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19 Cards in this Set

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What do the symbols stand for and what are their units in the equation?




Q=mcAT (delta T)



Q = Energy in Joules (J)


m = Mass in Kilograms (kg)


c = Specific heat capacity ( J/Kg C )


AT = Temperature change (*C)

1. How do you change from Degrees to Kelvin?




2. How do you change from Kelvin to Degrees?

1. add 273




2. subtract 273

What is the definition of Specific Heat


Capacity?

The specific heat capacity of a material is the energy required to heat a 1kg material through a temperature change of 1*C.

What is an ideal gas?

A gas that has no potential energy between particles therefore the internal energy is equal to the kinetic energy.

What is Internal Energy?

Internal energy is the sum of the kinetic and


potential energy of the particles that form the system.




U = Ek + Ep




Internal energy is randomly distributed

Temperature:


If the average kinetic energy of the molecules of a substance increase, then it has a higher temperature.




What determines the temperature?

The internal energy

What is the first law of thermodynamics?



The energy of the universe is constant.


Energy can be transferred from the system to the surroundings or vice versa, but never destroyed.




Euni = Esys + Esurr

The first law of thermodynamics also shows that the internal energy is the sum of the heat gained or lost by the system and the work done on or by the system.




What equation represents this?

Esys = Q + W

Example of the first law of thermodynamics: beaker of water on a hot plate

-Hot plate is turnedon
-System gains heat from its surroundings
-Temp & internal energy of the system increase
-E is positive
-When the hot plate is turned off
-Water loses heat to surroundings as it cools
-E is negative
Relationship between internal energy and work can be understood byconsidering the tungsten filament inside a light bulb:
-Workis done on this system by driving an electric current through the tungsten wire
-System becomes hotter and E is therefore positive. (Eventually, the wire becomes hot enoughto glow.)
Conversely, Eis negative when the system does work on its surroundings.
internal energy&temperature of a system
decrease (E < 0):
-systemeither loses heat or
-does work on its surroundings
internal energy&temperature of a system
increase (E> 0):
-system gains heat from its surroundings or -surroundings do workon the system

Ideal Gas Equations:




pV = nRT




pV = NkT




What do the symbols R, N and k stand for?

R = Universal Gas Constant (8.31 J/Kg mol)




k = Boltzman Constant (1.38x10-23 J/K)




N = Number of molecules

Molecular Kinetic Energy:




1/2m<c^2> = 3/2kT

Temperature must be measured in Kelvin

What 3 things does the specific heat capacity depend on?

1. Amount of heat energy transferred




2. The mass of an object




3. The material which the object is made of

The Maxwell-Boltzmanndistribution shows how many particles in a gas have the differentspeeds.

If you plot a graph of speed distribution against speed for a gas of two different temperatures, what can you conclude?



1. At a higher temperature the average speed
increases.

2. At a higher temperature the maximum speed increases.

3. At a higher temperature the distribution of speeds is greater.

Boyle's Gas Law:




The pressure of a given mass of an ideal gas is inversely proportional to its volume




Only if the temperature is constant

p & 1/V

Charles' Gas Law:




The volume of a given mass of an ideal gas is directly proportional to the temperature




Only if the pressure is constant

V & T (kelvins)

Pressure Law:




For a given mass of an ideal gas, the pressure is directly proportional to the temperature




Only if the volume is constant

p & T (kelvins)

What assumptions are made for an ideal gas?

1. The gas consists of a large numberof
identical molecules
2. The molecules obey Newton's laws
3. The volume of the molecules is negligibly small comparedto the volume occupied by the gas
4. No forces act on themolecules except during elastic collisions of negligible duration.