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56 Cards in this Set

  • Front
  • Back

Structure of the Earth

Iron & nickel core, mantle, crust

Tectonic plates

Crust and upper mantle are cracked into large pieces called tectonic plates. They move around- few cm per year

What shows the movement of tectonic plates?

Magnetic clues in rocks. When tectonic plates move apart under the sea, exposed mantle rises up and a new crust solidifies.


New crust is magnetised by Earth's magnetic field. Normal or reverse polarity.


pattern of normal/reversed polarised rocks used to estimate age of parts of crust


Track slow movement of plates



Sedimentary rocks contain clues

Look at features of rocks. Fossils- remains/imprints of dead organisms tells age of rock. Conditions it was formed in.


Shells, ripples,shapes of grains (water-borne or air-blown)

Minerals in the crust- formed by different processes

Sedimentation, Evaporation, Dissolving, Erosion, Mountain building.


Chemical industries grow.

Describe Limestone

-Sedimentary rock from seashells


-over millions of years layers of sediment get buried. Weight pressing down squeezes out water


-natural mineral cement

Describe coal

-Black in colour


-Sedimentary


-Mainly carbon


-lots of impurities

Where is salt found?

Rock salt- salt and impurities, found in underground deposits.


Massive deposits in Cheshire & Teeside, UK

What is normal salt mining?

Physical extraction of salt


Rock salt is drilled, blasted, dug out, brought to surface.


Mostly used on roads to stop ice forming.


- salt can be seperated- flavour food, making chemicals

What is solution mining?

Water is injected into salt deposit.


Dissolves to make brine.


Pressure forces brine to surface.


Brine stored in wells and pumped to refining plant.


Impurities removed.


Brine boiled, water evaporates, salt left.


Most table salt, chemical production.

How do these methods of mining salt impact the environment?

Pollution- mining requires a lot of energy.


Subsidence- land above collapse into holes


Risk reduced by filled in caverns.

Another method of obtaining salt

in hot countries, evaporating seawater.


Shallow pools, left in sun, salt is collected.


Purest salt- almost 100% NaCl

How is salt used in food production?

To enhance flavour. Mostly in processed foods.


As a preservative- when added to meat, kills bacteria

What are health issues with the use of salt?



High intake= High blood pressure, stroke, heart attacks


Increases risks of stomach cancer, osteoporosis, renal failure.



Government issues guidelines for salt intake

Watchdogs, Food Standards agency.


GDA


risk assessments, advise the public.


Food manufactures still include salt to support sales. Cost of reformulating recipes is great.

How is salt important for the chemical industry?

They electrolyse brine- they pass an electric current through it.


Causes chemical change- splits solution into Hydrogen, Chlorine and Sodium Hydroxide.

Electrolysis of Brine- 1) Chlorine


What are the uses?

Disinfectants


Killing bacteria


Household bleach


Plastics


HCL


Insecticides

Uses of hydrogen

ammonia


turning oils into fats- margarine


fuels


welding and metal cutting



Uses of Sodium Hydroxide

Very strong alkali


Soap


Ceramics


Organic chemicals


Paper pulp


Oven cleaner


Household bleach- when it reacts with Chlorine.

Environmental impact of large scale electrolysis

Pollution


Uses finite resources


Mercury and asbestos are used- they are toxic, can cause cancer, contaminate rivers

Chlorine used for water treatment

small amounts added to water to kill bacteria


Prevents algae growth


kills disease causing microorganisms



Why is chlorine important for water treatment?

it lowers death rates- less people die from water-bourne diseases.


Over 1bn dont have access to clean water- very expensive.


Chlorine increases life expectancy.


V important.

What are the disadvantages of chlorinating water?


Why do people object?

Chlorine reacts with compounds to form chlorinated hydrocarbons- carcinogenic.


Chlorine gas irritates respiratory system.


Liquid chlorine causes severe chemical burns.




Some say we dont get a choice- forced 'mass medication'

What are Alkalis?

Type of chemical.


A compound that forms hydroxide ions when dissolved in water.

What is a neutralisation reaction?

Acid and an alkali react to form a salt and water.


The products are neutral.



What are 2 types of neutralisation reactions?

Acid+ Hydroxide= Salt + water


Acid + Carbonate= Salt + water + carbon dioxide

What are the uses of alkalis?

Farmers use alkalis to neutralise acidic soils.


Make chemicals for natural dyes.


Convert fats and oils into soap.


Manufacture glass.



'History' of alkalis

Used for hundreds of years.


People relied on traditional sources- burnt wood & stale urine.


19th Century- Shortage

The LeBlanc Process

Alkalis had to be manufactured on a large scale.


Process invented to make sodium carbonate.




Sodium chloride mixed with sulfuric acid then heated with charcoal and limestone.



Problems of the LeBlanc Process

Very Polluting.


Large volumes of acidic hydrogen chloride- damaged environment.


A lot of solid waste.


Released toxic Hydrogen Sulfide. Foul smell of rotten eggs.

Products made using Chemistry

Drugs, paints, dyes, used in industry, used in the home. agricultural chemicals, plastics, metals, fuels.


So many chemicals- Cannot be tested thoroughly. Not enough data about risks.

Problems with toxic chemicals

Stay in environment if not broken down.


End up in water ways/ eaten by animals.


Spread over large area.


Passed along food chains.


Harm to animals, even humans



How can pesticides be harmful?

1) Insecticide seeps into river 2) small plants take it in 3)Tiny animals eat the plants 4) Small fish eats tiny animals 5) Eel eats small fish 6) Otter eats eels


Toxic to creatures.

How are plasticisers harmful?

Leach out into water sources. Also toxic.

Life Cycle Assessments- Stage 1

Choice of material:


Water mostly needed. Metals mined and extracted. Lots of energy= pollution.


Raw materials- No- renewable and finite. E.g: Crude oil: finite and causes lots of pollution.

LCA- Stage 2

Manufacture:


Lots of energy.


Pollution: CO, HCl.


How to dispose/ recycle.

LCA - Stage 3

Using the product-


can also damage environment.


Paint; toxic fumes


Burning; greenhouse gases


Fertilisers; can leech out, damage ecosystem



LCA- Stage 4

Product Disposal:


Landfill site.


Takes up space, pollutes.


Might be incinerated(burnt); air pollution




Some can be recycled- processed & re- used

as volcanic lava solidifies, igneous rocks are formed . magnetic materials in the lava line up along the Earths magnetic field

the earths magnetic field changes over time. geologists can date rocks and track the slow movement of continents using changes in magnetic patterns, linked to radioactivity. this evidence supports plate tectonic theory

there was limestone in the peak district. limestone formed while Britain was covered by sea:

- shellfish died forming sediments on the sea bed


- sediments compacted and hardened to form limestone, a sedimentary rock


- tectonic plate movements pushed the rock to the surface


- gradually the rocks above were eroded away until the limestone was exposed

coal was found in south Lancashire. coal contains fossils of the plants that formed it

coal formed in wet swampy conditions when plants like trees and ferns died and became buried. this excluded oxygen, slowing down the decay

salt formed while Cheshire was covered by a shallow sea:

- rivers brought dissolved salts into the sea


- climate warming evaporated the water, leaving salt that mixed with sand blown in by the wind


- rock salt formed and was buried by other sediments

limestone contains bits of shell-fragments from sea creatures



rock salt contains different-shaped water-eroded grains and wind-eroded grains

salt is used in:


- the food industry


- as a source of chemicals


- to treat icy roads in winter

salt can be obtained from:


- collecting and evaporating sea water


- mining underground deposits of rock salt



rock salt is spread on icy roads because:


- the rock is insoluble but the sand in the rock salt gives grip


- it shows up so people know when roads have been gritted


- the salt in solution lowers the freezing point, preventing ice forming as easily



solution mining- water is pumped at high pressure into the rock salt, he salt dissolves and the salt solution is pushed to the surface

salt is a valuable raw material, but its extraction can have an environmental impact

- mining rock salt and solution mining can cause subsidence. about half the rock salt cannot be mined, as it is left in for support


- mining can allow water in mines, which may let salt leach out into water supplied, contaminating them


- evaporating salt from sea water takes up large areas and spreads salt into the local environment, damaging habitats

salt is used in food as:


- flavouring


- preservative

a higher salt level prevents bacteria growth


- many people are worried about salt intake which can cause high blood pressure, heart failure and srokes

alkalis neutralise acids to make salts, called neutralisation

acid+ alkali--> salt + water

alkalis are used for:


- dying cloth


-neutralising acid sol


- making soap


- making glass

stale urine and ash from burnt wood were used in the past as a source of alkalis

the first alkali to be manufactured was lime(calcium oxide). this was done by heating limestone (calcium carbonate) in a lime kiln, using coal as fuel

lime us used for:


- neutralising acidic soils


- making glass when heated with sand


- removing impurities when iron is made

the leblanc process made sodium carbonate by reacting salt and limestone, heated with coal. but it gave off large amounts of hydrogen chloride. and produced heaps of solid waste, called galligu, that slowly released hydrogen sulfide

later, a process was invented to change the harmful hydrogen chloride into useful substances:


- chlorine used to bleach textiles prior to dying


- hydrochloric acid, which is a starting material for making other chemicals

chlorine can be made by reacting hydrochloric acid and manganese dioxide

- oxidation converts hydrogen chloride into chlorine


- compounds have different properties from those of the elements they contain

chlorine is added to water supplies to kill microorganism. chlorination killed water-borne microorganisms that cause diseases like cholera and typhoid

chlorine is a toxic gas and can affect human health if too much is present in water

electrolysis breaks up compounds using an electric current

the electrolysis of brine(sodium chloride solution) makes:


- chlorine gas


- hydrogen gas


- sodium hydroxide solution

industrial uses of these products are:


- chlorine for making plastics like PVC, in medicines and crop protection


- hydrogen for making margarine, as rocket fuel, in fuel cells in vehicles


- sodium hydroxide for paper recycling, industrial cleaners and reining aluminium

large amounts of electricity is needed for electrolysis, so its expensive

brine electrolysis is one of the many widely used industrial processes. while the products have many uses, they can have an environmental impact:

- chlorine products, e.g. from fridges and aerosols, are linked to ozon depletion and have been banned


- chlorine used in paper bleaching releases dangerous dioxins, increasing the risk of cancer


- the mercury diaphragm method of electrolysis, which is still used, releases mercury waste. this can enter the food chain and is a cumulative poison


- plastics made using chlorine are non-biodegradable