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10 Cards in this Set

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Structure: Triglycerides

1. Macromolecule


2. Condense glycerol + 3 fatty acids


3. Ester linkage btw OH and COOH


Structure & properties : Glycerol

Alcohol w/ 3 carbon ea w/ OH grp



- polar molecule


- form h-bond w/ water


- soluble in water

Structure & Properties: Fatty Acids

Long non-polar, hydrophobic hydrocarbon chains w/ carboxyl grp


- saturated: only c-c and c-h single bonds


- unsaturated: has c=c double bond


♢Trans: no kink


♢Cis: kink



Properties


- non-polar: many c-h bonds


- ✖h-bond w/ H2O: insoluble : hydrophobic


- weak acids: carboxyl dissociate

Properties: Triglyceride

1. Non-polar: ✖H-Bond w/ H2O: insoluble

F (x): Triglyceride

1. Major fx: energy storage (38kJg-1)


- 2x as much energy per gram


♢ higher proportion of C-H atoms + lower proportion of O2 for =vilant mass of c.hydrates.


○higher prop. C-h bonds for oxidation: more atp: compact energy store


♢Insoluble: does not affect water potential: efficient storage molecule


2. Production of Metabolic H2O during oxidation


3. Protect internal organs, thermal insulation, improve buoyancy, reservoir for fat soluble vitamins

Structure: Phospholipids

Component: 2 non-polar hydrophobic CH tails + glycerol + phosphate head


Bond:


glycerol - phosphate = phosphoester linkage


Glycerol - tail = ester bond




Properties: Phospholipids

- Amphipathic: Both h.phobic and h.phillic


♢ h.phillic charged phosphate head interact w/ h2o


♢ in h2o, aggregate and form hydrophobic core

Fx: phospholipids

1. Major comp of cell membranes


♢phospholipid bilayer


○acts as boundary- compartmentalisation


○hydrophobic core: low permeablilty for polar and charged molecules - barrier


♢move laterally -> membrane fluidity


♢liposome: vesical surrounded by phospholipid bilayer

Properties: Cholesterol

1. Insoluble in h2o, soluble in organic solvants


2. Slightly amphipathic, hydrophilic oh grp and hydrophobic ring structure


3. Fused ring structure is rigid => mechanical stability to fluid lipid layer

Fx: cholesterol

1. Regulates membrane fluidity - @high temp, cholesterol restricts phospholipid movement, preventing overly fluid membrane


2. Prevents close packing at low temperature