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51 Cards in this Set

  • Front
  • Back
In people with diabetes,glucose is not removed from the blood and hence cannot bestored in reserve. This leads to a lack of the synthesis of___________________.

A.cellulose


B. glycogen


C. ATP


D. starch.


E. sucrose

B.Glycogen
Which of the following terms includes all others?


A. monosaccharide


B. disaccharide


C. starch


D. polysaccharide


E. carbohydrate

E. Carbohydrate
Which of the following molecules would NOT be found in plants?

A. starch


B. glucose


C. cellulose


D. glycogen


E. phospholipids

D. Glycogen
When a carbonyl is found at the end of a monosaccharide, _(4)_.



A. the sugar is called an aldose


B. the sugar is called a carbonose


C. the sugar is called a ketose


D. Trick question –monosaccharides do not have carbonyl groups!

A. this sugar is an ALDOSE
What is the major structural difference between glycogen and starch?


A. The types ofcarbons involved in bonds.


B. The degree of branching.


C. The length of the molecule


D. There is no difference

B. The degree of branching
What polysaccharide is an important component inthe structure of many insects and fungi?

A. Cellulose.


B. Starch.


C. Chitin.


D. Protein.


E. Glycogen.

C. Chitin
Enzymes that readily break apart starch cannothydrolyze the bonds found in cellulose. Why is this logical?

A. The geometry of the moleculesare different, and enzymes are shape-specific.


B. Starch is held together by hydrogen bonding,not covalent bonding.


C. Cellulose molecules are highly branched; enzymes are too bulky to fit.


D. Cellulose molecules are not put together bydehydration synthesis,


and thus could not be broken by hydrolysis?

A. The geometry is different, and enzymes are shape-specific
List some of the functions of carbohydrates
Carbohydrates have six major functions within the body:

1. Providing energy and regulation of blood glucose


2. Sparing the use of proteins for energy


3. Breakdown of fatty acids and preventing ketosis


4. Biological recognition processes


5. Flavor and Sweeteners


6. Dietary fiber

The alpha and beta forms of glucose, found in starch and cellulose, differ in ...

(a) Whether the molecule is a ring or an open chain.


(b) Whether the ring contains five or six C atoms.


(c) Whether the first C atom is bound to one or two O atoms.


(d) How one of the -OH groups is oriented.


(e) None of the above.

(d) How one of the -OH groups is oriented.

One particular -OH group points to one side of the ring in alpha


glucose; the other side in beta glucose.

Which feature is shared by all monosaccharides?

(a) In their linear forms, they all contain a carbonyl and several hydroxyl functional groups.


(b) They are all pentoses.


(c) In their linear forms, they all contain a carboxyl and several hydroxyl functional groups.


(d) They all contain more than one sugar.

(a) In their linear forms, they all contain a

carbonyl and several hydroxyl functional groups.

How do the α and β forms of glucose differ?

(a) Their ring structures differ in the location of a hydroxyl group.


(b) Their linear structures differ in the location of a hydroxyl group.


(c) The α form can be involved in 1,4- and 1,6-glycosidic linkages; the β form can participate only in 1,4 linkages.


(d) The oxygen atom inside the ring is located in a different position.



(a) Their ring structures differ in the location of a hydroxyl group.

Glycogen is _____.



(a) A source of saturated fat


(b) A polysaccharide found in animals


(c) A transport protein that carries oxygen


(d) A polysaccharide found in plant cell walls


(e) The form in which plants store sugars

(b) A polysaccharide found in animals

Animals store energy in the form of glycogen.

_____ is the most abundant organic compound on Earth.



(a) Cellulose


(b) Glucose


(c) Starch


(d) Glycogen


(e) Lactose

(a) Cellulose



Cellulose, a component of plant cell walls, is the most abundant organic compound found on earth.

Which statement is true of sucrose?

(a) It's a disaccharide.


(b) It contains glucose.


(c) It's table sugar.


(d) Both (a) and (c).


(e) - (a), (b), and (c).

(e) - (a), (b), and (c)

We use sucrose as our table sugar because plants make plenty of it. They use it as their main circulating fuel, and sugar beets and sugar cane store a lot of it.


It's a disaccharide made of glucose and fructose .

Glycogen ...



(a) Contains several kinds of sugars.


(b) Occurs in animal cells and has branches.


(c) Is stronger, weight for weight, than steel.


(d) Occurs in chloroplasts and stores energy.


(e) None of the above.

(b) Occurs in animal cells and has branches.



Glycogen is the main energy-storing carbohydrate in animals and humans.

Which of the following structural features is

common to cellulose, chitin, and peptidoglycan?


(a) They can all form bonds between polymer chains that create parallel strands.


(b) They are all composed of glucose in either the α or β form.


(c) They are all composed of highly branched fibers.


(d) They all contain peptide bonds.

(a) They can all form bonds between polymer chains that create parallel strands.
Cellulose is _____.



(a) A monomer of starch.


(b) A major structural component of plant cell walls


(c) A polymer composed of fructose monomers


(d) Used by plants to make glycogen


(e) A storage polysaccharide for energy in plant cells

(b) A major structural component of plant cell walls .

What is "high fructose corn syrup" ?

High-fructose corn syrup is a common sweetener in sodas and fruit-flavored drinks

made from corn starch.

Define and explain the realtionship between


Monosaccharides, triose, pentose and hexose?

Monosaccharides:


most taste sweet; contain 3-7 carbon atoms, are either: ALDOSE (conatin an aldehyde group, or KETOSE (contain a ketose group); their names are composed by denoting the number of carbon atoms and the suffix -ose.


For example, the terms triose, pentose, and hexose signify monosaccharides with, respectively, three, five, and six carbon atoms.



Define: Aldose, Ketose and isomers

Monosaccharides are the simplest form of carbohydrates and may be subcategorized as aldoses or ketoses.


The sugar is an aldose if it contains an aldehyde functional group

A ketose signifies that the sugar contains a ketone functional group.

Isomeres are any of two or more substances that have the same molecular formula but differ in the way their atoms are connected to each other. Glucose, fructose and galactose are isomers, they have the same chemical formula (C6H12O6), but different structures.

What are Oligosaccharides and Polysaccharides?

Oligosaccharides are carbohydrates formed by the joining of 2 to 6 monosaccharide molecules,ie. Maltose - disaccharide formed in cells as a breakdown product of starch; Lactose - is a disaccharide found in milk and hence commonly called milk sugar; Sucrose is disaccharide found

extensively in plants. It is commonly called cane sugar.Polysaccharides: made up of many simple sugars chemically joined together (poly= many), ie.Starch (energy store in plants), glycogen (energy store in animals),


Cellulose (plant fibre)

What are Monosaccharides?

"Simple sugars" with the formula (C • H2O)n.

A monosaccharide is made up of one sugar (mono=one).


Have endings with "ose" : Fructose ("Fruit


Sugar"), Glucose, Galactose

What are Carbohydrates?

Carbohydrates are also known as sugars.

They are compounds of carbon, hydrogen and oxygen: C,H,O


1C : 2O : 1O (ie. C6H12O6)


Functions: * serve as raw material for synthesizing other molecules


* provide fibrous structural materials


* indicate cell identity


* store chemical energy

What are disaccharides?

A disaccharide is made up of two simple sugars chemically joined

together (di=2).


Examples:


Sucrose (Glucose + fructose = sugar cane/sugar beets)


Lactose (galactose + glucose = milk)


Maltose (glucose + glucose = in germinating grain)

What are Glycoproteins ?

Glycoproteins are proteins that have sugars attached to them.


They have diverse functions such as in our immune system, protection of our body, communication between cells, and our reproductive systems.

What are monomers?

Monomers=monosaccharides


They are monosaccharides that polymerize via


condensation reactions to form polymers like


polysaccharides.


The monosaccharides in polysaccharides are


joined by glycosidic linkages.

What are the functional groups of monomers,


or monosaccharides?

Carbonyl          C=O
+ Hydroxyl       OH-

Carbonyl C=O


+ Hydroxyl OH-



What are polymers?

Oligosaccahrides: small polymers


(oligo=few) (3-50 monosaccharides)


Polysaccharieds: many polymers


(poly=many) (over 50 monos)



Monosaccharides vary in structure by:

1. Location of the carbonyl group= they have one carbonyl


- at either end of the sugar, or in the middle of the sugar


thus called Aldose, or Ketose


2. Number of Carbon atoms (Triose=3; Pentose=5; Hexose=6)


3. Spatial arrangement of the atoms


(configuration/location of the hydroxyl (C-OH) groups)


4. Linear and alternative ring forms


(Sugars tend to form rings in aqueous solutions)

Difference between Aldose and Ketose?

left: carbonyl (C=O) group at the 
end of the carbon (C) chain=ALDOSE
right: carbonyl group in the middle
of the carbon chain= KETOSE
 

left: carbonyl (C=O) group at the


end of the carbon (C) chain=ALDOSE


right: carbonyl group in the middle


of the carbon chain= KETOSE


Draw chemical formula of an aldose


and a ketose

Glucose: 6 carbon aldehyde sugar
Fructose: 6 carbon ketose sugar

Glucose: 6 carbon aldehyde sugar


Fructose: 6 carbon ketose sugar

Sugars exist in linear and ring forms

Sugars normally have 
3-7carbons and form ring shapes,
if they have 5 carbons or more
example here: GLUCOSE (in linear          
                          and ring form)

Sugars normally have


3-7carbons and form ring shapes,


if they have 5 carbons or more


example here: GLUCOSE (in linear


and ring form)

draw the glycosidic linkage of the disaccharide


Maltose

Maltose: The hydroxyl group on C-1  is bonded with the hydroxyl group of C-4 of another molecule in form of a glycosidic link with the
 elimination of water (h2O)

Maltose: The hydroxyl group on C-1 is bonded with the hydroxyl group of C-4 of another molecule in form of a glycosidic link with the


elimination of water (h2O)

re the 2 most comm

2 most common glycosidic linkages:


α(1→4) glycosidic bonds and


β(1→4) glycosidic bonds


Linkage of sugars by hydrolysis takes place on the C1 carbon OH group


of the first ring in the α position and the C4 carbon OH group on the second ring. This connection is called a α(1→4) glycosidic bond,i.e.maltose,


glycogen. Linkage of the β glucose molecules on C1 and C4 OH group


is called β(1→4) glycosidic bonds, ie. cellulose.

 what is α and β Glucose?

what is α and β Glucose?

in β Glucose the OH group on 
C1 is pointing up
in α Glucose the OH group on 
C1 is pointing down

in β Glucose the OH group on


C1 is pointing up


in α Glucose the OH group on


C1 is pointing down

2 most common glycosidic linkages:
α(1→4) glycosidic bonds and 
β(1→4) glycosidic bonds

2 most common glycosidic linkages:α(1→4) glycosidic bonds and β(1→4) glycosidic bonds

What are macromolecules?

Have fifty-ish to thousands ofmonosaccharide monomers linked bydehydration synthesis = macromolecules!


1. Starch


2. Glycogen


3. Cellulose


4. Chitin


5. Peptidoglycan

what are examples of polysaccharides?

1. Glycogen in animals (highly branched α-glucose polymer)


2. Starch in plants (mixture of branched andunbranched


α-glucose polymer)


3. Cellulose in plants (polymer of β-glucose monomers)


4. Chitin in fungi/algae (comprised of N-acetylglucosamine (NAc)


monomers)


5. Peptidoglycan in bacterial cell walls (backbones of alternating


monosaccharides)

What is starch?

Storage (fuel) polysaccharide 
in plants
the glucose molecules form helices in form of amylose (unbranched), 
or amylopectin (branched)

Storage (fuel) polysaccharide


in plants


the glucose molecules form helices in form of amylose (unbranched),


or amylopectin (branched)

What is glycogen?

* Storage (fuel) polysaccharide 
     in animals
* All of glucose 
* Molecules form helices 
* HIGHLY branched (more so than 
                                    amylopectin)

* Storage (fuel) polysaccharide


in animals


* All of glucose


* Molecules form helices


* HIGHLY branched (more so than


amylopectin)

what is cellulose?

Structural polysaccharide 
(cell wall support) in plants 
All of β-glucose with β(1→4) linkage
Molecules form rods, sheets 
Unbranched 
Most abundant molecule on Earth!

Structural polysaccharide


(cell wall support) in plants


All of β-glucose with β(1→4) linkage


Molecules form rods, sheets


Unbranched


Most abundant molecule on Earth!

what is chitin?

Structural polysaccharide – Cell walls of fungi
•Chitin is a modified polysaccharide that contains nitrogen (all of one N-containing glucose derivative) 
•Exoskeletons of arthropods 
•Molecules form rods, sheets 
•Unbranched

Structural polysaccharide – Cell walls of fungi


•Chitin is a modified polysaccharide that contains nitrogen (all of one N-containing glucose derivative)


Exoskeletons of arthropods


•Molecules form rods, sheets


Unbranched

what is peptidoglycan ?

Structural (cell wall) polysaccharide in bacteria


•All of N-containing glucose derivatives covalently cross-linked


with short proteins (peptido=Protein; Glycan=glucose derivative)


• Molecules form rods, sheets


• “Un”branched (polysaccharide component)

How Do Carbohydrates Provide Structure?

* Cellulose, chitin, and peptidoglycan form long strands then


organized into fibres, orlayered in sheets, to give cells and


organisms greatstrength and elasticity!


* the β-1,4-glycosidic linkages ofstructural carbohydrates are


very difficult to hydrolyze

What do Carbohydrates Do?

A. Furnish building blocks: used directly (in RNA), or can provide


raw “carbon skeletons” (in amino acids)


B. Provide: their shape makes them difficult to break


(Chitin; Cellulose)


C. Cell Identity: as Glycoproteins (proteins joined to carbohydrates


bycovalent bonds) - cell-cell recognition andcell-cell signalling


ie. red blood cells - different blood types


D. Store/provide chemical energy in cells (photosynthesis in plants/ATP)


Explain Photosynthesis equation

Energy Stored in Glucose Is Transferred


to ATP


When a cell needs energy, carbohydrates


participate inexergonic reactions that


synthesize adenosine triphosphate(ATP):


CH2O + O2 + ADP + Pi → CO2 + H2O + ATP




Carbohydrates contain a large number of


C–H bonds, whichhave high free energy.

How Do Carbohydrates Store Energy?

Starch and glycogen are efficient energy-storagemolecules, because


the α-linkages are readilyhydrolyzed,


The enzymes amylase and phosphorylase catalyzethe hydrolysis


of α-glycosidic linkages inglycogen and starch, respectively.


The releasedglucose subunits can then be used in theproduction


of ATP.

Taste receptors and sweeteners

* We have taste receptors (TAS1R3) for sweetness, this tells us


a food is high in energy.


* A common sweetener, glucose–fructose (also called highfructose


corn syrup) is found in processed foods


* made by converting starch to glucose, then some glucose is


converted tofructose because glucose-fructose is both sweeter


and cheaper than sucrose

Artificial sweeteners

* Sucrose, sucralose, saccharin...


* Artificial sweeteners taste sweet becausethey bind to the


TAS1R3 (taste) receptor in tongue.


* The hydroxyl groups (OH) on sucrosereplaced with chlorine (Cl)

Types of Sweeteners Made from


Plant Sugars?

1. Table sugar (sucrose): from sugar beets/cane


2. Honey (glucose/fructose mixture):


flower nectar + bees


3. Glucose-Fructose: Corn + corn starch