The concentrations are very precise, with an extremely small standard deviation. Error could have resulted from accidently going past the equivalence point of the reaction, after the indicator changed colors, or from an incomplete transfer of the acidic salt into the analyte solution.
Discussion of Titration of Cola:
The objective of part B was to calculate the pH of a sample of cola by titrating it with a known concentration of a strong base measuring the pH with a pH probe.
The first equivalence point was at the addition of 9.25 mL of NaOH at a pH of 4.19. The second equivalence point was at the addition of 25.75 mL of NaOH at a pH of 8.63. The equivalence points were identified by locating the local maximums of the change in pH per volume of titrant.
(A19+A18)/2 was the formula used to calculate the avg. volume of titrant added per data point.
The initial pKa, pKa1 was calculated to be 1.46.
The formula used to calculate the initial concentration of H3PO4 was ((F30*F9)/(C13)).
The formula to calculate the pKa1 was