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13 Cards in this Set
- Front
- Back
- 3rd side (hint)
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HX in ether |
Markovnikov regiochemistry. X to more substituted carbon & H to less substituted carbon. |
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Cl2 or Br2 |
Anti addition with halorium ion intermediate Solvents: alkanes, ether, THF, CH2Cl2 |
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Halohydrin |
Markovnikov regiochemistry & anti stereochemistry Solvents: THF/H2O or DMSO/H2O |
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Oxymercuration demercuration |
Addition of water Markovnikov regiochemistry
1. Hg(OAc)2, H2O/THF 2. NaBH4 |
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Hydroboration oxidation |
Addition of water Non-markovnikov syn addition 1. BH3, THF 2. H2O2, OH- |
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Hydrogenation |
Syn addition H2 with Pd/C or PtO2 (catalysts) |
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Epoxidation |
Either alkene with MCBPA in CH2Cl2 Or halohydrin with OH- in H2O |
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Hydroxylation |
Addition of 2 OHs Syn addition 1. OsO4 2. NMO |
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Dichlorocarbene addition |
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Simmons-Smith reaction |
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Hydroxylation |
Anti steriochemistry Epoxide with Acid catalyst in water |
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Ozone cleavage |
1. O3 2. Zn/ CH3COOH |
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Cleavage of 1,2-diols |
1. HIO4 2. THF or H2O |
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