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33 Cards in this Set
- Front
- Back
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Alkane+O2
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CO2+water+heat
combustion CO if incomplete rxn |
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Alkane+Free radical
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alkyl radical
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Alkane+heat
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larger alkane after small-chain alkyl radicals
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RX+ -CN
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RCN
nitrile/cyanide |
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RCN + H+/H2O
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carboxylic acid + ammonia (NH3) or ammonia salt
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RX+Mg/Ether
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RMgBr (Grignard reagent)
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RMgBr+1) dry ice (CO2 (s)) (2) H+,Et2O, THF
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Carboxylic acid
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RX2 (alkyl dihalide)
+ base/heat (base: NaNH2 or n-BuLi) |
alkyne (removes geminal/vicinal halides)
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Alcohol + H+/heat
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alkene (dehydration)
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Alcohol + HX
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RX
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Alcohol+Tosyl chloride
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Tosylate
(p-toulenesulfonate=good LG) |
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Alcohol+PCC
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1*alcohol-->aldehyde
2*alcohol-->ketone |
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Alcohol+dichromate salt (Na2Cr2O7/H2SO4)
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1*alcohol-->carboxylic acid
2*alcohol-->ketone |
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Alcohol+CrO3/H2SO4
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1*alcohol-->carboxylic acid
2*alcohol-->ketone Jones's Oxidtion |
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Alcohol+KMnO4
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carboxylic acid
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Alkene+H2/Pd or Pt or Ni
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Alkane
(syn addition) |
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Diene + Br2
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1,2-addition
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Alkene + H2O/H2SO4
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alcohol
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Carbonyl+Grignard reagent and H+/Et2O or THF
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Alcohol
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Alkene + (1) BH3/THF (2) H2O2, -OH
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alkane, alcohol added anti-markovnikov, syn addition
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Alkene + KMnO4 (cold, dilute)
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alcohol on either side of double bond
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Alkene + KMnO4 (hot)
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cleavage
1*C-->carboxylic acid 2*C-->ketone |
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Alkene + (1) O3/CH2Cl2 (2) Zn, H2O
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Cleavage
1*C-->aldehyde 2*C-->ketone |
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Alkene + (1) O3/CH2Cl2 (2) Zn, H2O (3) NaBH4 or LiAlH4
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Cleavage
alcohol |
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Alkene+ HX + peroxides or UV light
X= Br and CL only |
extended alkane with halogen anti-markovnikov for radical stability
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alkene + MCPA (peroxycarboxylic acids)
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epoxide
syn addition |
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Alkene+R*/heat/high pressure
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polymer with R on each end
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Alkyne+Lindler's catalyst (PdSO4 or BaSO4)
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Alkene cis/Z
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Alkyne+Na+NH3 (l)
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Alkane, trans/E
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Alkyne +Br2
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Alkene, markovnikov addition (do again to get alkane)
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Alkyne +R*
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alkene trans/E anti-Markovnikov
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Alkyne +H2SO4+HgSO4+H2O
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ketone
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Alkyne +1/2B2H6-->acetic acid
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alkene cis/Z syn addition
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