Orgo 1 (Lesson Book)

Front 1

A compound is aromatic only if it follows what 4 rules

Back 1

Planar, Cyclic, Conjugated, 2-6-10-14 electrons

Front 2

What type of bonds make up a single bond

Back 2

Sigma bond

Front 3

What type of bonds make up a double bonds

Back 3

One sigma, one pi

Front 4

What type of bonds make up triple bonds

Back 4

One sigma, two pi

Front 5

sp3 hybridization follow which bond angle

Back 5

109.5

Front 6

sp2 hybridization follows which bond angle

Back 6

120

Front 7

sp hybridization follows which bond angle

Back 7

180

Front 8

A carbon atom that has four different groups bonded to it is referred to as a

Back 8

Chiral carbon

Front 9

When designating molecules as R or S, what do these two indicate

Back 9

R = clockwise, S = counterclockwise

Front 10

Under which cercumstance do you change a molecule from R to S

Back 10

When the group with the lowes priority (4) is on the horizontal axis

Front 11

Which type of compounds possess a plane of symmetry

Back 11

Meso Compounds

Front 12

Pairs that have chiral centers and nonsuperimposable mirror images

Back 12

Enantiomers

Front 13

Pairs that have chiral centers and but different arrangement of atoms

Back 13

Diastereomers

Front 14

The type of designation used for simple alkenes in which one non-hydrogen group is attached to each side of the double bond

Back 14

Cis-Trans designation

Front 15

The type of designation used for more complex alkenes (priority is used and you're looking for where 1 and 2 are located about a double bond)

Back 15

(E)-(Z) designation

Front 16

If DAT asks to rank compounds according to solubility, what do you look for

Back 16

Electronegativity (more electronegative means, more soluble in water)

Front 17

Nucleophiles "love" positive or negative charges

Back 17

Positive charges

Front 18

Electrophiles "love" positive or negative charges

Back 18

Negative charges

Front 19

In which substitution reaction (SN1 / SN2) does the rate law show direct dependence of the reaction rate on the concentration of the alkyl halide only

Back 19

SN1

Front 20

How many steps does it take to complete an SN1 reaction

Back 20

2

Front 21

Between SN1 and SN2, which of the two reactions favors a strong nucleohile

Back 21

SN2 (necessary to push out weak leaving group)

Front 22

SN1 or SN2 rxns have rate laws that show direct dependence of the rxn rate on the concentrations of both alkyl halide and nucleophile

Back 22

SN2

Front 23

Which type of solvents are used for SN2 reactions

Back 23

Aprotic (acetone and DMSO)

Front 24

Which type of solvents are used for SN1 reactions

Back 24

Protic (water and alcohol)

Front 25

A compound is aromatic only if it follows what 4 rules

Back 25

Planar, Cyclic, Conjugated, 2-6-10-14 electrons

Front 26

What type of bonds make up a single bond

Back 26

Sigma bond

Front 27

What type of bonds make up a double bonds

Back 27

One sigma, one pi

Front 28

What type of bonds make up triple bonds

Back 28

One sigma, two pi

Front 29

sp3 hybridization follow which bond angle

Back 29

109.5

Front 30

sp2 hybridization follows which bond angle

Back 30

120

Front 31

sp hybridization follows which bond angle

Back 31

180

Front 32

A carbon atom that has four different groups bonded to it is referred to as a

Back 32

Chiral carbon

Front 33

When designating molecules as R or S, what do these two indicate

Back 33

R = clockwise, S = counterclockwise

Front 34

Under which cercumstance do you change a molecule from R to S

Back 34

When the group with the lowes priority (4) is on the horizontal axis

Front 35

Which type of compounds possess a plane of symmetry

Back 35

Meso Compounds

Front 36

Pairs that have chiral centers and nonsuperimposable mirror images

Back 36

Enantiomers

Front 37

Pairs that have chiral centers and but different arrangement of atoms

Back 37

Diastereomers

Front 38

The type of designation used for simple alkenes in which one non-hydrogen group is attached to each side of the double bond

Back 38

Cis-Trans designation

Front 39

The type of designation used for more complex alkenes (priority is used and you're looking for where 1 and 2 are located about a double bond)

Back 39

(E)-(Z) designation

Front 40

If DAT asks to rank compounds according to solubility, what do you look for

Back 40

Electronegativity (more electronegative means, more soluble in water)

Front 41

Nucleophiles "love" positive or negative charges

Back 41

Positive charges

Front 42

Electrophiles "love" positive or negative charges

Back 42

Negative charges

Front 43

In which substitution reaction (SN1 / SN2) does the rate law show direct dependence of the reaction rate on the concentration of the alkyl halide only

Back 43

SN1

Front 44

How many steps does it take to complete an SN1 reaction

Back 44

2

Front 45

Between SN1 and SN2, which of the two reactions favors a strong nucleohile

Back 45

SN2 (necessary to push out weak leaving group)

Front 46

SN1 or SN2 rxns have rate laws that show direct dependence of the rxn rate on the concentrations of both alkyl halide and nucleophile

Back 46

SN2

Front 47

Which type of solvents are used for SN2 reactions

Back 47

Aprotic (acetone and DMSO)

Front 48

Which type of solvents are used for SN1 reactions

Back 48

Protic (water and alcohol)

Front 49

A racemic mixture of products is obtained in SN1 or SN2 reactions

Back 49

SN1

Front 50

When is E2 favored over SN2?

Back 50

When a bulky base is present

Front 51

What's a good indicator that you're dealing with an E2 reaction?

Back 51

The presence of heat