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19 Cards in this Set

  • Front
  • Back
The process of solute particles being surrounded by solvent particles is known as______.
Solvation
Pairs of liquids that will mix in all proportions are called _____ liquids
Miscible
The mole fraction of He in a gaseous solution prepared from 4.0 g of He, 6.5 g of Ar, and 10.0 g of Ne is ___________
.60
The morality of urea in a solution prepared by dissolving 16g of urea (MW=60.0 g/mol) in 39 g of H2O is _________M. The density of the solution is 1.3 g/mL.
6.3
A solution containing 10.0 g of an unknown liquid and 90.0 g water has a freezing point of -3.33°C. Given for water, the molar mass of the unknown liquid is
62.2
A saturated solution________
contains dissolved solute in equilibrium with undissolved solute.
An unsaturated solution is one that __________.
has a concentration lower than the solubility
Pressure has an appreciable effect on the solubility of __________ in liquids.
gases
A solution contains 28% phosphoric acid by mass. This means that __________.
100 g of this solution contains 28 g of phosphoric acid
A solution is prepared by dissolving calcium chloride in water and diluting to 500 mL If this solution contains 44 ppm chloride ions, the concentration of calcium ions is __________ ppm.
22
As the concentration of a solute in a solution increases, the freezing point of the solution __________ and the vapor pressure of the solution __________.
decreases, decreases
Calculate the vapor pressure of a solution made by dissolving 109 grams of glucose (molar mass = 180.2 g/mol) in 920.0 ml of water at 25°C. The vapor pressure of pure water at 25°C is 23.76 mm Hg. Assume the density of the solution is 1.00 g/ml.
23.48 mm Hg
Adding a nonvolatile solute to a solution decreases the vapor pressure of the solution. (T/F)
True
The osmotic pressure of a solution formed by dissolving 25.0 mg of aspirin (C9H8O4) in 0.250 L of water at 25°C is __________ atm.
.0136
Consider the following reaction:
3A -> 2B
The average rate of appearance of B is given by Δ[B]/ Δt. Comparing the rate of appearance of B and the rate of disappearance of A, we get Δ[B]/ Δt=_____x (-Δ[A]/Δt).
2/3
If the rate law for the reaction:
2A + 3B -> products
is first order in A and second order in B, then the rate law is
Rate law is equal to k[A][B]2
The kinetics of the reaction below were studied and it was determined that the reaction rate increased by a factor of 9 when the concentration of B was tripled. The reaction is __________ order in B.
A+B ->P
second
The rate of disappearance of HBr in the gas phase reaction:
2HBR (g)-> H2 (g)+ Br2 (g)
is 0.301 M s-1 at 150°C. The rate of appearance of Br2 is __________ M s-1.
.151
The decomposition of N2O5 in solution in carbon tetrachloride proceeds via the reaction
2N2O5 (soln) -> 4NO2 (soln) +O2 (soln)
The reaction is first order and has a rate constant of 4.82 x 10-3 s-1 at 64°C. If the reaction is initiated with 0.058 mol in a 1.00-L vessel, how many moles remain after 151 s?
.028