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34 Cards in this Set

  • Front
  • Back

Alkane to halogenoalkane

Cl2(g) , Sunlight



Via radical substitution


Alkene to bromoalkane

Concentrated HBr (aq), Room temperature


Via electrophilic addition

Alkene to dibromoalkane

Br2, Room temperature, organic solvent


Via electrophilic addition

Alkene to alcohol

H2O (g), Phosphoric acid catalyst, 300 degrees, 50 atm




Concentrated H2SO4 followed by H2O




Via electrophilic addition

Alkene to alkane

H2 (g), Finely divided Ni, 150 degrees, 5 atm




Pt catalyst, room temperature,1 atm




Via electrophilic addition

Halogenoalkane to amine

Concentrated NH3 (aq), Heat in sealed tube




via nucleophilic substitution

Halogenoalkane to alcohol

H2O (l), Slow




NaOH (aq), reflux




Via nucleophilic substitution

Alcohol to ester

R'-COCl or (R'CO)2O, anhydrous conditions




R'-COOH, concentrated H2SO4 catalyst, reflux




Esterification

Alcohol to alkene

Al2O3 (s), 300 degrees




Concentrated H2SO4, reflux




Dehydration

Alcohol to bromoalkane

HBr (aq) ( NaBr (s) + c. H2SO4), reflux




via nucleophilic substitution

Alcohol to chloroalkane

Concentrated HCl

P. Alcohol to aldehyde

Acidified K2Cr2O7, distil

Aldehyde to p.alcohol

NaBH4

Aldehyde to carboxylic acid

Acidified K2Cr2O7, reflux

Aldehyde to cyanohydrin

HCN, alkali

S. Alcohol to ketone

Acidified K2Cr2O7, reflux

Ketone to cyanohydrin

HCN, alkali

Carboxylic acid to carboxylate ion

NaOH (aq)

Carboxylate ion to carboxylic acid

HCl (aq)

Carboxylic acid to ester

R'-OH, concentrated H2SO4 catalyst

Ester to carboxylic acid

Reflux with aqueous acid or alkali

Acyl chloride to ester

R'-OH, room temperature

Acyl chloride to primary amide

Concentrated NH3 (aq), room temperature

Acyl chloride to secondary amide

R'-NH2, room temperature

Primary amide to carboxylic acid

reflux with aqueous acid or alkali

Secondary amide to carboxylic acid

reflux with aqueous acid or alkali

Acid anydride to ester

R'-OH, anhydrous conditions, reflux

Benzene to chlorobenzene

Cl2(g), AlCl3, room temperature, anhydrous

Benzene to nitrobenzene

concentrated HNO3, concentrated H2SO4, < 55 degrees

Benzene to alkylbenzene

R-Cl, AlCl3, reflux, anhydrous

Benzene to acetylbenzene

R-COCl or (RCO)2O, AlCl3, reflux, anhydrous

Benzene to cyclohexane

H2(g), finely divided Ni, 300 degrees, 30 atm

Benzene to bromobenzene

Br2(l), FeBr3, room temperature

Benzene to benzenesulfonic acid

Concentrated H2SO4, reflux