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27 Cards in this Set

  • Front
  • Back
Additional polymerization/free radical polymerization is known as what

Common mode of reaction for many dental materials

Explain Monomer (3)

Reactive/ Functional groups



C=C




Liquid of polymer-monomer reactions

What are the steps of Polymerization

Inititation (2 phases




Propogation




Termination

What are the phases of polymerization

Phase one: Free radical formation (heat, light, chemical)




Phase two: free radical that has formed react with C=C double bond form an atomic bond changes to C-C with and unpaired electron at the end of the chain for continual bonding

Propogation step

Same as the 2nd phase in the initiation step= additional 2nd, 3rd, 4th, ect monomers

Termination Step

Two chains contacting and terminating each other or the introduction of contaminants will terminate the reaction

What are the methods of activation

Heat activated


Initiator: Benzolperoxide




Chemically activated


Initiator: Benzoperoxide and is activated by tertiary amines




Light Cure




Dual Cure:


Cures via light and chemical means

What is the inhibitor of polymerization reactions

Hydroquinone

What are conflicts with the resign and its properties (3)

Polymerization Shrinkage


Coefficient Thermal Expansion


Polyermic material lacks strength

COMPOSITE MATERIALS

..............

What are the two phases for composite materials

Matrix


Filler

What does the Matrix do (3)

bis-GMA




responsible for creating the solid mass and bonding to tooth structures




Weak by itself

What is the filler

Compensate and resolve the weakness of the matrix by itself




Increased filler=increased composite strength

Increased filler = Decreased resin (matrix) therefore what happens (3)

Decreased coefficient thermal expansion


Polymerization shrinkage decreases


Resulting product is more similiar to a natural tooth

What are the different types of composite material

Macrofilled


Microfilled


Hybrid


Improved hybrid

Describe macrofilled composites (4)

1st type developed


Quarts


Large particles (feels rough)


Not ideal for posterior teeth

Microfilled composites

Much smaller




Smooth surface




Smaller particles are fused silica requires more resign

What is a disadvantage for microfilled composites

Smaller particles are fused silica less filler for strength

Hybrid Composites

Blended composites

Improved Hybrid

Increased number of nano particles further decrease the resin-filler ratio while retaining strength, esthetics, and physical properties

What are factors to consider with composite (3)

Depth of cure




Incremental addition




Air Inhibition

What is depth of cure

The thickness of the composite that is to be cured by light

Glass IONOMER MATERIAL

...............

What are the different types of glass ionomers (4)

Chemical cured glass ionomer




Resign modified glass ionomer




Acid base chemically activated resign modified glass ionomer




Recharging glass ionomer

Describe chemically cured glass ionomer (4)

Acid base reaction


FL releasing


1st true adhesive material


Crazing

Describe resign modified glass ionomer (1)

Acid base reaction in combination via light or chemical activation

Describe Acid based chemically activated resign modified glass ionomer (2)

Superior




Need in instances where directed light cannot access the material