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20 Cards in this Set

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freezing-point depression
the difference in temperature between the freezing point of a solution and the freezing point of the pure solvent
boiling-point elevation
the difference in temperature between the boiling point of a solution and the boiling point of the pure solvent
colligative property
a property of a solution that depends only upon the number of solute particles, and not upon their identities; boiling-point elevation, freezing-point depression, and vapor-pressure lowering are colligative properties
- vapor-pressure lowering, freezing-point depression, and boiling-point elevation.Colligative properties of solutions include
Colligative properties of solutions include
Henry’s law
at a given temperature, the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid
supersaturated solution
a solution that contains more solute than it can theoretically hold at a given temperature; excess solute precipitates if a seed crystal is added
immiscible
describes liquids that are insoluble in each other; oil and water are immiscible
miscible
describes liquids that dissolve in each other in all proportions
unsaturated solution
a solution that contains less solute than a saturated solution at a given temperature and pressure
saturated solution
a solution containing the maximum amount of solute for a given amount of solvent at a constant temperature and pressure; an equilibrium exists between undissolved solute and ions in solution
solubility
the amount of a substance that dissolves in a given quantity of solvent at specified conditions of temperature and pressure to produce a saturated solution
stirring, temperature, and surface area
Factors that determine how fast a substance dissolves are...
a state of dynamic equilibrium exists between the solution and any undissolved solute, provided that the temperature remains constant.
In a saturated solution, a state of ________________ exists between the solution and any undissolved solute, provided that the temperature remains constant.
Temperature affects the solubility of solid, liquid, and gaseous solutes in a solvent; both temperature and pressure affect the solubility of gaseous solutes.
Temperature affects the solubility of _____________in a solvent; both temperature and pressure affect the solubility of ____________.
mole fraction
the ratio of the moles of solute in solution to the total number of moles of both solvent and solute
molality (m)
the concentration of solute in a solution expressed as the number of moles of solute dissolved in 1 kilogram (1000 g) of solvent
molal freezing-point depression constant (Kf)
the change in freezing point for a 1-molal solution of a nonvolatile molecular solute
molal boiling-point elevation constant (Kb)
the change in boiling point for a 1-molal solution of a nonvolatile molecular solute
The magnitudes of freezing-point depression and boiling-point elevation are proportional to molality.
The magnitudes of freezing-point depression and boiling-point elevation are proportional to _________.
in molality and in mole fractions.
Chemists use two ways to express the ratio of solute to solvent: in ______________.