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33 Cards in this Set

  • Front
  • Back

Energy

The capacity to do work.

Radiant energy

Solar energy, that comes from the sun.

Thermal energy

Associated with random motion of atoms.

Chemical energy

Energy that is stored within the structural units of chemical substances.

Potential energy

Energy available by virtue of an object's position.

Law of conservation of mass

Total quantity of energy in the universe is assumed constant (Matter can't be created or destroyed).

Heat

The transfer of energy between two bodies that are at differwnt temperatures.

Thermochemistry

The study of heat change in chemical reactions.

System

Specific part of the universe that is of intrest to us.

Surroundings

The rest of the universe outside the system.

Open system

Can exchange mass and energy, usually in the form of heat with its surroundings.

Closed system

Allows transfer of heat but now mass.

Isolated system

Doea not allow the transfer of either mass or energy.

Exothermic process

Any process that gives off heat, that transfers thermal energy to the surroundings.

Endothermic process

Heat has to be supplied to the system by the surroundings.

Thermodynamics

The study of the interconversion of heat and other kinds of energy.

State of a system

The value of all relevant microscopic properties(composition, energy, temperature, pressure, and volume).

State functions

Properties that are determined by the state of the system, regardless of how that condition was achieved.

First law of thermodynamics

Energy can be converted from one form to another, but cannot be created or destroyed.

Work

Work = Force × Distance.


(w = f × d)

Calorimetey

The measurment of heat changes.

Specific heat

Amount of heat required to raise the temperature of one gram of the substance by one degree Celsius.

Heat capacity

The amount of heat required to raise the temperature of a given quantity of the substance by one degree Celsius.

Standard enthalpy of formation

By convention, the standared enthalpy of formation in its most stable form, is zero.

Standard state

Substances are in the standard state at 1 atm.

Standard enthalpy of reaction

The enthalpy of a reaction carried out at 1 atm.

Hess' law

When reactants are converted to products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps.

Heat of solution (Enthalpy of solution)

The heat generated or absorbed when a certain amount of solute dissolves in a certain amount of solvent.

Latrice energy (U)

The energy required to completley seperate one mole of a solid ionic compound into gaseous ions.

Heat of hydration

The enthalpy change associated with the hydration process.

Heat of dilution

The heat change associated with the dilution process.

Key Equations

Thermochemical equations

Show the enthalpy changes as well as the mass relationships.