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55 Cards in this Set

  • Front
  • Back
Distinguish between an atom, molecule, element and compound
Element- simplest form of a substance, one or more of a single type of atom

Molecule- two or more chemically bound atoms

Compound- two or more different types of atoms
Difference between Law & Theory
Scientific laws descibe observations, they don't explain them. Theories provide an explanation which incorporates facts, laws, inferences, & tested hypotheses
Avogadro's Number Equals...
One mole - which is the number of atoms or molecules present in a sample of an element or compund with a mass equal to its atomic or molecular mass expressed in grams

6.02 * 10^23
What is Atomic Mass?
The mass of one mol of each particular atom

Units in g/mol

1 mol N atoms = 14g
1mol Pb atoms = 207.2g
Calculate the Mm of H2O
(2*1 g/mol)+(1*16 g/mol) = 18g/mol
Conversion Process
Grams of a Substance ⇆ Moles of a Substance ⇆ Number of Particles

(150g of S_8 ⇆ 0.6 mol S_8 ⇆ 3.6*10^22 molecules of S_8)
O2 = How many mol oxygen molecule?

How many mole of oxygen atom?
1 mol oxygen molecule

2 mol oxygen atom
Limiting Reactant
The reactant which is used up completely in a reaction. The other is in excess.
(A/Z) X ^n

What do A, Z, & n represent?
(A)=Mass number - # of protons +# of neutrons

(Z)=Atomic number - # of protons (often omitted)

(n)=charge ( - or + )
Isotope
atoms that have the same number of protons (are the same element) but have different number of neutrons
Cations
ions with more protons than electrons

#p > #e

Na - e- → Na+
Anions
ions with less protons than electrons

#p < #e

Cl + e- → Cl-
Element. List some examples
A substance is composed of identical atoms. Gold, silver, oxygen, hydrogen, lead, chlorine, helium, iron, copper, fluorine, arsenic
Compound. List some examples
substance composed of two or more elements chemically combined. Water - H2O; Salt - NaCl; Sugar - C6H12O6; Ammonia - NH3
Atomic Number: What are the atomic numbers of helium, hydrogen, carbon, oxygen?
The number of protons in the nucleus of an atom of an element. Helium-2; carbon-6; hydrogen-1; oxygen-8
Mass number
The sum of protons plus neutrons n the nucleus of an atom
Molecule
A group of two or more atoms held together by chemical bonds
Ion (provide examples)
An atom or group of atoms which contains a positive or negative electrical charge (ex. Na+; Cl-; SO4^2-)
Cation and Anion (provide examples)
cation - positively charged ion (Na+; Fe+2; NH4+; Ag+); anion - negatively charged ion (Cl-; SO4-2; OH-; P-3)
Valence electroncs
The electrons found in the outermost energy level of an atom
Oxidation number
A number (positive or negative) representing the charge on an ion or atom involved in a chemical bond
Three general rules for determining oxidation numbers
1) Atoms of uncombined elements equal 0; 2) Hydrogen = +1 (in metallic hydrides =-1); 3) Oxygen = -2 (in peroxides =-1); (bonded with fluorine =+2)
Positive Ion: which elements tend to form them?
Metals tend to form positive ions by losing electrons (Na → Na+ e-)
Negative Ion: which elements tend to form them?
Non-metals form negative ions by gaining electrons (Cl +e- →Cl-)
Atomic Mass
A weighted average mass of the atoms of an element (assuming the carbon-12 isotope is exactly 12) (ex. Atomic mass of C=35.45 is calculated from two isotopes. Cl-35 and Cl-36)
For any substance, write a general formula to convert from Moles to Grams
g=(n)(MM) where, n = moles MM = molecular mass g = grams
For any substance, write a general formula to convert from Grams to Moles
n = g/MM; n = moles; MM = molecular mass; g = grams
For any substance, write a general formula to convert from Moles to Number of Particles
(n)(6.02x10^23) = P; n = number of moles; P = number of particles
For any substance, write a general formula to convert from Number of Particles to Moles
n = P/6.02x1023; n = number of moles; P = number of particles
Reactants; Products
1) The starting materials in a chemical reaction; 2) The substances formed in a chemical reaction
Balance Equations: H2 + N2 ↔ NH3; NaCL + Br2 ↔ NaBr + Cl2
1) 3H2 + N2 ↔2NH3; 2) 2NaCl + Br2 ↔2NaBr + Cl2
Period
A horizontal row of elements in the periodic table. All have the same number of shells of e-. Across the period, the elements' properties change.
Column or Family
A verticle group of elements on the periodic table in the same column. They have similar properties and the same number of valence electrons.
Describe the change in atomic radius across the periodic table
The atomic radius tends to decrease from left to right across the table and increase down the columns
Ionization energy
The energy change required for the removal of the outermost electron from the gaseous atom to form a +1 ion
Describe the change in Ionization Energy across the periodic table
Ionization energy tends to increase from left to right across the table and decrease down the columns
Quantum Number
A number used to describe the energy levels available to an electron. Each electron in an atom has a unique set of four.
Ground State
Electron is at its lowest energy level as close to the nucleus as possible
Excited State
An electron absorbs energy and moves to a higher energy level above the ground state
List the names of the four sublevels and their electron capacities
sublevel s holds two electrons; p holds 6; d holds 10; f holds 14
Which sublevels are present in energy levels 1, 2, 3, and 4-7?
1: s; 2: s, p; 3: s, p, d; 4-7: s, p, d, f
Describe the shapes of the orbitals: 1) s; 2) p; 3) d; 4) f
1) s- sphere; 2) p - dumbbell shape with 2 lobes; 3) d - double dumbbell; most have 4 lobes; 4) f - most have 8 lobes
What is the order for filling sublevels (aufbau process) from lowest to highest energy
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d
Electron configuration
The distribution of electrons into shells and sublevels for an atom of an element. Each element has a unique electron configuration.
Valence
The number of electrons in the atom's highest numbered shell.
List the four steps of the scientific method
1. observation & collection of quantitative or qualitative data

2. formulation of a hypothesis to explain the observation

3. prediction based on the hypothesis

4. testing the prediction
Nature seeks a position of _________energy and favors a change in E that is __________
Lowest

Negative
Electromagnetic Force
When charged particles are brought together, the are either attracted, or repelled by each other
Coulomb's Law
Energy = Force * Distance

E ~ q1q2 / r
For attractive forces, E is _________
Negative
For repulsive forces, E is ___________
Positive
When a proton and an electron move apart, there is a(n) _______ in energy
Increase
All waves travel at ___________
The speed of light

(c) = 2.998 * 10^8 ms^-1
Long wavelength =

______________ frequency

&

_________________ energy
Low
short wavelength =

_________ frequency

&

___________ energy
High