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21 Cards in this Set
- Front
- Back
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Hydrogenation
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H2 with Pt, Pd, or Ni
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More hydrogenation
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H2, Lindlar catalyst (cis)
OR Na or K in liquid ammonia (NH3 (l)) (trans) |
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Addition of HX
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H, X
for alkynes to alkenes: (1 eq) for alkynes to alkanes: (XS) |
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Halogenation
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X2
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Mercuric Ion-Catalyzed Hydration
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H2SO4 (aq), HgSO4
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Hydroboration-Oxidation
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1) (Sia)2BH (alkynes
1) BH3 2) H2O2, -OH |
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KMnO4 (vig)
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KMnO4 (vig)
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KMnO4 (mild)
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KMnO4 (mild)
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Ozonolysis
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1) O3
2) DMS or pretty much anything else as long as first thing was O3 |
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Osmium tetroxide
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OsO4
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Epoxidation + Ring Opening
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R-CO3H, H+ (aq)
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Epoxidation
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R-CO3H
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Halohydrin formation
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X2, H2O
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Addition of halogens
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X2, inert solvent
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alpha-elimination
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CH2X2 or CHX3
strong base |
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Simmons-Smith
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CH2I2, Zn(Cu)
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Hydroboration-Oxidation
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1) "BH3"
2) H2O2, -OH |
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Alkoxymercuration-Demercuration
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1) Hg(OAc)2, ROH
2) NaBH4 |
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Oxymercuration-Demercuration
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1) Hg(OAc)2, H2O
2) NaBH4 |
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Acid-Catalyzed Hydration
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H3O+
or H2SO4/H2O or H2O/H+ |
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HBr with H2O2
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HBr, peroxide
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