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39 Cards in this Set

  • Front
  • Back
more readily form pi bonds
first element of each group
making hydrogen
Strong acid and metal
Methane and water
Carbon and Water at 1000 C
Electrolysis of water
Electrolysis of brine
Strong acid and metal
2M+2HX->2MX+H2
Methane and water
CH4+H2O->3H2+CO
CO+H2O->CO2+H2
Carbon and Water at 1000 C
C+H2O->CO+H2
Electrolysis of water
2H2O->2H2+O2
Electrolysis of brine
NaCl+H2O->NaOH+Cl2+H2
Halogens are good reductants or oxidants?
Oxidants
Hydrogen Isotopes
Protium 1/1H
Deuterium 2/1H
Tritium 3/1H
How noble gases form compounds
Unfilled d-orbitals
How do inner halogen compounds react
oxidizes the anions of the halogens below it on the periodic table
Br2 +2I- -> 2Br - +I2
Are inner halogen compounds reactive?
yes highly reactive
How to make halogen hydrides
including exceptions
salt + H2SO4 -> H-halide + XSO4
exceptions: I, Br
use H3PO4 instead
How to make oxygen
Photosynthesis:
CO2+H2O+light -> C6H12O6 + 6O2
Lab prep
KClO3 -> KCl + O2
Naming oxyacids
HClO hypo- -ous +1
HClO2 -ous +3
HClO3 -ic +5
HClO4 per- -ic +7
Nonmetal reactivity
Metal reactivity
Nonmetals form covalent oxides
Most metals form ionic oxides
Peroxides
H2O2
-1 Oxidation state
Superoxides
NaO2
-1/2 Oxidation state
Ostwald process
4 NH3 (g) + 5 O2 (g) -> 4 NO (g) + 6 H2O (g)
2 NO (g) + O2 -> 2 NO2 (g)
2 NO2 (g) + H2O (l) -> 2 H+ + 2 NO3- (aq) + NO (g)
Ammonia with bleach
NH3 + OCl- -> NH2Cl
PCl3
PCl5
P+Cl2 -> PCl3
PCl3+ Cl2 -> PCl5
CO2 production
Carbon combustion
C (s) + O2 (g) -> CO2 (g)
Baking
Solubility in water
Baking- CO2 production
NaHCO3 (s) + H+ (aq) -> Na+ (aq) + CO2 (g) + H2O (l)
Solubility in water- CO2 production
CO2 (g) + H2O (l) -> H2CO3 (aq)
Carbonate reactivity
Dissolving minerals with acids:
CaCO3 (s) + 2 H+ (aq) -> Ca2+ (aq) + H2O (l) + CO2 (g)
Metallurgy
the science of extracting metals from their natural sources and preparing them for practical use.
pyrometallurgy
add heat
using heat to alter minerals to reduce metals.
electrometallurgy
use of electric and electrolytic processes to purify metals or reduce metallic compounds to metals.
hydrometallurgy
Using aqueous reactions to extract metal
blast furnace
Iron oxide ores in
Coke (carbon) = fuel
Limestone facilitates slag
Calcination –
using heat to release volatiles
PbCO3(s) -> PbO(s) + CO2(g)
Roasting –
using heat and reducing gases
PbO(s) + CO(g) -> Pb(l) + CO2(g)
Smelting
equation
Process of producing molten metal & slag
CaO (i) + SiO2 (l) -> CaSiO3 (l)
Slag
molten silicate materials
Down's cell
liquid Na, gaseous Cl2
Hall Process
makes molten aluminum
electrometallurgy
Electron-Sea Model
Metals can be thought of as cations suspended in a “sea” of valence electrons.
Attractions hold electrons near cations, but not so tightly as to impede their flow.
3 types of magnetism
diamagnetism
paramagnetism-unpaired d electrons
ferromagnetism-iron
alloy
mixtures of two metals