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60 Cards in this Set

  • Front
  • Back
Compare the acidity of HCl and HF based on the electronegative and atomic size of fluorine compare to chlorine?
HCl is more acidic because fluorine is a smaller atom than chlorine. This higher acidity is not related to electronegativity because fluorine is actually more electronegative than chlorine.
What pH is required to consider something a strong base?
pH greater than or equal to 13.
Poiseuille's law
As the pressure difference across a pipe decreases so does the volume flow rate.
Continuity Equation: Definition
The continuity equation says that as the amount of fluid flowing into a narrow and wide region are the same. Therefore, for the volume flow rate to be conserved, as the cross sectional area of a pipe decreases the velocity of the liquid must increase.
Bernoulli's Principle
As the average speed of a fluid increase the pressure the fluid exerts against the walls decreases. This is attributed to less collisions with walls of the tube.
In a graph of fraction of molecules at a certain kinetic energy vs. kinetic energy, what is the area under the graph?
The area under the graph represents the total number molecules, and this would not change with increasing temperature.
Is the favorability of a reaction related to its kinetics or thermodynamics? How the actions of a catalyst?
The favorability of a reaction is related to the relationship between the products and reactants, so it's based on thermodynamics. In contrast, the actions of a catalyst are related lower the energy of the transition state.
If a oxidation reaction is favorable, would it have a positive or negative voltage for oxidation (or its oxidation potential)? What about it reduction potential?
It would have positive oxidation potential and a negative reduction potential. The reactant is easily oxidized or loses electrons.
Conduction
The transfer of kinetic energy through direct contact with a solid.
Convection
The transfer of kinetic energy through fluid medium whose individual molecules are capable of translational motion.
Radiation
Transfer of electromagnetic energy in the form of waves or particles.
When is the acceleration on a pendulum the greatest?
When the force of gravity on the pendulum is the greatest, which is when it's farthest from the ground.
If the velocity of an ion slows down as move into a magnetic field, how does this impact the radius? What is the formula that shows this relationship?
As the ion slows down, the force decreases, and the radius of the path becomes smaller.

The formula that shows this relationship: r = mv/qb
How many electrons are removed when two particles collide energetically?
At least one electron is removed.
How do you calculate the velocity of a charge particle accelerated through a potential difference of V?
PE = KE = qV; v = sqrt(2qV/m)
In what direction, are cations accelerated across a potential difference? How about anions?
Cations are accelerated form high voltage to low voltage. Anions are accelerated from low voltage to high voltage.
How can be describe the bonds broken and formed in an endothermic reaction?
The bonds broken are of a higher energy than the bonds formed.
If an object weights 5000 N on earth, how much would it weight a distance of 6 * earth radius away?
It would decrease by a factor of r squared or about 50 times. The weight would be 100 N.
Gay-Lussac's law
At constant volume, the change in temperature is directly proportional to a change in pressure.
Where is the focal point for nearsighted person? Farsighted person?
For a nearsighted person, the focal is in front of the retina because either the eyeball is too long or the cornea's curvature is too pronounced. For a farsighted person, the focal point is behind the retina because either the curvature is too small or the eyeball is too short.
How do the kinetic energy of gases differ at the same temperature? How about their velocity and rate of effusion?
At the same temperature, all gases have the same kinetic energy. Therefore, the only difference in velocity comes from differences in their masses. The lighter the gas, the faster its velocity, and rate of effusion.
The heat of fusion is related to which state? The heat of vaporization is related to which state?
Heat of fusion is associated with freezing point. The heat of vaporization is association with boiling point, and increases as the boiling point increases.
How is the heat capacity of gas changing if as it cools it releases less heat at higher temperatures?
That would that as temperature increases, the objects heat capacity decreases.
How does the density of air change with temperature?
The lower the temperature the denser, the tenser the air.
How is density of the air related to the index of refraction?
As the density increases, the index of refraction increases, and the object slows down more.
What kind of image is produced by a concave mirror for an object that lie beyond its focal length? Why is the image smaller?
Real, inverted. The image is smaller because because the image significantly closer to the mirror than the object.
What is the most important factor to consider in deciding how efficient a mixture will be in isolating isotopes in an effusion tube?
The most separation will come from the greatest velocity ratio, which is inversely proportional on the square root of the masses. Therefore, the greater the difference in the masses of the mixtures, the greater the velocity difference, and the more efficient the separation of the isotopes.
What can said of two gases that collide with the same force on the walls of a container?
They have the same momentum.
Two gases with different masses at the same temperature share what factors and have what factors different?
They have the same kinetic energy and pressure. The lighter has a greater velocity. The heavier exerts a greater force on the walls of container, and has a greater momentum.
What is the most important factor to consider in deciding how efficient a mixture will be in isolating isotopes in an effusion tube?
The most separation will come from the greatest velocity ratio, which is inversely proportional on the square root of the masses. Therefore, the greater the difference in the masses of the mixtures, the greater the velocity difference, and the more efficient the separation of the isotopes.
What causes lift?
Lower pressure above a surface than below the surface due to a faster air flow above than below. At lower speed, there are more collisions, and therefore greater pressure.
What are the two major forces at play in a pendulum? Which one is considered the restoring force? Do they vary? When are they maximum and minimum?
The two major forces are the the tension and gravity. The force of gravity is constant, although its components vary. The tangential component of gravity is the restoring force. Tension varies and is greatest at the bottom of the swing and lowest at the greatest height.
What is the normal boiling point?
The boiling at which there is equal chance of the object existing as a gas or a liquid at 1 atm.
In carbon dating, what would cause a reading of an artifacts age to come out younger than the actual age of the object?
If another object is also emitting beta particle because it's undergoing beta decay. This make it seem like there's more carbon 14 in the artifact, less nitrogen 14, and the age of artifact is younger than its actual age.
How does thermal conductivity relate to the dissipation of heat? For example, what kind thermal conductivity would want in an organ that struck by X-ray?
The greater the thermal conductivity, the greater the dissipation of heat. Therefore, we would want high thermal conductivity in the organ, in order to make sure the energy to transferred would dissipate as heat.
Where is the best application of X-ray? How about Ultrasound?
X-rays are best applied when there are difference in the densities of the tissue. An example of this is bone. Meanwhile, ultrasounds are used for fetal positions and blood flow.
What are the reactant and products of a reduction potential equation?
The reactants are cations and electrons, and the products are solids and neutral.
What determines how much an impurity will elevate the boiling point? What kind of property is this? What other physical properties share this characteristic?
The number of particles the compound forms in solution. The greater the number of compounds, the greater the elevation. This explains why MgCl2 elevates the boiling point more than ethanol or NaCl. Since the boiling point elevation only depends on the number of solute particles in a given volume, it is consider a colligative property. Similarly, freezing point depreciation is also considered a colligative property.
Let's consider a converging lens. Where in relationship to the focal point of the lens can we place an object if we want a virtual image? How will the image compare in size to the object? Where in relation to the focal point would we place an object if we wanted a real image? How would the size of the image compare to the object? Finally, how does the size of the image change as the object approaches the converging lens?
To produce a virtual image we need to place the object between the focal point and the lens. The virtual image would be farther to the left of the object (on the same side), which explains why the image must be bigger than the object. In contrast, to produce a real image we need to place the object behind the focal point. For a real image as the object approaches the lens, the image gets larger, while the virtual image gets smaller as the object approaches the lens.
A dead giveaway that a reaction is endothermic?
Bonds in the reactants are broken, but no new bonds have been formed.
If a compound has a higher vapor pressure then what can we conclude about its heat or enthalpy of vaporization and boiling point? What determines the melting point?
It has a lower heat/enthalpy of vaporization and a lower boiling point. The melting is determined by the size of the molecule most significantly, and secondly by intramolecular interactions.
In gel electrophoresis, or any other charge capacitor, how are the plates define? How is this different than a discharging system? What is the classical example of a discharging system?
In a charged system, like gel electrophoresis, the plates are defined by the charge that has built on them. Therefore, the anode of the battery forces electrons to build on the cathode (defining it as NEGATIVE), while leaving a lack of electrons at the anode (defining it as POSITIVE). Meanwhile for a discharging system, like an electrochemical cell, we can think of the mnemonic RED cat, OX an. The cathode is the sight of reduction, while the anode is the sight of oxidation. Therefore, the electrons would move from the sight of oxidation, the cathode, to the sight of reduction, gain of electrons.
Simple question, what is meant if we say an electron has a kinetic energy 1 eV?
The amount energy that is an electron gains when it moves through 1 volt potential difference.
How much will volume will one mole of an ideal gas at STP occupy?
22.4 L
In what electron orbital are the interacting electrons of a transitional metal?
The electrons in the d orbital, because they are at the highest energy.
If two waves form a standing wave like pattern, what can be said about their relationship? What would be the distance between two adjacent nodes in the standing wave?
The two ways would be traveling in opposite directions with equal magnitude. The distance between two adjacent nodes would be half of a wavelength.
What is a monochromatic light? What is a coherent light source? What is an example? What kind of light source are normal light bulbs?
Monochromatic light is light of a single frequency. A coherent light source emits light that maintains a phase difference. Both of these properties can be seen in lasers. In contrast, light bulbs emit have intrinsic irregularity in the way they produce light. Since excitation occurs in random manner, the light they produce don't maintain a distinct phase difference.
What can be said about the solubility of nitrates and sodium salts?
Nitrates and sodium salts are both always water soluble.
How is the probability of an X-ray emission event at a given wavelength measured?
The intensity is the measure how probable an X-ray emission is at a given wavelength.
How does the voltage of a device in parallel differ from the voltage of a single device? How about a a device in series?
If the devices are in parallel, then the total voltage would be the same. Meanwhile, if the voltage for devices in series are summed.
What must be true about the relationship between the photon energy (hf) and the work function in order to liberate an electron?
The photon energy (hf) must be greater than the work function. This gives us a positive value for the kinetic energy of the photon.
How does the oxidation # of sulfur change in going from sulfuric acid to sulfur dioxide?
The oxidation number is reduced from +6 to +4.
How does the rate of change in volume alter as you descend into water?
The greatest change in volume comes occurs initially, as you descend more the change in volume caused by the change pressure decreases.
If two balls are shout up with the same velocity but in different directions, what can be said about their flight time? How about their apex? How about their final velocity?
The ball that is shout up with more vertically will travel a greater distance vertically. Therefore, it will be in the air longer, and have a longer travel time. Both balls, however, will have the same final velocity because conservation of energy.
How does the presence of ammonia affect the bond between an electrophile and a leaving group? What kind of role is ammonia playing?
Ammonia acts as an electron donating group. The donation of electron density to the electrophile weekends the bond between the electrophile and the leaving group, which increases the reactivity of the leaving group.
What is the coordination number?
# of ligands a metal is attached to
How does the speed of sound wave compare to the speed radio wave?
Radio waves are electromagnetic waves, and therefore sound waves are much slower.
What is meant by a saturated solution of salt?
A solution that holds the maximum number of salt ions without the formation of a precipitate.
What do waves transport?
Waves transport energy, but not matter because they are local oscillations of material, and do not move very far from the equilibrium position.
Where is the image formed from a plane mirror?
The image is formed behind the mirror at a distance equal to the distance between the object and the mirror.