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27 Cards in this Set
- Front
- Back
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KMnO4 |
Creates carboxylic acids. |
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To add Br |
Use Br2 and FeBr3 |
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Add two methyl groups |
Use 2 CH3Cl |
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When reacted with esters, Mg |
Cleaves the non-phenol R group and creates and alcohol, which opens 2 spaces to be filled |
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LiAlH4 |
Turns all oxygen into alcohol. |
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HNO3 and pyridine |
Cleaves alcohols and makes alkenes. |
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AlCl3 is great for |
Adding substituent groups that have chlorine that can be cleaved off |
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Cr03 and H |
Convert alcohols to carboxylic acids |
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PCC |
Converts alcohols to aldehydes and ketones. |
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To add an alcohol to benzene |
Add a chlorine with Cl2/FeCl3 first and then just add hydroxy |
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To add an aldehyde with a long R chain |
Use AlCl3 and and aldehyde with a chlorine on it |
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To eliminate the oxygen of an aldehyde group |
Use H2/Pd |
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POCl3 works by |
losing 2 chlorines to absorb and oxygen and create an alkene. |
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How do you add florine to benzene? |
Use the florine/chlorine nitrogen ring with the 2 step carbon bridge |
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Nitro does not react at all when |
using AlCl3 |
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The two parts of oxymercuration are |
1) Hg(O2CCF3)2 2) NaBH4 |
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Oxygen rings can form carbon-carbon bonds and an alcohol group using what? |
R-Br and Mg |
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Why is para favored over meta? |
Delocalization of electrons, usually by an oxygen group. |
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You add a nitro group with |
HNO3 and H2SO4 |
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What does TMSCl do? |
Occupies an oxygen in a hydroxyl group for a while |
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What does OLi on an alkene do? |
You can use it to create a ketone by disposing of a halide. |
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Hg(OAc)2 does what? |
Creates a ketone out of an alkene. |
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Thiourea does what? |
Replaces halides with SH |
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What bonds to sulfurs together? |
KOH/H2O+I2 and a base |
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What takes priority in numbering when determining a name; an alcohol or a double bond? |
Alcohol |
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What is the most reactive part of a benzene ring? |
The carbon immediately attached to it. |
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mCPBA does what to sulfur? |
Adds 2 double bonded oxygens. |
