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5 Cards in this Set

  • Front
  • Back
What happens in the following reaction:

R-Br + Mg in ether
Grignard - An alkylmagnesium product of R-MgBr is formed
What happens in the following reaction:

R-Cl + 2Li in pentane
An alkyllithium product of R-Li + LiCl is formed
What happens to organometallics in water?
The strong bases act as proton acceptors and the metal is kicked out
CH₃CH₂MgBr + H₂O → CH₃CH₂-H + Mg(OH)Br
What is the formula for creation of Gilman Reagents
CH₃CH₂CH₂CH₂Li + CuI
ether
-------->
THF
(CH₃CH₂CH₂CH₂)₂CuLi + LiI
What does Gilman Reagent do?
No Conversion of bonds.

Halogen replaces Methyl