The result has liquid-crystalline behavior, and mechanical drawing orients the polymer chains in the fiber's direction. Hexamethylphosphoramide (HMPA) was the solvent initially used for the polymerization, but for safety reasons, DuPont replaced it by a solution of N-methyl-pyrrolidone and calcium chloride. As this process had been patented by Akzo (see above) in the production of Twaron, a patent war ensued.Poly-paraphenylene terephthalamide – branded Kevlar – was invented by Polish-American chemist Stephanie Kwolek while working for DuPont,[6] in anticipation of a gasoline shortage. In 1964, her group began searching for a new lightweight strong fiber to use for light but strong tires.[6] The polymers she had been working with at the time, poly-p-phenylene-terephthalate and polybenzamide,[7] formed liquid crystal while in solution, something unique to those polymers at the
The result has liquid-crystalline behavior, and mechanical drawing orients the polymer chains in the fiber's direction. Hexamethylphosphoramide (HMPA) was the solvent initially used for the polymerization, but for safety reasons, DuPont replaced it by a solution of N-methyl-pyrrolidone and calcium chloride. As this process had been patented by Akzo (see above) in the production of Twaron, a patent war ensued.Poly-paraphenylene terephthalamide – branded Kevlar – was invented by Polish-American chemist Stephanie Kwolek while working for DuPont,[6] in anticipation of a gasoline shortage. In 1964, her group began searching for a new lightweight strong fiber to use for light but strong tires.[6] The polymers she had been working with at the time, poly-p-phenylene-terephthalate and polybenzamide,[7] formed liquid crystal while in solution, something unique to those polymers at the