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10 Cards in this Set

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Hydrohalogenation

Alkene + HX
Markovikov addition

Peroxide (ROOR) gives anti-markovnikov

Both are racemic mixtures
Hydration

Alkene + (H30+)
Proton transfer and markovnikov addition of water
Hydroboration Oxidation

1)BH3-THF
2)H202, NaOH
Anti-markovnikov addition of water

Syn enantiomer of H and OH
Catalytic Hydrogenation

H2/Pd
Syn addition of hydrogen
Halogenation

X2
Adds best with Cl and Br, adds anti
Halohydrin

X2 + H20 solvent
Water attacks more because it has higher concentration
It will attack the most substituted carbon
Anti-dihydroxylation

RCO3H
Creates epoxide, then water attacks anti

Creates 2 enantiomers
Syn-dihydroxylation

OsO4/NMO & Na2SO3/H2O
Creates Syn diol
Can also be achieved by KMnO4 under cold conditions

MnO4- can further oxidize diols
Oxidative cleavage

1) O3 2) DMS
Cleaves by making =O bond between the alkene double bond
Oxymercuration-demurcuration

1)Hg+OAc, H20
2) BH4
allows markovinov addition of water without rearrangement