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105 Cards in this Set

  • Front
  • Back
Scientists realized that the Rutherford model did not explain:
where the electrons were located in the space around the nucleus
first the Bohr model and then the Quantum Mechanical Model evolved as scientists studied the __________ and ________ of light by matter
absorption and emission
taking in of light by matter
absorption
giving off of light by matter
emission
the studies showed that there is an intimate relationship between _____ and an atom's electrons
light
the studies also showed that light behaves as both _____ and _________
waves and particles
Rhythmic disturbances that carry energy through matter or space
Wave
waves in which the medium moves at right angles to the direction the wave travels
Transverse Waves
Transverse waves do not always need a ______ to carry energy
medium
any material through which a wave can transfer energy
medium
water waves transfer energy through _____
water
Earthquakes transfer energy through _____
earth
light waves are transverse waves that need no ______ to transfer energy
medium
top of a wave
Crest
bottom of a wave
Trough
distance from crest to crest or trough to trough on a wave
wavelength (λ)
distance from crest or trough to the rest position of the medium
amplitude
the # of waves that pass a given point in a second
frequency (ν)
The units for frequency are the _____(Hz), cycles/second(cycles/s) or /second ( /s)
Hertz
speed a wave is travelling
wave velocity
transverse waves produced by the motion of electrically charged particles that travel through space at the speed of light—3.00 x 108m/s
Electromagnetic Waves
Electromagnetic waves are also called _____, _________, _______ ______, _______________ _________ because the waves radiate from the electrically charged particles
light, radiation, radiant energy, electromagnetic radiation
all forms of electromagnetic radiation move at a constant speed of about 3.00 x 10^8m/s through a ______ and slightly slower through ______
vacuum; matter
Since air is mostly space, the value of 3.00 x 10^8m/s is light's approximate speed through ___
air
Light wave velocity can be described by the formula:
C = λ ν
the speed of light, 3.00 x 108m/s
C
the wavelength of the wave in meters
λ
the frequency of the wave
ν
this represents an _______ __________ because if λ goes down, ν goes up and if λ goes up, ν goes down
inverse proportion
Together, all forms of EMR form the _______________ ________
electromagnetic spectrum
The greater the frequency or energy, the greater the ______
danger
The greater the _________, the smaller the __________
frequency; wavelength
radio waves have lowest _________, greatest __________
frequency; wavelength
Radio Waves are used in ____________
communications
used in cooking and communications
microwaves
Microwaves carry energy inside food to make the molecules move ______, heating the food
faster
this is the heat given off by everything on earth, living or not. Used in night vision, many devices such as t v remote controls and organisms such as pit vipers use it to find their prey
infrared
ROY G BIV is a small part of EMR
visible light
- harmful to skin if too much exposure
- helpful—used to treat skin disease, sterilize milk & water
ultraviolet rays
- used to see inside the body
- go through most muscle but are absorbed by bone
X-rays
- highest frequency, shortest wavelength
- most destructive yet some frequencies are used to treat cancer
Gamma rays
In the early 1900's, scientists conducted 2 experiments involving the interactions between light & matter that could not be explained by the ____ ______ __ _____
wave theory of light
___ ______ proposed that hot matter does not emit EMR continuously as would be expected if the light given off were in the form of waves
Max Planck
Instead Plank suggested that the light is given off in small, specific amounts called _____
quanta
_______ is the minimum amount of energy that can be lost or gained by an atom.
Quantum
In student terms, a quantum is a "______ __ ______"
packet of energy
the emission of electrons from a metal when light of a certain frequency shines on it
Photoelectric Effect
Electricity is a flow of _________
electrons
Mystery involved is why it took a certain ________ to work
frequency
If the light striking the metal had enough energy, then the _________ were knocked off
electrons
If the light striking the metal did not have enough ______ then the electrons were not emitted no matter how long the light shone on the metal
energy
It seemed that if light were in waves then any _________ would work to emit the electrons
frequency
Photoelectric effect explained by ______ ________
Albert Einstein
The photoelectric effect was expanded on Planck's theory of the _______
quantum
Said that EMR has a duel ____-________ ______
wave-particle nature
While light has wave-like properties, it can also be thought of as a ______ __ _________
stream of particles
Each particle of light carries a _______ __ ______
quantum of energy
Einstein called the particles _______
photons
a particle of EMR having zero mass and carrying a quantum of energy
Photons
the energy in a particular photon depends on the frequency of the _________
radiation
radio waves have lower frequency than gamma rays so a photon from a radio wave has less ______ than one from a gamma ray
energy
The _________ in atoms absorb energy from EMR
electrons
This increases the energy in the atom's electrons by a certain ______
amount
the relationship between the energy in a photon and the frequency of the radiation is represented by the formula:
E = hν
Amount of energy in the photon expressed in Joules
E
Planck’s Constant or 6.63 x 10^-34 Joules / seconds
h
stays the same
constant
Joules is a SI unit for ______
energy
frequency
v
this represents a ______ __________
direct proportion
If _ goes up, then _ goes up
E; v
If _ goes down, then _ goes down
E; v
the electrons in atoms ______ energy
absorb
Einstein said EMR is absorbed by matter only in:
whole numbers of photons
In order for an electron to be ejected from a metal’s surface, the electron must be struck by a single photon with the minimum energy needed to knock the electron loose. This minimum energy corresponds to a minimum frequency. If the photon's frequency is below the minimum, then the electron stays attached to the metal. Since electrons in different metals are bound more or less tightly, different metals require different frequencies to show the photoelectric effect
note
lowest energy state of an atom
ground state
the ground state is the most ______ state of an atom
stable
In the ground state, electrons occupy the ______ ______ ______ possible and carry the least amount of energy to stay in those levels
lowest energy levels
a state in which an atom has a higher energy state than it has in the ground state
excited state
In the excited state, electrons have ________ energy
absorbed
if electrons gain the right amount of energy, they jump to a ______ _____
energy level
When electrons absorb energy and move to higher Energy levels, the atom becomes ________
unstable
The atom returns to the ground state as the electrons give off the same amount of energy that they absorbed in the form of light (photons)
electron transition
Electrons can change energy levels only with _____ amounts of energy. If it only gains some of the energy it just spins faster and won't change ______ ______
exact; energy levels
Examples of electron transition in everyday include:
- light bulbs
- fireworks
- neon lights
pattern of EMR
Spectra
tool used to the study the structure of atoms and the composition of matter
spectroscope
A spectroscope uses ______ to separate light into a spectrum which can be examined
prisms
A spectroscope bends light different amounts according to its __________
wavelength
There are different types of spectra:
- continuous spectrum
- discontinuous spectrum
one color blends into the next because all frequencies of light within the range are being emitted
continuous spectrum
Each element has its own ____ _________ ________ that is like the element's finger prints
line emission spectrum
formed when excited atoms of an element are formed by passing electricity through its gas or vapor under ___ ________
low pressure
the color characteristic of the element is emitted as the electrons return to the ______ _____
ground state
Passing the color emitted by the element through a spectroscope produces the ____ _________ ________ for the element
line emission spectrum
We see narrow bands of color that correspond to the wavelengths of visible light given off by the element as it undergoes ________ __________
electron transition
There are also bands of _____ between the visible colors. These bands represent areas where no light is being emitted. Bands in the ___________ and ________ ranges are sometimes detected but not seen because they are not in the visible range
black; ultraviolet and infrared
Scientists studied the line emission spectrum for hydrogen first. As they tried to explain why not all colors were visible, they devised the _______ _________ _____ of the atom
quantum mechanical model
Bohr linked the atom's ________ with ______ _________
electron; photon emission
electrons circle in ______
orbits
electrons closest to the _______ have least amount of energy
nucleus
the farther the electron is from the nucleus, the _______ energy it has
greater
If an electron gains the right amount of energy, it can move to a ______ ______ _____
higher energy level
The electron has to gain the amount of energy equal to the difference between the higher-energy orbit and the initial lower-energy orbit. Based on the wavelengths of hydrogen's line emission spectrum, Bohr calculated the energies the electrons would have in the various energy levels.
note
It was soon realized that Bohr's model didn't explain the ____ _________ ______ for atoms with more than one electron and did not explain how chemical reactions occur
line emission spectra