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14 Cards in this Set

  • Front
  • Back
Formula for max. # of
diastereomers a cpd can have
2ⁿ where n = # of chiral centers
Name the 2 types of
stereoisomers
conformational and configurational
Under what type of stereoisomer does geometric
isomer fall
diastereomer of the cis-/trans-
type.
which isomer has a mirror
image?
enantiomer (mneumo: an ant in
a mirror [picture it!] ) Courtesy of exam krackers
define chiral carbon
has 4 different substituents
what is chiral?
chiral is handedness. cannot be superimposed.
Another word for chiral center
Stereogenic center
Type of isomer that contains at least 2 chiral centers, yet the molecule itself is not chiral-
it is optically inactive
meso compound
Meso cpds have a ___ of ___ through their centers, dividing it into a ___ ___ if itself
plane of symmetry; mirror image
Type of diastereomer that exists due to hindered rotation
around a bond
geometric isomer, cis- and trans-
Concerning cis- and trans-, which one has a dipole moment?
cis-
Between cis- and trans-, which
has stronger intermolecular forces?
cis-
Stronger intermolecular forces means ___ boiling points
higher
lower symmetry in cis- isomers means ___
likely to form crystals (less/more)
less