term1 Definition1term2 Definition2term3 Definition3
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ET< ES
Spin selection rule:∆S = 0,
Laporte selection rule:
a change in parity is required, since a photon has angular momentum
electronic spetra are generally broad(due to vibrations and rotations)
-absorptions characterised by Amax and λmax
-Molar extinction coefficient εmax = Amax /c×l - how intense an absorption is
adsorb - hold on surface
absorb - takes in
c = νλ
E = hv = hc/λ = hcv̄
FWHM - full-width at half maximum
axis scale must be directly proportional to energy (not log or anything)
t2g = dxy, dxz, dyz
eg = dx2-y2, dz2
a1g = s
t1u = px, py, pz
eg
t1u
a1g
one band in electronic spectra of Oh d-block complexes except d⁵ high-spin = no bands
works for d¹, d⁴, d⁶,d⁹ (high spin)
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