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7 Cards in this Set

  • Front
  • Back
Ionization Potentials
amt. of energy it takes to move an e- inf. dist. from the nucleus; opp of e- energy on table

Factors that influence it:
orbital size, nuclear charge, orbital occupancy
molecular orbital vs. atomic orbital relating to IP
MO IP > AO IP b/c bonds are lower in energy
Energy and Bonds
*know diagram in notes
-forming bonds stabilizes (lowers energy) of e-s
-breaking bonds supplies energy
-i.e. if - formal charge, e- energy high and IP low
-high e- energy are more chemically reactive
-valent
mono-, di-, tri-, tetra-

how many bonds to each......

i.e. CH4: C is tetravalent/H is monovalent
condensed structure
( ) - comes off chain
Ph - benzene ring
Formal Charges
homolytic vs. heterlytic bond cleavage
homo - electrically neutral/ fishhook used to move e-s individually

herer - anion(-) or cation(+); doublehead arrow used

formal charge = (# valence e's- (# non-bonding e's) - 1/2 (# e's in bonds)
wavefunction
psi = f(n,l,m,s,r)

P(r) = psi squared