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52 Cards in this Set

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  • Back
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Residues


Oligopeptides


Polypeptide


Alpha carbon


Absolute configuration L/D.. human animo acids are ?

R GROUP determines what?


Substrate binds depends on?


Folds?


Reaction mechanism?


Animo acid flash cards!

Pka of side chains. Low to high?


Cooh


Acidic


His


NH3+


Basic



Essential vs non essential amino

Zwitterion

Isoelectric point


Peptide bind formation In animo acids


N and c terminus


Resonance?

Affects on amino acids


Strecker synthesis


Gabriel synthesis

Cleave protiens on the carboxylic side

Protein structure


Primary


Secondary


- alpha vs beta


Tertiary


Quatinary

Globules


Molten mobile


Molten


Hydrophobic core


Hydro surface


Electrostatic interaction


Hydrogen bonds


Disulfide bonds

Salt bridges


Proline turns


Salvation later


Entropy and folding

Isoelectric point and electrophoresis


Protien separation

Actin , tubulin, keratin, elastin


Myosin, kinesis, dyneins

Oxidoreductases


Transferases


Hydrolases


Isomerases


Lyases


Ligases


Mnemonic

Cofactors


Coenzymes


Prosthetic


Simple vs conjugated -example

Fat soluble vitamins


Mineral vs vitamin

A,d,e,k

Michaelis menton kinetics


Equation


V =


Km=

Lineweaver-burk plots


Y and X intercepts


Enzyme inhibition

Inhibition (vmax and Km)


Competove


Uncompetitive


Non competitive


Mixed

Ose


Deoxy


Aldose vs ketose


Glucose


Fructose


Galactose


Lactose


Maltose


Sucrose



Other common sugar names?

Man nose- RRLL

Pyranose vs furanose


Hemiacitals vs hemiketals


D vs L


A vs b


Anno vs epimers

Intramolecular nuclophilic substitution in ring closing (Fisher to ring)



Keto-enol tautomerism if monosaccharides



Polymerization, a and beta linkage



Glycogen, starch, cellulose

Lipids


2 characteristics


3 types (sat vs unsat as well) - found in body. Not eat. Lol

Triaglycerols and phospholipids


Steroids


Autocribe vs paracribe

Amino acids flash cards plz!

Should be in there esomehwre

Bioenergetics and thermodynamics?


Why do living this contains non equalibrium ?


Delta G? For reactions?

Dynamic steady state


How is equilibrium dif from steady state?


Delta G equals ?

Physiological conditions?


Ph?


Delta g and delta g prime?


When is a reaction. At this?


Delta G = (equation)


How does KEQ relate?

Endergonic ?


Exergonic?

ATP


delta G for ATP


Cyclization does?


ATP -> ADP delta G and?


Amp to camp is?


Atp formation


Substrate level ?


Location ?



Oxidative phosphorylation?


Location ?

Consumption of ATP


Hydrolysis?


Phosphoryl group transfer?


Phosphorylation using stp?

Bio Redox reactions?


Half reaction?


What makes you think Redox?

Carbohydrate metabolism ?


Def?


Respiration ?


Glycolysis?... know the whole things . You have other flashcard set. Do it.


Glycogen metabolism


Fructose metabolism


Galactose metabolism

Fermentation (anaerobic glycolysis) ?


Ethanol fermentation ?


Lactic acid fermentation ?


Why is it important?

Gluconeogesis , where at?


Penrose phosphate pathway?


2 things to think?


NADPH? how important?


R5-P? Used how?

Oxidative phase ?


Non oxidative phase ?

Pdh complex?


Pyruvate 3 destination ?

Citric acid cycle?


Acetyl-coa


Know cycle ?


Diagram?


Energetic steps?

2 per glucose


Per 2 glucose:


1 atp


5 NADH


1 FAD2h


2 co2


ETC ?


Ox-phos?


ATP per NADH and FADH2?

BIOchemical shuttles?


Malate-aspartate? . How does NADH pass through the inner mitochondrial?


Glycerol - 3- phosphate?


How dies get In?

Carnitine shuttle?


Citrate - acetyl coa shuttle?

ATP synthesis ?


Ox-phos ?


Chemiosmotic coupling?


Uncoupling?


Proton motive force?

Regulation of carbohydrates metabolism?


Alltostic control?


3 things ?


Allosteric enzymes?


Allosteric regulation?

Hormonal control? .4 metabolism hormones?



Glucocorticoids ... most significant ex?



Catecholamines?



T3 and t4?


1 more?

Beta oxidation if fatty acids?


Location?


How they get into the mitochondria ?


How it happens? (Think class)


What it requires?

Net result of beta oxidation?


Difference in oxidation with unsaturated fatty acids?

Ketone bodies?


Acetone, acetoacetate, 3 hydroxybutyrate?


Formed by?


Causes?



Potentially confusing location issues?

Protein metabolism?


Transamination?

Organism-level regulation metabolism?



For insulin, glucagon, catabolism, glycogenolysis, glucongenesis?


Well-fed state?


Fasting state?


Starvation?


Tissue specific metabolism?


As in ketones, fatty acids, or glucose?


Liver?


Muscle?


- cardiac


- skeletal?


Exercise duration dependent?


Brain?


Adipose tissue?


Red blood cells?



Obesity and regulation of body mass


Body mass regulation?


Hormones ?


Threshold for weight gain?


Order of burning for fuel?

Anabolism of fats and carbs?


Non- template synthesis? Why?


Fatty a is synthesis of which fatty acid? Why? Where?


Where are all other ones synthesis ?