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28 Cards in this Set
- Front
- Back
the reversible exchange of ions between a liquid and a solid.
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Ion Exchange
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the process whereby impurities present in the incoming fluid (water) are removed by exchanging impure ions with H+ and OH‑ ions, resulting in the formation of pure water.
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Demineralize
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an ion with a negative charge.
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Anion
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an ion with a positive charge
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Cation
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3 reasons for removing impurities in Rx water:
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To minimize corrosion
To minimize radiation levels To minimize fouling of heat transfer surfaces. |
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are large molecules formed by the combining many molecules of one or two compounds in a repeating structure that produces long chains.
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Polymers
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a vessel, usually with a volume of several cubic feet, that contains the resin.
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Mixed-bed demineralizer
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a ratio of the concentration (or activity) of the fluid at the inlet compared to the concentration (or activity) at the effluent, which expresses the effectiveness of an ion exchange process.
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Decontamination Factor
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ion exchange resins are formed in the shape of very small beads, called ______, with an average diameter of about 0.005 millimeters.
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resin beads
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The relative strength of the ionic attraction between different ions
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Relative Affinity
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5 filtration mediums (7)
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Ion exchangers
Sand Activated Charcoal Anthracite Diatomaceous Earth |
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How mixed-bed ion exchangers control PH
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As reactor coolant passes through the ion exchange system, ionic impurities will be removed and NH4+ and OH‑ will be added.
Thus, the resin serves both to purify the coolant and to help maintain the pH of the coolant by releasing NH4OH. |
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Resin Malfunctions (9)
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Channeling
Breakthrough Exhaustion |
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the attraction between a resin and a given ion
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Affinity
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a ratio of the concentration (or activity) of the fluid at the inlet compared to the concentration (activity) at the effluent, which expresses the effectivenes of an ion exchange process.
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Decontamination Process
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exchanges positive ions
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Cation Resin
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Exchanges negative ions
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Anion Resin
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We use the _____ to classify atoms.
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Atomic Number
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when the shared pair of electrons is not shared equally, one end of the bond is positive, and the other end is negative. This produces a bond with two poles.
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Polar Covalent Bond
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Is defined as the number of equivalents of solute dissolved in one liter of solution
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Normality
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The loss of electrons by one substance and the simultaneous gaining of electrons by another
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Oxidation- reduction Process
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Dissolved solids _____ conductivity
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Increase
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Methods to controld general corrosion?
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Passivation
Cathodic protection Removal of corrosive agents Chemical Additions |
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Formation of an oxide layer
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Passivation
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Problems with Crud
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Foul heat transfer
radiation radiative hot spots crud burst lead to more corrosion complicates disposal of coolant |
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Locations susceptible to galvanic corrosion?
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Condenser tubes- brass
condenser tube sheet - steel allow |
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Methods to minimize galvanic corrosion?
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insulate the junction
coat one of both use similar metals use pure water sacrifical anodes |
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formation of a compound, between the metal atoms on the surface of a grain boundary,of a monomolecular layer of the substance
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Chemisortion
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