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28 Cards in this Set

  • Front
  • Back
the reversible exchange of ions between a liquid and a solid.
Ion Exchange
the process whereby impurities present in the incoming fluid (water) are removed by exchanging impure ions with H+ and OH‑ ions, resulting in the formation of pure water.
Demineralize
an ion with a negative charge.
Anion
an ion with a positive charge
Cation
3 reasons for removing impurities in Rx water:
To minimize corrosion
To minimize radiation levels
To minimize fouling of heat transfer surfaces.
are large molecules formed by the combining many molecules of one or two compounds in a repeating structure that produces long chains.
Polymers
a vessel, usually with a volume of several cubic feet, that contains the resin.
Mixed-bed demineralizer
a ratio of the concentration (or activity) of the fluid at the inlet compared to the concentration (or activity) at the effluent, which expresses the effectiveness of an ion exchange process.
Decontamination Factor
ion exchange resins are formed in the shape of very small beads, called ______, with an average diameter of about 0.005 millimeters.
resin beads
The relative strength of the ionic attraction between different ions
Relative Affinity
5 filtration mediums (7)
Ion exchangers
Sand
Activated Charcoal
Anthracite
Diatomaceous Earth
How mixed-bed ion exchangers control PH
As reactor coolant passes through the ion exchange system, ionic impurities will be removed and NH4+ and OH‑ will be added.
Thus, the resin serves both to purify the coolant and to help maintain the pH of the coolant by releasing NH4OH.
Resin Malfunctions (9)
Channeling
Breakthrough
Exhaustion
the attraction between a resin and a given ion
Affinity
a ratio of the concentration (or activity) of the fluid at the inlet compared to the concentration (activity) at the effluent, which expresses the effectivenes of an ion exchange process.
Decontamination Process
exchanges positive ions
Cation Resin
Exchanges negative ions
Anion Resin
We use the _____ to classify atoms.
Atomic Number
when the shared pair of electrons is not shared equally, one end of the bond is positive, and the other end is negative. This produces a bond with two poles.
Polar Covalent Bond
Is defined as the number of equivalents of solute dissolved in one liter of solution
Normality
The loss of electrons by one substance and the simultaneous gaining of electrons by another
Oxidation- reduction Process
Dissolved solids _____ conductivity
Increase
Methods to controld general corrosion?
Passivation
Cathodic protection
Removal of corrosive agents
Chemical Additions
Formation of an oxide layer
Passivation
Problems with Crud
Foul heat transfer
radiation
radiative hot spots
crud burst lead to more corrosion
complicates disposal of coolant
Locations susceptible to galvanic corrosion?
Condenser tubes- brass
condenser tube sheet - steel allow
Methods to minimize galvanic corrosion?
insulate the junction
coat one of both
use similar metals
use pure water
sacrifical anodes
formation of a compound, between the metal atoms on the surface of a grain boundary,of a monomolecular layer of the substance
Chemisortion