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15 Cards in this Set

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  • Back

Thermochemistry

The study of the transfers of energy as heat that accompany chemical reactions and physical changes.

Calorimeter

The energy absorbed or released as heat in a chemical or physical change; measurement.

Temperature

A measure of the average kinetic energy of the particles in a sample of matter.

Joules


SI unit of heat as well as all other forms of energy.



Heat

The energy transferred between samples of matter because of a difference in their temperatures.

Specific Heat

The amount of energy required to raise the temperature of one gram of substance by one Celsius degree or one Kelvin.

Enthalpy Change

The amount of energy absorbed by a system as heat during a process at constant pressure.

Enthalpy of Reaction

The quantity of energy transferred as heat during a chemical reaction.

Thermochemical Equation

An equation that includes the quantity of energy released or absorbed as heat during the reaction as written.

Molar Enthalpy of Formation

The enthalpy change that occurs when one mole of a compound is formed from its elements in their standard state at 25C and 1 atm.

Enthalpy of Combustion


The energy released as heat by the complete combustion of specific amount of a substance at constant pressure or constant volume.


Hess's Law

The overall enthalpy change in a reaction is equal to the sum of enthalpy changes for the individual steps in the process.

Entropy

The measure of the degree of randomness of the particles, such as molecules, in a system; defined as "S".

Free Energy

The combined enthalpy-entropy function of a system,

Free-energy Change

At a constant pressure and temperature, the free-energy change, delta G, of a system is defined as the difference between the change in enthalpy, delta H, and the product of the Kelvin temperature and the entropy change, whose denied as T delta S.




delta G = delta H - T delta S