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21 Cards in this Set
- Front
- Back
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Hydration |
H2O -> H + OH Markov H2SO4 or H3PO4 H3O+ |
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Hydrogenation |
H2 -> H + H
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Dihydroxylation |
HOOH -> OH + OH |
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Oxidative Cleavage |
O2 -> O + O (Two separate molecules) Split molecule in half, forms either ketones or aldehydes |
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Epoxidation |
O in triangle Uses Peroxyacid MCPBA Uses H3O+ to open ring and form two OH's Attacks on backside |
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Halogenation |
X2 -> X + X Anti-Addition Forms triangle, attacks from rear |
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Halohydride Formation |
XOH -> X + OH Markov Anti-Addition X2 H2O |
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HX Addition |
HX -> H + X Markov |
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Cyclopropanation |
CH2 -> CH2 in triangle Diazomethane- CH3N2, UV or Heat Simmons-Smith- CH2I2 and ZnCu (Used) Alpha Elimination of a Haloform- CHX3, NaOH,H2O Retains cis or trans |
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Free-Radical Initiation |
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Oxymercuration-Demercuration Reaction |
Hydration using Mercury as intermediate Hg taken off be NaBH4 Hg forms triangle, H2O attacks from other side Markov |
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Alkoxymercuraiton-Demercuration |
Same as last one, except ether instead of OH |
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Hydroboration |
Hydration with BH3 intermediate BH3 THF H2O2 NaOH H2O Anti-Markov Syn Addition |
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-OH |
Strong base promotes E2 reaction |
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Catalytic Hydrogenation |
Hydrogenation with catalyst Pt, Pd, Ni Syn |
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Syn Hydroxelation |
Adds 2 OHS on same side OsO4 and H2O2 KMnO4 and OH- |
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KMnO4 |
Harsh Conditions- Oxidative Cleavage Mild Conditions- Syn Hydroxelation |
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Ozonolysis |
O3 and (CH3)2S Forms ketones or aldehydes (CH3)2SO |
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Cationic Polymerization |
Pronate Molecule, attach more to pronated side |
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Radical Polymerization |
Forms radicals, then combines them |
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Anionic Polymerization |
Creates anions, combines them |
