic polypropylene |
b) linear and isotactic polypropylene
|
|
For each of the following pairs of polymers decide which is more likely to crystallize?
a) lightly branched isotactic polypropylene; b) linear polyethylene |
b) linear polyethylene
|
|
For each of the following pairs of polymers decide which is more likely to crystallize?
a) alternating poly(styrene-ethylene) copolymer; b) random poly(vinyl chloride-tetrafluoroethylene) copolymer |
a) alternating poly(styrene-ethylene) copolymer
|
|
For each of the following pairs of polymers, decide which is more likely to have the greater tensile strength?
a) lightly cross-linked polyethylene; b) network phenol-formaldehyde |
b) network phenol-formaldehyde
|
|
For each of the following pairs of polymers, decide which is more likely to have the greater tensile strength?
a) lightly cross-linked polyvinyl chloride; b)branched polyvinyl chloride |
a) lightly cross-linked polyvinyl chloride
|
|
For each of the following pairs of polymers, decide which is more likely to have the greater tensile strength?
a) 95% crystalline and linear PTFE having a number average molecular weight of 650,000 g/mol; b)80% crystalline and linear PTFE having a number average weight of 500,000 g/mol |
a) 95% crystalline and linear PTFE having a number average molecular weight of 650,000 g/mol
|
|
For each of the following pairs of polymers, decide which is more likely to have the greater tensile strength?
a) Atactic polypropylene having a weight average molecular weight of 750,000 g/mol b)isotactic polypropylene having a weight average molecular weight of 750,000 g/mol |
b)isotactic polypropylene having a weight average molecular weight of 750,000 g/mol
|
|
For each of the following pairs of polymers, decide which is more likely to have the greater tensile strength?
a) alternating styrene butadience co-polymer; b)graft styrene butadiene co-polymer |
a) alternating styrene butadience co-polymer
|
|
Polyethylene is being processed. H2O2 is used as the source of free radicals. Batch A is made with 0.1 wt. %
H2O2. Batch B is made with 0.2 wt. % H2O2. Which batch do you expect to have better mechanical properties? a) Batch A b) Batch B c) They will be about the same d) there is not enough information to tell |
Batch A
|
|
Which alloy has higher hardenability, 1040 or 4340? a) 1040 b) 4340 c) no difference is expected
|
4340
|
|
How will addition of a filler affect the ease of crystallization of a polymer?
a) it will make it easier b) it will make it more difficult c) it will have no effect |
b) it will make it more difficult
|
|
Increasing the carbon content in steel will cause the ductility to __________________.
(a) increase (b) decrease (c) not change |
b) decrease
|
|
Increasing the deformation (strain) rate ________________ the toughness of polyethylene.
(a) increases (b) decreases (c) does not change |
decreases
|
|
A sample of amorphous polyethylene is found to have an average molecular weight of 25,000 amu. What is the degree of polymerization of the average polyethylene molecule. Assume at. Wt. of C=12, H=1.
a) 2154 b) 1786 c)1250 d) 893 |
d) 893
|
|
Chemical tempering of a glass leads to increased strength by replacement of near surface ions. The replacement ions _____________________ the ions they substitute for.
a) Are smaller than b) are larger than c) have a higher valence than d) have lower valence than |
b) are larger than
|
|
f cupric oxide (CuO) is exposed to a reducing atmosphere at elevated temperatures, some of the Cu2+ ions will become Cu+. What effect will this change in valence have on the stoichiometry?
a) none b) a Frenkel defect will be created c) a Schottky defect wil be created d) the stoichiometry will change (e.g. CuO1-x) to maintain charge balance |
d) the stoichiometry will change (e.g. CuO1-x) to maintain charge balance
|
|
Which of the following is false
a) Concrete is made from stone, cement, sand and water b) heat is given off as concrete hardens c) hardening of concrete can continue for months d) concrete hardens as water evaporates |
d) concrete hardens as water evaporates
|
|
A thin piece of glass (~ 2mm) will be ____________________ to temper than a thick (~10mm) piece. a) easier b) more difficult c) equally challenging
|
more difficult
|
|
A coarse grained polycrystalline material will have a yield strength that is _______________ a fine grained version of the same material.
a) greater than b)less than c) approximately the same as |
less than
|
|
Increasing the grain size of a metal ________________ its toughness.
(a) increases (b) decreases (c) does n\not change |
decreases
|
|
As the impurity concentration in a dilute solid solution of a metal is decreased, the yield strength _________________.
(a) increases (b) decreases (c) does not change |
decreases
|
|
Initially fully annealed Lead ( mp=327C) and Copper (mp=1085C) are both deformed 20% at 50C. Which one experiences the greater change in hardness?
a) lead b) copper c) both will increase the same relative amount d) neither one will change |
b. copper
|
|
The area under the stress-strain curve up to fracture is related to:
a) hardness b) ductility c) toughness d) stiffness |
toughness
|
|
Bulk diffusion is __________________ grain boundary diffusion
(a) faster than (b) slower than (c) same rate as |
slower
|
|
For an alloy of composition 80 wt%Ag cooled slowly from the melt, the mass fraction of proeutectic beta-phase at room temperature is
a) 8% b) 42% c) 50% d) 58%. |
42%
|
|
The tendency for brittle fracture _____________ as surface energy decreases. (a) increases (b) decreases (c) does not change
|
increases
|
|
The diffusion coefficients for copper in aluminum at 500 and 600oC are 4.8 x 10-14 and 5.3 x 10-13 m2/s, respectively. Determine the approximate time (in hrs.) at 500 oC that will produce the same diffusion result (in terms of concentration of Cu at some specific point in the Aluminum) as a 10hr heat treatment at 600oC.
a) 55.2 b) 220.8 c) 1218.8 d) 110.4 |
110.4
|
|
The driving force for grain growth ______________ as the grain size increases. (a) increases (b) decreases (c) does not change
|
decreases
|
|
Brittle failure is _____________ likely to occur at low temperatures than(as) at high temperatures. a) less b) more c) just as
|
more
|
|
With a decrease in strain rate, the yield strength will ___________ . (a) increase (b) decrease (c) not change
|
decrease
|
|
As the grain size decreases, the hardness ______________ (a) increases (b) decreases (c) is unaffected
|
increases
|
|
Cold-work causes the resistivity of a metal to ______________. (a) increase (b) decrease (c) not change
|
increase
|
|
Recrystallization will __________ the yield strength. (a) increase (b) decrease (c) not change
|
decreases
|
|
As cold work decreases, the density of dislocations __________________. (a) increases (b) decreases (c) is unaffected
|
decreases
|
|
We are asked to produce a brass wire using an alloy of 70wt%Cu-30wt%Zn with a yield strength of greater than 50 [ksi], and a ductile elongation of more than 20% in the final wire. Is it possible to make such a brass wire?
a) No b) Yes c) There is insufficient information given |
yes
|
|
The activation energy for substitutional diffusion is ________________ that for interstitial diffusion .
a) greater than b) less than c) about the same as |
greater than
|
|
Shot peening will cause the fatigue strength of an alloy to _______________. (a) decrease (b) increase (c) not change, as it only cleans the surface
|
increases
|
|
The mobility of dislocations in a metal will ________________ as the ambient temperature is increased. (a) increase (b) decrease (c) not change
|
increases
|
|
At a given temperature the creep resistance of a strain free single crystal of an alloy will be __________________ that of a heavily cold worked polycrystalline sample of the same alloy.
a) greater than b) less than c) about the same as |
greater than
|
|
During recrystallization the number of grains will _____________________.
(a) decrease (b) increase (c) not change |
increases
|
|
A cup-and-cone surface is associated with_______________________
a) brittle fracture b) ductile fracture c) case-hardening |
ductile fracture
|
|
KIc is a value that quantifies the _________________ of a material.
a) yield strength b) creep resistance c) fracture toughness d) fatigue tendency |
c) fracture toughness
|
|
Creep rate will ________________ as the temperature is increased.
(a) increase (b) decrease (c) be relatively unaffected |
increase
|
|
Why does aluminum foil have a shiny side and a dull side
a) the top side becomes dull because of oxidation effects b) only the side contacting the roller is shiny c) it is too expensive to make both sides shiny d) temperature uniformity will be improved during cooking e) only one side gets acid-etched |
b) only the side contacting the roller is shiny
|
|
For a steel alloy it has been determined that a 12 hr carburizing heat treatment will raise the carbon concentration to 0.38 wt% at a point 1.5 mm from the surface. Estimate the time (in hrs) necessary to achieve the same concentration at a 4.7 mm position for an identical steel and at the same carburizing temperature.
a)118hrs b) 38 hrs c) 451hrs d) 1414hrs |
118 hours
|
|
In measuring a stress-strain curve of a metal, I load past the yield stress and release the load. If I then reapply a load, the
yield stress the second time will be __________________ the first value. a) greater than b) less than c) unchanged from |
greater than
|
|
An impurity atom that is larger than a host atom for which it substitutes exerts __________ strain on the surrounding crystal lattice.
a) compressive b) tensile c) no |
compressive
|
|
Such an atom, in order to cancel some of the strain associated with a dislocation in the lattice (see
figure) will reside __________________ the slip plane a) just above b) just below c) far away from |
just below
|
|
What type(s) of bonding would be expected for each of the following materials? For bonds which could share ionic and covalent character, choose the one that would predominate.
a) barium sulfide (BaS) b) bronze |
ionic
metallic |
|
NaCl has _____ bonding.
CH4 has ____ bonding. |
ionic
covalent |
|
What is the atomic packing factor for the BCC crystal structure?
|
.68
|
|
For an FCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (111) plane?
|
greater
|
|
For a given material, would you expect the surface energy to be greater than, the same as, or less than the grain boundary energy?
|
greater
|
|
Is the grain boundary energy of a small-angle grain boundary less than for a high-angle one? (yes or no)
|
yes
|
|
Which of the following characteristics that relate the solutes and solvents (and their atoms) determine the degree to which the solute species dissolves in the solvent?
Valence Atomic number Atomic size Crystal structure Electronegativity |
Valence
Atomic size Crystal structure Electronegativity |
|
Solute or impurity atoms replace or substitute for the host atoms.
|
substitutional
|
|
Impurity atoms fill the voids or interstices among the host atoms.
|
interstitial
|
|
Which of the following are linear defects?
A Frenkel defect A screw dislocation A Schottky defect An edge dislocation |
A screw dislocation
An edge dislocation |
|
Diffusion by which mechanism occurs more rapidly in metal alloys?
|
interstitial
|
|
After an edge dislocation has passed through some region of a crystal, the atomic arrangement of that region is disordered.
|
false
|
|
The process by which plastic deformation is produced by dislocation motion is called
|
slip
|
|
During the recovery of a cold-worked material, which of the following statement(s) is (are) true?
Some of the internal strain energy is relieved. All of the internal strain energy is relieved. There is some reduction in the number of dislocations. There is a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state. The electrical conductivity is recovered to its precold-worked state. The thermal conductivity is recovered to its precold-worked state. The metal becomes more ductile, as in its precold-worked state. Grains with high strains are replaced with new, unstrained grains. |
Some of the internal strain energy is relieved.
There is some reduction in the number of dislocations. The electrical conductivity is recovered to its precold-worked state. The thermal conductivity is recovered to its precold-worked state. |
|
During the recrystallization of a cold-worked material, which of the following statement(s) is (are) true?
The electrical conductivity is recovered to its precold-worked state. Grains with high strains are replaced with new, unstrained grains. The thermal conductivity is recovered to its precold-worked state. All of the internal strain energy is relieved. There is a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state. The metal becomes more ductile, as in its precold-worked state. Some of the internal strain energy is relieved. There is some reduction in the number of dislocations. |
Grains with high strains are replaced with new, unstrained grains.
All of the internal strain energy is relieved. There is a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state. The metal becomes more ductile, as in its precold-worked state. |
|
Grain growth must always be preceded by recovery and recrystallization.
|
false
|
|
How would the plane strain fracture toughness of a metal be expected to change with rising temperature?
|
increase
|
|
Which of the following factor(s) favor(s) brittle fracture in polymers?
Increasing in temperature. Increasing in strain rate. The presence of a sharp notch. Decreasing specimen thickness. |
Increasing in strain rate.
The presence of a sharp notch. |
|
Which of the following affect(s) the creep characteristics of metals?
Grain size Ductility Resilience Yield strength Melting temperature Elastic modulus |
Grain size
Melting temperature Elastic modulus |
|
If either stress or temperature is increased, indicate which of the following consequences will result.
The instantaneous strain at the time of stress application decreases. The steady-state creep rate increases. The rupture lifetime is diminished. |
The steady-state creep rate increases.
The rupture lifetime is diminished. |
|
For the list below, select four metallurgical/processing techniques that are employed to enhance the creep resistance of metal alloys.
anneal the metal alloy hardening (carburizing, nitriding) or shot peening polishing the surface to remove stress amplification sites dispersion strengthening by using an insoluble second phase solid solution alloying unidirectional solidification of alloys increasing the grain size or producing a grain structure with a preferred orientation. |
dispersion strengthening by using an insoluble second phase
solid solution alloying unidirectional solidification of alloys increasing the grain size or producing a grain structure with a preferred orientation. |
|
For a solution, which of the following is present in the higher concentration?
solvent solute |
solvent
|
|
At a eutectic point on a binary temperature-composition phase diagram, how many phases are present when the system is at equilibrium?
|
3
|
|
A eutectoid reaction involves which of the following phases?
One liquid and one solid One liquid and two solid Two liquids and one solid Three solid |
Three solid
|
|
Match each transformation description below with the name of a corresponding transformation.
Diffusion-dependent with change(s) in phase composition(s) Diffusionless Diffusion-dependent with non change(s) in phase composition(s) |
eutectoid
martensitic recrystalization |
|
Is the net reduction in ferrite-cementite phase boundary area the driving force for the formation of spheroidite?
|
yes
|
|
rank by ductile - brittle
Alloy A: 0.20 wt% carbon, coarse pearlite Alloy B: 0.20 wt% carbon, spheroidite Alloy C: 0.75 wt% carbon, fine pearlite Alloy D: 0.75 wt% carbon, coarse pearlite |
B,A,D,C
|
|
What is the function of alloying elements (e.g., Cr, V, W, and Mo) in tool steels?
The alloying elements in tool steels improve the capacity of these alloys to be heat treated. The alloying elements in tool steels combine with the carbon to form easily melted carbide compounds. The alloying elements in tool steels give rise to a variety of strength-ductility combinations. The alloying elements in tool steels improve the corrosion resistance. The alloying elements in tool steels combine with the carbon to form very hard and wear-resistant carbide compounds. |
The alloying elements in tool steels combine with the carbon to form very hard and wear-resistant carbide compounds.
|
|
Which type of steel has the designation 4330?
Alloy steel Plain carbon steel |
alloy steel
|
|
Which type of steel has the designation 1015?
Alloy steel Plain carbon steel |
plain carbon steel
|
|
What is the carbon concentration of a steel having the designation 1050?
0.01 wt% C 0.05 wt% C 0.10 wt% C 0.50 wt% C Impossible to say |
0.50 wt% C
|
|
Which three elements in the list below are primary alloying elements for the stainless steels?
Silicon Copper Chromium Vanadium Molybdenum Nickel Tungsten |
Chromium
Molybdenum Nickel |
|
Which of the sequences below represents the various steels types in order of decreasing hardness?
Medium-carbon > Low-carbon > High-carbon Low-carbon > High-carbon > Low-carbon Low-carbon > Medium-carbon > High-carbon Medium-carbon > High-carbon > Low-carbon High-carbon > Low-carbon > Medium-carbon High-carbon > Medium-carbon > Low-carbon |
High-carbon > Medium-carbon > Low-carbon
|
|
The successful heat treatment of an alloy steel produces which final phase/microconstituent?
Martensite Pearlite Bainite Tempered martensite Austenite Ferrite |
Tempered martensite
|
|
Which type of steel contains only residual amounts of alloying elements?
Alloy steel Plain carbon steel |
Plain carbon steel
|
|
Which type of forming operation produces a higher quality surface finish, better mechanical properties, and closer dimensional control of the finished piece?
hot or cold working |
cold
|
|
Cold working takes place at a temperature that is below a metal's
Melting temperature Recrystallization temperature Eutectoid temperature Glass transition temperature |
Recrystallization temperature
|
|
Which type of forming operation has lower deformation energy requirements?
Cold working Hot working |
hot working
|
|
Forging operations normally take place at
High temperatures Room temperature Low temperatures |
high
|
|
Hot working takes place at a temperature that is above a metal's
Melting temperature Recrystallization temperature Eutectoid temperature Glass transition temperature |
Recrystallization temperature
|
|
What influence does the presence of alloying elements (other than carbon) have on the shape of a hardenability curve?
It causes a much more rapid decrease in hardness with position from the quenched end. The presence of alloying elements (other than carbon) does not influence on the shape of a hardenability curve. It causes a much more gradual decrease in hardness with position from the quenched end. |
It causes a much more gradual decrease in hardness with position from the quenched end.
|
|
How would you expect a(n) decrease in the austenite grain size to affect the hardenability of a steel alloy?
Increase Decrease Has no effect |
decrease
|
|
Which of the following may occur during annealing?
Toughness may be increased. Stresses may be relieved. A specific microstructure may be produced. Ductility may be increased. |
Toughness may be increased.
Stresses may be relieved. A specific microstructure may be produced. Ductility may be increased. |
|
How does increasing the annealing temperature influence the rate of an annealing process?
Decreases the rate. Increases the rate. |
increases
|
|
How does increasing carbon content influence the hardenability of a steel?
Increases the hardenability. Decreases the hardenability. |
increases
|
|
During a Jominy end-quench test on a plain-carbon steel, the amount of which of the following constituents increases with distance from the quenched end?
Pearlite Bainite Austenite Martensite |
pearlite
|
|
Which of the following correctly represents the sequence of procedures that is used to strengthen/harden a precipitation-hardenable alloy?
Quenching; Solution heat treatment; Cold working; Precipitation heat treatment Cold working; Precipitation heat treatment; Solution heat treatment; Quenching Precipitation heat treatment; Solution heat treatment; Quenching; Cold working Solution heat treatment; Quenching; Cold working; Precipitation heat treatment Cold working; Solution heat treatment; Quenching; Precipitation heat treatment Solution heat treatment; Quenching; Precipitation heat treatment; Cold working |
Solution heat treatment; Quenching
Precipitation heat treatment; Solution heat |
|
The phase diagram for an alloy system that is amenable to precipitation hardening must display which of the following characteristics?
Have an appreciable maximum solubility of one component in another. Have a solubility limit that rapidly decreases in concentration of the solute with temperature reduction. Be for a binary alloy. |
Have an appreciable maximum solubility of one component in another.
Have a solubility limit that rapidly decreases in concentration of the solute with temperature reduction. |
|
An alloy that has been precipitation hardened may be used at elevated temperatures without compromising its hardness and strength.
False True |
false
|
|
The hardening of portland cement is associated with
A chemical reaction involving a compound other than water. A drying process. A chemical reaction involving water (i.e. hydration). |
A chemical reaction involving water (i.e. hydration).
|
|
What is the distinction between glass transition temperature and melting temperature?
They are two temperatures corresponding to specific viscosity values. Glass transition temperature is a characteristic of a noncrystalline material and melting temperature is for a crystalline material. Glass transition temperature is a characteristic of soda-lime glass and melting temperature is for a borosilicate glass. Melting temperature is a characteristic of a noncrystalline material and glass transition temperature is for a crystalline material. |
Glass transition temperature is a characteristic of a noncrystalline material and melting temperature is for a crystalline material.
|
|
Once thermal stresses have been introduced into a ceramic piece, it is impossible to remove them.
T/F |
F
|
|
Which of the following represents the correct phase transformation sequence as a glass material is heated?
Supercooled liquid; Solid; Liquid Liquid; Supercooled liquid; Solid Liquid; Solid; Supercooled liquid Solid; Supercooled liquid; Liquid Solid; Liquid; Supercooled liquid Supercooled liquid; Liquid; Solid |
Solid; Supercooled liquid; Liquid
|
|
The strength of a glass piece may be improved by inducing thermal compressive residual surface stresses.
T/F |
T
|
|
Thermal tempering results in the introduction of
Compressive stresses on the surface. Compressive stresses internally. Tensile stresses on the surface. Tensile stresses internally. |
Compressive stresses on the surface.
Tensile stresses internally. |
|
For the following pair of polymers do the following: indicate if it is not possible to determine if one polymer is more likely to crystallize the other. On the other hand, if it is possible to make such a determination then indicate which of the two is more likely to crystallize.
Not possible Linear, syndiotactic poly(vinyl chloride) Linear, isotactic polystyrene |
Linear, syndiotactic poly(vinyl chloride)
|
|
For the following pair of polymers do the following: indicate if it is not possible to determine if one polymer is more likely to crystallize the other. On the other hand, if it is possible to make such a determination then indicate which of the two is more likely to crystallize.
Network phenol-formaldehyde; linear, heavily crosslinked cis-isoprene |
not possible
|
|
For the following pair of polymers do the following: indicate if it is not possible to determine if one polymer is more likely to crystallize the other. On the other hand, if it is possible to make such a determination then indicate which of the two is more likely to crystallize.
Linear polyethylene; lightly branched isotactic polypropylene |
linear polyethylene
|
|
For the following pair of polymers do the following: indicate if it is not possible to determine if one polymer is more likely to crystallize the other. On the other hand, if it is possible to make such a determination then indicate which of the two is more likely to crystallize.
Alternating poly(styrene-ethylene) copolymer; random poly(vinyl chloride-tetrafluoroethylene) copolymer |
Alternating poly(styrene-ethylene) copolymer
|
|
Which of the following may form linear polymers?
Polystyrene Nylon Rubber Epoxy Polyethylene Phenol-formaldehyde |
Polystyrene
Nylon polyethylene |
|
Which of the following form network polymers?
Polystyrene Nylon Rubber Epoxy Polyethylene Phenol-formaldehyde |
epoxy
phenol-formaldehyde |
|
Match the stereoisomer descriptions with their configuration classifications.
All R groups are on the same side. R groups alternate sides of the chain. R groups are randomly positioned along the chain. |
isotactic
syndiotactic atatic |
|
Is it possible to grind up and reuse phenolformaldehyde?
|
no
|
|
For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, select which is the more likely to crystallize.
Linear and syndiotactic polypropylene Crosslinked cis-isoprene |
Linear and syndiotactic polypropylene
|
|
How do the densities of crystalline and amorphous polymers of the same material and having the same molecular weight compare?
density of crystalline polymer =density of amorphous polymer density of crystalline polymer > Density of amorphous polymer Density of crystalline polymer < density of amorphous polymer |
density of crystalline polymer > Density of amorphous polymer
|
|
During a tensile test on a semicrystalline polymer, once a neck forms in the gauge section of the specimen, continued specimen elongation proceeds by
neck propagation along the specimen gauge length. further neck constriction. |
neck propagation along the specimen gauge length.
further neck constriction. |
|
Significant tensile deformation of a semicrystalline polymer results in a highly-oriented structure.
T/F |
T
|
|
How does annealing an undeformed semicrystalline polymer affect its yield strength?
increases/decreases |
increases
|
|
How does each of the following influence the tensile or yield strength of a semicrystalline polymer?
(a) Molecular weight increase (b) Degree of crystallinity increase (c) Deformation by drawing (d) Annealing of an undeformed material (a) - non-direct influence, (b) - increase, (c) - decrease, (d) - increase (a) - increase, (b) - increase, (c) - increase, (d) - increase (a) - decrease, (b) - increase, (c) - decrease, (d) - decrease (a) - increase, (b) - decrease,(c) - decrease, (d) - increase |
(a) - increase, (b) - increase, (c) - increase, (d) - increase
|
|
Would you expect the tensile strength of polychlorotrifluoroethylene to be greater, the same as, or less than that of a polytetrafluoroethylene specimen having the same molecular weight and degree of crystallinity?
|
greater
|
|
List two molecular characteristics that are essential for elastomers.
(1) Elastomer must not easily crystallize and (2) the lowest temperature at which rubber-like behavior persists is between -50 and -90oC. (1) Elastomers must experience a rise in temperature when stretched and (2) the modulus of elasticity decreases with increasing temperature. (1) For elastomers to experience relatively large elastic deformations, the onset of plastic deformations must be delayed and (2) elastomers must have huge molecular weight. (1) Elastomers must be amorphous, having chains that are extensively coiled and kinked in the unstressed state and (2) there must be some crosslinking. |
(1) Elastomers must be amorphous, having chains that are extensively coiled and kinked in the unstressed state and (2) there must be some crosslinking.
|
|
For the following pair of polymers, decide whether or not it is possible to determine which has the higher tensile strength. If it is not possible, then click on the "not possible" button. If it is possible, then select the one with the higher strength.
Syndiotactic poly(vinyl chloride) with a degree of polymerization of 1000. Atactic poly(vinyl chloride) with a degree of polymerization of 1000. Atactic poly(vinyl chloride) Syndiotactic poly(vinyl chloride) Not possible |
Syndiotactic poly(vinyl chloride)
|
|
For the following pair of polymers, decide whether or not it is possible to determine which has the higher tensile strength. If it is not possible, then click on the "not possible" button. If it is possible, then select the one with the higher strength.
Alternating styrene-butadiene copolymer having a weight-average molecular weight of 750,000 g/mol, with 15% of possible sites crosslinked. Random styrene-butadiene copolymer having a weight-average molecular weight of 500,000 g/mol, with 10% of possible sites crosslinked. |
alternating
|
|
For the following pair of polymers, decide whether or not it is possible to determine which has the higher tensile strength. If it is not possible, then click on the "not possible" button. If it is possible, then select the one with the higher strength.
Branched polyethylene with a number-average molecular weight of 100,000 g/mol. Linear polyethylene with a number-average molecular weight of 80,000 g/mol. |
not possible
|
|
How does increasing the degree of crystallinity of a semicrystalline polymer affect its tensile strength?
|
increases
|
|
How does increasing the molecular weight of a semicrystalline polymer affect its tensile strength?
|
increases
|
|
In order for a polymer to behave as an elastomer, which of the following is (are) necessary?
The polymer must be above its glass transition temperature. Chain bond rotations must be relatively free. The polymer must be below its glass transition temperature. It must crystallize easily. Chain bond rotations must not be relatively free. It must not crystallize easily. |
The polymer must be above its glass transition temperature.
Chain bond rotations must be relatively free. It must not crystallize easily. |
|
As the sulfur content of a rubber increases, its hardness
|
increases
|
|
Which polymerization technique generally has longer reaction times?
Addition polymerization Condensation polymerization |
condensation
|
|
Which polymerization technique is generally used to produce crosslinked and network polymers?
Addition polymerization Condensation polymerization |
condensation
|
|
Why are fillers added to polymers?
To improve tensile strength. To improve compressive strength. To improve toughness. To improve thermal stability. To improve flexibility. |
To improve tensile strength.
To improve compressive strength. To improve toughness. To improve thermal stability. |
|
Why are plasticizers added to polymers?
To improve compressive strength. To improve thermal stability. To improve toughness. To improve flexibility. To improve tensile strength. |
To improve toughness.
To improve flexibility. |
|
Amorphous thermoplastics are formed above their
Softening points. Glass transition temperatures. Melting temperatures. |
GTT
|
|
Which of the following polymer types is more amenable to recycling?
Thermosetting Thermoplastic |
thermoplastic
|
|
For composite materials, which is phase is normally harder?
The dispersed phase The matrix phase |
dispersed
|
|
From the following numbered list of characteristics, decide which pertain to (a) precipitation hardening, and which are displayed by (b) dispersion strengthening.
(1) The strengthening mechanism involves the hindering of dislocation motion by precipitates/particles. (2) The hardening/strengthening effect is not retained at elevated temperatures for this process (3) The hardening/strengthening effect is retained at elevated temperatures for this process (4) The strength is developed by a heat treatment (5) The strength is developed without a heat treatment |
a) 1 2 4
b) 1 3 5 |
|
For an aligned fibrous composite, when a stress is applied in a direction that is parallel to the fibers, what is the reinforcement efficiency?
|
1
|
|
For an aligned fibrous composite, when a stress is applied perpendicular to the fibers, what is the reinforcement efficiency?
|
0
|
|
From the following numbered list of mechanical characteristics, decide which pertain to (a) the matrix phase, and which are displayed by (b) the dispersed phase for fiber-reinforced composites.
(1) Stiff (2) Relatively weak (3) Low elastic modulus (4) Brittle (5) Quite ductile (6) Quite strong |
a) 2 3 5
b) 1 4 6 |
|
For the following pair of alloys that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which alloy will corrode.
brass (60Cu-40Zn) and monel (70Ni-30Cu) |
corrosion unlikely
|
|
Metals near the top of the galvanic series are
Cathodic Anodic Unreactive Reactive |
cathodic
unreactive |
|
Metals near the bottom of the galvanic series are
Cathodic Anodic Unreactive Reactive |
aniodic
reactive |
|
Oxidation of an atom involves the
|
loss of e-
|
|
oxidation takes place at the
|
annode
|
|
Which of the following is/are oxidation reactions?
Fe --> Fe2+ + 2 e- H2 --> 2 H+ +2 e- Al --> Al3+ + 3 e- 2 H+ + 2 e- --> H2 |
Fe --> Fe2+ + 2 e-
H2 --> 2 H+ +2 e- Al --> Al3+ + 3 e- |
|
Reduction of an atom involves the
|
gain of e-
|
|
Reduction takes place at the
|
cathode
|
|
Which of the following are reduction reactions?
H2 --> 2 H+ +2 e- Fe --> Fe2+ + 2 e- Al --> Al3+ + 3 e- 2 H+ + 2 e- --> H2 |
2 H+ + 2 e- --> H2
|
|
Which of the following describes crevice corrosion?
Oxidation and reduction reactions occur randomly over the surface. Corrosion that results from a difference in concentration of ions or dissolved gases in the electrolyte. One element is preferentially removed as a result of corrosion. Corrosion resulting from the combined action of chemical attack and mechanical abrasion or wear. Two metals/alloys of different compositions are coupled while exposed to an electrolyte. Corrosion resulting from the combined action of an applied tensile stress and a corrosive environment. Corrosion that occurs preferentially along grain boundaries. Localized corrosion that may be initiated at a surface defect. |
Corrosion that results from a difference in concentration of ions or dissolved gases in the electrolyte.
|
|
Which of the following describes galvanic corrosion?
Corrosion that results from a difference in concentration of ions or dissolved gases in the electrolyte. Corrosion resulting from the combined action of an applied tensile stress and a corrosive environment. Oxidation and reduction reactions occur randomly over the surface. Two metals/alloys of different compositions are coupled while exposed to an electrolyte. Corrosion resulting from the combined action of chemical attack and mechanical abrasion or wear. Localized corrosion that may be initiated at a surface defect. Corrosion that occurs preferentially along grain boundaries. One element is preferentially removed as a result of corrosion. |
Two metals/alloys of different compositions are coupled while exposed to an electrolyte.
|
|
Which of the following describes pitting?
Corrosion that occurs preferentially along grain boundaries. Oxidation and reduction reactions occur randomly over the surface. Two metals/alloys of different compositions are coupled while exposed to an electrolyte. Localized corrosion that may be initiated at a surface defect. Corrosion that results from a difference in concentration of ions or dissolved gases in the electrolyte. One element is preferentially removed as a result of corrosion. Corrosion resulting from the combined action of chemical attack and mechanical abrasion or wear. Corrosion resulting from the combined action of an applied tensile stress and a corrosive environment. |
Localized corrosion that may be initiated at a surface defect.
|
|
Which of the following describes stress corrosion?
Corrosion resulting from the combined action of chemical attack and mechanical abrasion or wear. Two metals/alloys of different compositions are coupled while exposed to an electrolyte. Corrosion resulting from the combined action of an applied tensile stress and a corrosive environment. Localized corrosion that may be initiated at a surface defect. Corrosion that occurs preferentially along grain boundaries. One element is preferentially removed as a result of corrosion. Oxidation and reduction reactions occur randomly over the surface. Corrosion that results from a difference in concentration of ions or dissolved gases in the electrolyte. |
Corrosion resulting from the combined action of chemical attack and mechanical abrasion or wear.
|
|
Cathodic protection reduces the corrosion rate of a metal when an electrical connection is made to another metal that is
Higher in the galvanic series. Lower in the galvanic series. |
Lower in the galvanic series.
|
|
In most instances, one way to reduce the corrosion rate is to
Decrease the fluid temperature. Increase the fluid temperature. |
Decrease the fluid temperature.
|
|
Galvanizing involves applying a layer of what metal to the surface of steel?
Copper Zinc Iron Nickel Aluminum |
Zinc
|
|
Polymer degradation may occur from exposure to or as a result of which of the following?
Radiation Electrochemical reactions Heat Swelling Physiochemical reactions |
Radiation
Heat Swelling Physiochemical reactions |
|
The swelling of a polymer results in it becoming
Harder Softer |
softer
|
|
olymer deterioration by swelling may be reduced by
Increasing the degree of crosslinking. Decreasing the degree of crosslinking. Increasing the molecular weight. Decreasing the molecular weight. Increasing the degree of crystallinity. Decreasing the degree of crystallinity. |
Increasing the degree of crosslinking.
Increasing the molecular weight. Increasing the degree of crystallinity. |
|
Are energies for electrons that participate in the conduction process (i.e., free electrons) greater or less than the Fermi energy?
|
greater than
|
|
An insulator has an energy band gap that is relatively
narrow. wide. |
wide
|
|
For nonmetallic materials, which of the following is true?
The wider the band gap, the higher the electrical conductivity at a given temperature. The wider the band gap, the lower the electrical conductivity at a given temperature. |
The wider the band gap, the lower the electrical conductivity at a given temperature.
|
|
Which of the following have a significant influence on a material's electrical resistivity?
Grain size Cold work Vacancy concentration Impurity concentration Temperature |
Cold work
Vacancy concentration Impurity concentration Temperature |
|
How do the electrical conductivities of metals compare with those of semiconductors?
σMetals > σSemiconductors σMetals =σSemiconductors σMetals < σSemiconductors |
σMetals > σSemiconductors
|