As a talented film and stage actor, he held an undergraduate degree from the University of Saskatchewan, a graduate degree from Carleton University, and an honourary doctorate in Law from the University of Ottawa.
In 1966 to 1969, Daniels attended the University of Saskatchewan, and majored in political science. His first experience with elected office in native associations came in 1972, when he served as Vice President of the Métis Association of Alberta. During this period, he was also a representative for Aboriginal people at the United Nations conference on the Environment in Stockholm, Sweden.
Daniels held the elected office of Secretary Treasurer of the Native Council of Canada between 1974 and 1975. He was also the director of Aboriginal Rights Research for the Métis Association of Alberta. In 1979, Daniels served as chairman of the Métis and Non-Status Crime and Justice