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11 Cards in this Set

  • Front
  • Back
What does it do?

Na⁺NH₂⁻
Converts alkyne to ionized product:
HC≡CH + Na⁺NH₂⁻ → HC≡C⁻Na⁺
What does it do to an alkene?

Br₂
Breaks DB and puts Br on α Carbon
What does it do to an alkyne?

Br₂
Puts a Br trans on each α Carbon
What does it do to an dibromonated alkane, H₂BrC-CBrH₂?

2 NaNH₂ (or other Strong base)
---------->
NH₃(l)
Two dehydrohalogenations to give alkyne
What does it do to an alkyne?

HBr
What about two additions?
Br on α Carbon, Markov. Another Br adds to the same C
What does it do to a terminal alkyne?

BH₃
----------->
H₂O₂,NaOH
Converts terminal alkyne to a tautomer
What does it do to an alkyne?

(sia)₂BH
----------->
H₂O₂,NaOH
Aldehyde
What does it do to an alkyne in water?

H₂SO₄
--------->
HgSO₄
Tautomer on more substituted Carbon
What does it do to an alkyne?

H₂
---->
Pd
Hydrogenates alkyne to alkane
What does it do to an alkyne?

H₂
---->
Lindlar
Cis Hydrogenates alkyne to alkene
What does it do to an alkyne?

2 Na
---------->
NH₃(l)
Trans hydrogenates to alkene