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10 Cards in this Set

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  • Back

In optical activity, what does it mean if the light rotates?

A chiral molecule is present

In optical activity, what is observed rotation?

The plane of rotated light due to the action of the 3-D molecule

In optical activity what does (+) mean?

Clockwise rotation

In optical activity what does (-) mean?

Counterclockwise rotation

In optical activity what does optically inactive mean? (2)

1)Equal mixture of R & S


2) Or there is no chrial molecule present

Diastereomer characteristics (3)

1) Stereoisomers that are non-superimposable mirror images


2)Opposite configuration at some stereo centers


3)In molecules with multiple stereos center

Meso compounds characteristics (3)

1) Multiple stereo centers yet achiral


2)Look for line of symmetry


3) Superimposable mirror image

Chiral Molecule Characteristics (3)

1) Non-superimposable mirror image


2) Stereocenter


3) R,S,(+),(-)

Stereoisomer

Same connections but different 3-D structure

Are axial or equatorial bonds less stable?

Axial