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41 Cards in this Set

  • Front
  • Back

Alkane > haloalkane

Alkane + halogen



Presence of UV light



Free radical substitution

Alkane > dihaloalkane

Alkane + halogen



Presence of UV light



Free radical substitution

Alkene > alkane

Alkene + hydrogen



Nickel catalyst with high temp & pressure



Addition

Alkene > haloalkane

Alkene + hydrogen halide



Room temp



Electrophilic addition

Alkene > dihaloalkane

Alkene + halogen



Room temp



Electrophilic substitution

Alkene > alcohol

Alkene + steam



Phosphoric acid catalyst, high temp and pressure



Electrophilic addition

Primary alcohol > aldehyde

Primary alcohol and acidified potassium dichromate



Heat and distil



Oxidation

Primary alcohol > carboxylic acid

Primary alcohol and acidified potassium dichromate



Reflux



Oxidation

Secondary alcohol > ketone

Secondary alcohol and acidified potassium dichromate



Reflux



Oxidation

Alcohol > alkene

Alcohol



Reflux with sulfuric acid catalyst



Dehydration

Alcohol > haloalkane

Alcohol with sodium halide and sulfuric acid



Reflux



Nucleophilic substitution

Haloalkane > alcohol

Haloalkane + NaOH



Reflux



Hydrolysis

Benzene > nitrobenzene

Benzene + conc nitric acid



Conc sulfuric acid catalyst and 50oC



Electrophilic substitution

Benzene > halobenzene

Benzene + halogen



Halogen carrier



Electrophilic substitution

Benzene > alkylbenzene

Benzene + haloalkane



Halogen carrier



Electrophilic substitution

Benzene > acylbenzene

Benzene + acyl chloride



Halogen carrier



Electrophilic substitution

Phenol > phenoxide

Phenol + Base



Room temp



Acid-base

Phenol > halophenol

Phenol + halogen



Room temp



Electrophilic substitution

Phenol > nitrophenol

Phenol + nitric acid



Room temp



Electrophilic substitution

Aldehyde > carboxylic acid

Aldehyde + acidified potassium dichromate (or tollens reagent)



Reflux



Oxidation

Aldehyde > primary alcohol

Aldehyde + NaBH4



Warmed



Reduction

Ketone > secondary alcohol

Ketone + NaBH4



Warmed



Reduction

Carbonyl > hydroxynitrile

Carbonyl + HCN



Sodium cyanide + sulfuric acid provide the HCN



Nucleophilic addition

Carboxylic acid > carboxylate salt

Carboxylic acid + Base



Room temp



Acid-base

Carboxylic acid + alcohol > ester

Warmed with concentrated sulfuric acid catalyst



Condensation

Acid anhydride + alcohol > ester

Just acid anhydride + alcohol



Condensation

Ester > alcohol + carboxylic acid

Ester under Reflux with a dilute sulfuric acid catalyst



Hydrolysis

Ester > alcohol + carboxylate salt

Reflux with sodium hydroxide



Hydrolysis

Carboxylic acid > acyl chloride

React with SOCl2 (thionyl chloride)



Condensation

Acyl chloride > carboxylic acid

Acyl chloride + water



Condensation

Acyl chloride > ester

Acyl chloride + alcohol



Condensation

Acyl chloride > primary amide

Acyl chloride + ammonia



Bubble ammonia through



Condensation

Acyl chloride > secondary amide

Acyl chloride + primary amine



Condensation

Haloalkane > primary amine

Haloalkane + ammonia + NaOH



Ethanol used as solvent and ammonia in large excess



Nucleophilic substitution

Nitroarene > arylamine

Nitroarene Refluxed with HCl and tin catalyst


Then react with excess NaOH to get rid of salt

Polyamide > amides

Polyamide + water + protons



Conc sulfuric acid gives the protons



Hydrolysis

Polyamide > amide salt

Polyamide + NaOH



Hydrolysis

Haloalkane > nitrile

Haloalkane + KCN



Nucleophilic substitution

Nitrile > amine

Nitrile + hydrogen gas



Nickle catalyst



Addition

Nitrile > carboxylic acid

Nitrile + water + HCl



Reflux



Hydrolysis

Making an addition polymer

Reflux