Reading...
Play button
Play button
Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
9 Cards in this Set
- Front
- Back
|
Addition of HX*
|
Additional Reagents: HX
What adds: -H, -X Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: Yes |
|
|
Addition of HBr with peroxide*
|
Additional Reagents: HBr, peroxide
What adds: -H, -Br Regioselectivity: Anti-Markovnikov Stereoselectivity: N/A Rearrangement: No |
|
|
Acid-Catalyzed Hydration*
|
Additional Reagents: H20, H+
What adds: -H, -OH Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: Yes |
|
|
Oxymercuration-Demercuration
|
Additional Reagents:
1) Hg(OAc)2, H2O 2) NaBH4 What adds: -H, -OH Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: No |
|
|
Alkoxymercuration-Demercuration
|
Additional Reagents:
1) Hg(OAc)2, ROH 2) NaBH4 What adds: -H, -OR Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: No |
|
|
Hydroboration-Oxidation
|
Additional Reagents:
1) "BH3" 2) H2O2, -OH What adds: -H, -OH Regioselectivity: Anti-Markovnikov Stereoselectivity: Syn Rearrangement: No |
|
|
Hydrogenation
|
Additional Reagents: H2 with Pt, Pd, or Ni
What adds: -H, -H Regioselectivity: N/A Stereoselectivity: Syn Rearrangement: No |
|
|
Simmons-Smith
|
Additional Reagents: CH2I2, Zn(Cu)
What adds: -CH2- (triangle) Regioselectivity: N/A Stereoselectivity: Retention of stereochemistry Rearrangement: No |
|
|
Alpha-elimination
|
Additional Reagents: CH2X2 or CH3X, with strong base
What adds: -CHX- or -CX2- (triangles) Regioselectivity: N/A Stereoselectivity: Retention of stereochemistry Rearrangement: No |
