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29 Cards in this Set

  • Front
  • Back
standard heat of formation
the enthalply change for the formation equation when all substances are in their standard states
heat of reaction
the enthalpy change of a reaction
change in enthalpy
the change in internal energy plus the product of the constant pressure and the change in volume
fossil fuel
any fuel, including coal, petroleum, and natural gas, derived from the products of the decay of dead organisms
pressure-volume work
a type of work in which a volume change occurs against an external pressure
formation equation
an equation in which 1 mole of a compound forms from its elements
standard heat of reaction
the enthalpy change that occurs during a reaction, with all substances in their standard states
standard states
a set of specifications used to compare thermodynamic data
Hess's law of heat summation
a law stating that the enthalpy change of an overall process is the sum of the enthalpy changes of the individual steps of the process
thermochemical equation
a chemical equation that shows the heat of reaction for the amounts of substances specified
calorimeter
a device used to measure the heat released or absorbed by a physical or chemical process taking place within it
heat
the energy transferred between objects because of differences in their temperatures only; thermal energy
surroundings
all parts of the univers other than the system being considered
system
the defined part of the universe under study
thermochemistry
the branch of thermodynamics that focuses on the heat involved in chemical reactions
thermodynamics
the study of heat (thermal energy) and and its interconversions
molar heat capacity
the quantity of heat required to change the temperature of 1 mole of a substance by 1 K
specific heat capacity
the quantity of heat required to change the temperature of 1 gram of substance by 1 K
heat capacity
the quantity of heat required to change the temperature of an object by 1 K
endothermic process
one occurring with an absorption of heat from the surroundings and therefore an increase in the enthalpy of the system
enthalpy diagram
a graphic depiction of the enthalpy change of a system
enthalpy
a thermodynamic quantity that is the sum of the internal energy plus the product of the pressure and volume
state function
a property of a system determined by its current state, regardless of how it arrived at that state
exothermic process
one occuring with a release of heat to the surroundings and therefore a decrease in the enthalpy of the system
calorie
a unit of energy defined as exactly 4.184 joules; originally defined as the heat needed to raise the temperature of 1 gram water 1 degree celsius
joule
the SI unit of energy
law of conservation of energy

first law of thermodynamics
a basic observation that the total energy of the universe is constant
work
the energy transferred when an object is moved by force
internal energy
the sum of the kinetic and potential energies of all the particles in a system