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25 Cards in this Set

  • Front
  • Back

kinetics

is the study of reaction rates and of the mechanisms, or bond breaking and making processes

rate equation

shows the mathematical relationship between the individual reactant concentrations and the reaction rate.

reaction order

the relationship between increasing reactant concentrations and the reaction rate increasing or decreasing is expressed as an exponential term refers to what?

rate constant

is a proportionality constant that varies only when the reaction temperature changes.

overall reaction order

is the sum of the orders of the individual reactants.

percent transmittance

is the measure in percentage of light that passes through a given solution. When you have all light passing through solution, you have 100% when partial light is absorbed, you have less than 100%.

analytical wavelength

is the wavelength at which percent transmittance is lowest. this solution at the wavelength is most sensitive which is used for analysis.

concentration of absorbing substance




path length of light through the solution




molar absorptivity

what are three variables that influence specific responses of the solution, regarding spectrophotometric analysis?

Beer's law

the product of three variables used the calculate absorbance A is known as

reference solution

is used to compensate for interference when calculating absorbency. it contains all the components of the solution except the species being determined.

cuvettes

type of test tube used to analyze the absorbency of a solution.

beers law plot

a graph that is plotted and represents absorbence versus concentration.

at equilibrium

when there is no further change in the concentrations of either reactants or products we say the reaction is ............

titration

is the addition of a chemically equivalent volume of a solution of known concentration, called a standardized solution, to the solution of unknown concentration being analyzed.

titrant

the ........ is the standardized solution being added to our buret.

strong

in ........... acids, virtually every molecule dissociates, releasing a hydrogen ion to a water molecule, producing hydronium ion.

equivalence point

the neutralization of a reaction is complete at this point. meaning, the number of moles of your titrants equals the number of moles of your solution your analyzing.

weak

in ........ acids, only a small percent of acid molecules dissociate to produce hydronium ion.

solubility product constant

the equilibrium constant for solids dissolving in a solvent is termed the....

reduction reaction

chemical species gains the electrons lost by another chemical species in the oxidation process.

oxidation reaction

uncombined elements have lost electrons to form ions.

spontaneous

we say a redox reaction is ......... if the electron exchange occurs without outside influence.

galvanic or voltaic

when you physically separate out the half reactions , we can cause the electrongs to flow throughan external circuit. this system is known as a ............cell

electrolytes

are composed of solvated ions and can conduct an electric current.

salt bridges

contain a non interfering electrolyte.